Stereoselective thermal conversion of s-trans-diallene into dimethylenecyclobutene via s-cis-diallene in the crystalline state

Angewandte Chemie - International Edition

Volumn 37, Issue 19, 1998, Pages 2724-2727

  Toda, Fumio ^a   Tanaka, Koichi ^a   Tamashima, Tomoyuki ^a   Kato, Masako ^b  

^a EHIME UNIVERSITY   (Japan)

^b NARA WOMEN'S UNIVERSITY   (Japan)

Author keywords

Allenes; Cyclobutenes; Electrocyclic reactions; Solid state chemistry

Indexed keywords

EID: 0032538470     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19981016)37:19<2724::AID-ANIE2724>3.0.CO;2-Y     Document Type: Article

References (24)

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19. max = 55°. The structures of 2b and 5b were solved by direct methods and heavy-atom Patterson methods, respectively, and expanded with Fourier techniques. The diallene moiety of 5b was found to be disordered. All calculations were carried out with the teXsan crystallographic software package from the Molecular Structure Corporation.
20. b) Crystallographic data for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-101408. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
21. [10b]
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