How does the intrinsic barrier of intermolecular proton transfer depend on molecular parameters?

Angewandte Chemie - International Edition

Volumn 37, Issue 21, 1998, Pages 3052-3054

  Goez, Martin ^a   Heun, Rainer ^a  

^a MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

Author keywords

Kinetics; NMR spectroscopy; Protonations; Valence bond methods

Indexed keywords

ACID; ANILINE DERIVATIVE; PROTON;

ARTICLE; ENERGY; KINETICS; MODEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON TRANSPORT; THERMODYNAMICS;

EID: 0032538767     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19981116)37:21<3052::AID-ANIE3052>3.0.CO;2-A     Document Type: Article

References (29)

1. a) R. P. Bell, The Proton in Chemistry, Chapman & Hall, London, 1973;
2. b) V. Gold, E. Caldin, Proton-transfer Reactions, Chapman & Hall, London, 1975;
3. c) C. H. Bamford, Proton Transfer, Elsevier, Amsterdam, 1978;
4. d) "Proton and Electron Transfer": Faraday Discuss. Chem. Soc. 1982, 74;
5. e) Electron and Proton Transfer in Chemistry and Biology (Eds.: A. Müller, H. Ratajczak, W. Junge, E. Diemann), Elsevier, Amsterdam, 1992;
6. f) "Hydrogen Transfer: Experiment and Theory": Ber. Bunsenges. Phys. Chem. 1998, 102.
7. a) R. A. Marcus, J. Chem. Phys. 1956, 24, 966-978;
8. b) R. A. Marcus, J. Phys. Chem. 1968, 72, 891-899;
9. c) F. Scandola, V. Balzani, J. Am. Chem. Soc. 1979, 101, 6140-6141.
10. a) R. A. Marcus, Annu. Rev. Phys. Chem. 1964, 15, 155-196;
11. b) M. Goez, Z. Physik. Chem. Neue Folge 1990, 169, 133-145.
12. Recent reviews: a) C. F. Bernasconi, Adv. Phys. Org. Chem. 1992, 27, 119-238;
13. b) C. F. Bernasconi, Acc. Chem. Res. 1992, 25, 9-16, and references therein.
14. a) C. F. Bernasconi, P. J. Wenzel, J. Am. Chem. Soc. 1996, 118, 10949-10504;
15. b) C. F. Bernasconi, P. J. Wenzel, J. Am. Chem. Soc. 1996, 118, 11446-11453;
16. c) C. F. Bernasconi, P. J. Wenzel, J. R. Keeffe, S. Gronert, J. Am. Chem. Soc. 1997, 119, 4008-4020;
17. d) C. F. Bernasconi, R. L. Montanez, J. Org. Chem. 1997, 62, 8162-8170.
18. a) J. P. Guthrie, J. Am. Chem. Soc. 1996, 118, 12886-12890;
19. b) J. P. Guthrie, J. Am. Chem. Soc. 1997, 119, 1151-1152.
20. M. Eigen, Angew. Chem. 1963, 75, 489-508.
21. J. F. Coetzee, Prog. Phys. Org. Chem. 1967, 4, 45-92.
22. M. Goez, R. Heim, Ber. Bunsenges. Phys. Chem. 1998, 102, 560-566.
23. a) H. K. Hall, Jr., J. Phys. Chem. 1956, 60, 63-70;
24. b) B. M. Latta, R. W. Taft, J. Am. Chem. Soc. 1967, 59, 5172-5178;
25. c) C. K. Mann, K. K. Barnes, Electrochemical Reactions in Nonaqueous Systems, Marcel Dekker, New York, 1970;
26. d) A. Buchs, Helv. Chim. Acta 1970, 53, 2026-2035.
27. a) A. Pross, S. S. Shaik, Acc. Chem. Res. 1983, 16, 363-369;
28. X2 Mechanism, Wiley Interscience, New York, 1992;
29. c) A. Pross, Theoretical and Physical Principles of Organic Reactivity, Wiley-Interscience, New York, 1995.