The biosynthesis of the fungal meroterpenoids boviquinone-3 and -4 follows two different pathways

Tetrahedron Letters

Volumn 39, Issue 29, 1998, Pages 5167-5170

  Mühlbauer, Andrea ^a   Beyer, Jürgen ^a   Steglich, Wolfgang ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

Biosynthesis; Fungal pigments; Meroterpenoids; Quinones

Indexed keywords

BOVIQUINONE 3; BOVIQUINONE 4; PROTOCATECHUIC ACID; QUINONE DERIVATIVE; TERPENOID; UNCLASSIFIED DRUG;

ARTICLE; BASIDIOMYCETES; NONHUMAN; PRENYLATION; SYNTHESIS;

BASIDIOMYCOTA; CHROOGOMPHUS RUTILUS; RUTILUS; SUILLUS BOVINUS;

EID: 0032537659     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)01039-9     Document Type: Article

References (19)

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8. [8] Arnold, R.; Steglich, W. unpublished experiments.
9. [9] Beyer, J.; Lang-Fugmann, S.; Mühlbauer, A.; Steglich, W. Synthesis, in press.
10. 13C enrichment of 1.1%.
11. 13C enrichments: C-4 (δ 146.9) 50%, C-10 (δ 161.3) 25% and C-12 (δ 167.1) 25%.
12. 13C enrichments: C-4 (δ 146.9) 50%, C-10 (δ 161.3) 25% and C-12 (δ 167.1) 25%.
13. [12] Jägers, E.; Pasupathy, V.; Hovenbitzer, A.; Steglich, W. Z. Naturforsch. 1986, 41b, 645.
14. 13C enrichment of 36% at C-4 (δ 142.1).
15. 13C enrichments of 0.5 and 1.1%. respectively.
16. [15] Piattelli, M.; Geraci, C.; Lambusta, D.; Cianci, P. Planta Med. 1992. 58, 383.
17. 13C]acetate. respectively, before entering the mevalonate pathway.
18. 13C enrichment 9% ), C-10 and C-12 (each 5%).
19. [18] Compare e.g. Strack, D. Phenolic Metabolism, Academic Press, San Diego 1997.