메뉴 건너뛰기




Volumn 120, Issue 23, 1998, Pages 5764-5770

Theoretical investigation of Stevens rearrangement of P and As ylides. Migration of H, CH3, CH = CH2, SiH3, and GeH3 groups on P and As atoms

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; METHYL GROUP; VINYL DERIVATIVE;

EID: 0032540674     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9803207     Document Type: Article
Times cited : (13)

References (50)
  • 16
    • 37049128089 scopus 로고
    • s symmetry. They ascribed this small activation energy to the large exothermicity of 87 kcal/mol, and proposed the concerted mechanism for this migration. However, this small activation energy obtained by the semiempirical calculations is not reliable. We obtained the activation energy of 43 kcal/mol at the B3LYP level of calculations under the same symmetry constraint. Dewar, M. J. S.; Ramsden, C. A. J. Chem. Soc., Perkin Trans. 1 1974, 1839.
    • (1974) J. Chem. Soc., Perkin Trans. , vol.1 , pp. 1839
    • Dewar, M.J.S.1    Ramsden, C.A.2
  • 50
    • 17344368042 scopus 로고    scopus 로고
    • Makita, K.; Koketsu, J.; Koga, N. To be submitted
    • Makita, K.; Koketsu, J.; Koga, N. To be submitted.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.