Cycloadditions of allylsilanes, part 13: Lewis acid-promoted stereospecific [2+2] cycloaddition of crotylsilanes and methyl propynoate

Tetrahedron Letters

Volumn 39, Issue 42, 1998, Pages 7705-7708

  Knölker, Hans Joachim ^a   Baum, Elke ^a   Schmitt, Oliver ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; SILANE DERIVATIVE; TITANIUM DERIVATIVE;

ARTICLE; GERMANY; MOLECULAR INTERACTION; STEREOSPECIFICITY; SYNTHESIS;

EID: 0032532571     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)01678-5     Document Type: Article

References (51)

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44. 3): δ = 0.68 (dd, J = 15.6, 10.0, 1 H), 1.01-1.09 (m, 22 H), 1.10 (d, J = 7.2, 3 H), 2.90 (dq, J = 4.4, 7.2, 1 H), 3.25 (br dt, J = 10.0, 3.7, 1 H), 3.70 (s, 3 H), 6.75 (s, 1 H).
45. 3): δ = 0.64 (dd, J = 15.2, 12.2, 1 H), 1.01-1.09 (m, 21 H), 1.17 (d, J = 7.8, 3 H), 1.35 (dd, J = 15.2, 2.2, 1 H), 2.34 (br q, J = 7.0, 1 H), 2.59 (ddd, J = 12.2, 1.9, 1.6, 1 H), 3.72 (s, 3 H), 6.75 (s, 1 H).
46. 6): δ = 0.99-1.12 (m, 21 H), 1.62 (dd, J = 6.7, 1.6, 3 H), 2.19 (d, J = 9.4, 2 H), 3.46 (s, 3 H), 5.78 (dq, J = 15.5, 6.7, 1 H), 6.14 (t, J = 9.4, 1 H), 6.21 (dd, J = 15.5, 1.0, 1 H).
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50. 2 (SHELXL-93); the program SCHAKAL-97 was used for the graphical representation of the crystal structure. Atomic coordinates, bond lengths and angles, and thermal parameters have been deposited at the Cambridge Crystallographic Data Centre.
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