Structures of solvent-free, monomeric liCCH, naCCH, and KCCH

Angewandte Chemie - International Edition

Volumn 37, Issue 19, 1998, Pages 2678-2681

  Grotjahn, Douglas B ^a   Apponi, Aldo J ^b   Brewster, Matthew A ^b   Xin, Ju ^b   Ziurys, Lucy M ^b  

^a SAN DIEGO STATE UNIVERSITY   (United States)

^b University of Arizona   (United States)

Author keywords

Alkali metals; Alkynes; Gas phase chemistry; Rotational spectroscopy

Indexed keywords

EID: 0032538574     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19981016)37:19<2678::AID-ANIE2678>3.0.CO;2-6     Document Type: Article

References (47)

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7. Reviews: a) J. L. Wardell in Comprensive Organometallic Chemistry, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1982, Chap. 2, pp. 43-120; b) W. N. Setzer, P. von R. Schleyer, Adv. Organomet. Chem. 1985, 24, 353-451; c) C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278; d) E. Weiss, Angew. Chem. 1993, 105, 1565-1587; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501-1523; e) P. G. Willard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, pp. 1-47; f) M. A. Beswick, D. S. Wright in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, New York, 1995, Chap. 1.
8. Reviews: a) J. L. Wardell in Comprensive Organometallic Chemistry, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1982, Chap. 2, pp. 43-120; b) W. N. Setzer, P. von R. Schleyer, Adv. Organomet. Chem. 1985, 24, 353-451; c) C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278; d) E. Weiss, Angew. Chem. 1993, 105, 1565-1587; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501-1523; e) P. G. Willard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, pp. 1-47; f) M. A. Beswick, D. S. Wright in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, New York, 1995, Chap. 1.
9. Reviews: a) J. L. Wardell in Comprensive Organometallic Chemistry, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1982, Chap. 2, pp. 43-120; b) W. N. Setzer, P. von R. Schleyer, Adv. Organomet. Chem. 1985, 24, 353-451; c) C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278; d) E. Weiss, Angew. Chem. 1993, 105, 1565-1587; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501-1523; e) P. G. Willard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, pp. 1-47; f) M. A. Beswick, D. S. Wright in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, New York, 1995, Chap. 1.
10. Reviews: a) J. L. Wardell in Comprensive Organometallic Chemistry, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1982, Chap. 2, pp. 43-120; b) W. N. Setzer, P. von R. Schleyer, Adv. Organomet. Chem. 1985, 24, 353-451; c) C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278; d) E. Weiss, Angew. Chem. 1993, 105, 1565-1587; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501-1523; e) P. G. Willard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, pp. 1-47; f) M. A. Beswick, D. S. Wright in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, New York, 1995, Chap. 1.
11. Reviews: a) J. L. Wardell in Comprensive Organometallic Chemistry, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1982, Chap. 2, pp. 43-120; b) W. N. Setzer, P. von R. Schleyer, Adv. Organomet. Chem. 1985, 24, 353-451; c) C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278; d) E. Weiss, Angew. Chem. 1993, 105, 1565-1587; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501-1523; e) P. G. Willard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, pp. 1-47; f) M. A. Beswick, D. S. Wright in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, New York, 1995, Chap. 1.
12. Reviews: a) J. L. Wardell in Comprensive Organometallic Chemistry, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1982, Chap. 2, pp. 43-120; b) W. N. Setzer, P. von R. Schleyer, Adv. Organomet. Chem. 1985, 24, 353-451; c) C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278; d) E. Weiss, Angew. Chem. 1993, 105, 1565-1587; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501-1523; e) P. G. Willard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, pp. 1-47; f) M. A. Beswick, D. S. Wright in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, New York, 1995, Chap. 1.
13. Reviews: a) J. L. Wardell in Comprensive Organometallic Chemistry, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1982, Chap. 2, pp. 43-120; b) W. N. Setzer, P. von R. Schleyer, Adv. Organomet. Chem. 1985, 24, 353-451; c) C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278; d) E. Weiss, Angew. Chem. 1993, 105, 1565-1587; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501-1523; e) P. G. Willard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, pp. 1-47; f) M. A. Beswick, D. S. Wright in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, New York, 1995, Chap. 1.
14. Solution studies: a) G. Fraenkel, P. Pramanik, J. Chem. Soc. Chem. Commun. 1983, 1527-1529; b) R. Hässig, D. Seebach, Helv. Chim. Acta 1983, 66, 2269-2273; c) W. Bauer, D. Seebach, Helv. Chim. Acta 1984, 67, 1972-1988 d) R. Gareyev, A. Streitwieser, J. Org. Chem. 1996, 61, 1742-1747.
15. Solution studies: a) G. Fraenkel, P. Pramanik, J. Chem. Soc. Chem. Commun. 1983, 1527-1529; b) R. Hässig, D. Seebach, Helv. Chim. Acta 1983, 66, 2269-2273; c) W. Bauer, D. Seebach, Helv. Chim. Acta 1984, 67, 1972-1988 d) R. Gareyev, A. Streitwieser, J. Org. Chem. 1996, 61, 1742-1747.
16. Solution studies: a) G. Fraenkel, P. Pramanik, J. Chem. Soc. Chem. Commun. 1983, 1527-1529; b) R. Hässig, D. Seebach, Helv. Chim. Acta 1983, 66, 2269-2273; c) W. Bauer, D. Seebach, Helv. Chim. Acta 1984, 67, 1972-1988 d) R. Gareyev, A. Streitwieser, J. Org. Chem. 1996, 61, 1742-1747.
17. Solution studies: a) G. Fraenkel, P. Pramanik, J. Chem. Soc. Chem. Commun. 1983, 1527-1529; b) R. Hässig, D. Seebach, Helv. Chim. Acta 1983, 66, 2269-2273; c) W. Bauer, D. Seebach, Helv. Chim. Acta 1984, 67, 1972-1988 d) R. Gareyev, A. Streitwieser, J. Org. Chem. 1996, 61, 1742-1747.
18. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
19. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
20. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
21. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
22. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
23. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
24. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
25. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
26. Solid-state structures: a) H. Föppl, Angew. Chem. 1958, 70, 401; b) E. Weiss, H. Plass, Chem. Ber. 1968, 101, 2947-2955; c) M. Atoji, J. Chem. Phys. 1972, 56, 4947-4951; d) B. Schubert, E. Weiss, Angew. Chem. 1983, 95, 499-500; Angew. Chem. Int. Ed. Engl. 1983, 22, 496-497; e) B. Schubert, E. Weiss, Chem. Ber. 1983, 116, 3212-3215; f) M. Geissler, J. Kopf, B. Schubert, E. Weiss, W. Neugebauer, P. von R. Schleyer, Angew. Chem. 1987, 99, 569-570; Angew. Chem. Int. Ed. Engl. 1987, 26, 587-588; g) B. Goldfuss, P. von R. Schleyer, F. Hampel, J. Am. Chem. Soc. 1997, 119, 1072-1080.
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39. a) Spectroscopic details for NaCCH have been reported in reference [9b]. Here we report corrected data, which properly assign the ground vibrational state. In addition, excited-state data for LiCCH have been obtained and will be reported separately;
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