Investigation of dual-staged polymerization and secondary forming of photopultruded, fiber-reinforced, methacrylate-copolymer composites

Journal of Biomedical Materials Research

Volumn 41, Issue 4, 1998, Pages 549-559

  Kennedy, K C ^a,b,c   Kusy, R P ^a,b  

^a NORTH CAROLINA STATE UNIVERSITY   (United States)

^b UNIVERSITY OF NORTH CAROLINA   (United States)

^c Minrad Inc   (United States)

Author keywords

Composites; Fiber reinforced polymers; Methacrylates; Photopolymerization; Photopultrusion

Indexed keywords

BIOASSAY; BIOMECHANICS; COPOLYMERS; FIBER REINFORCED PLASTICS; PHOTOCHEMICAL REACTIONS; PHOTOPOLYMERIZATION; POLYMETHYL METHACRYLATES; SOLUBILITY;

DUAL STAGED POLYMERIZATION; PHOTOPULTRUSION;

BIOMATERIALS;

COPOLYMER; POLYMETHACRYLIC ACID;

BIOMECHANICS; CONFERENCE PAPER; GEL PERMEATION CHROMATOGRAPHY; GELATINIZATION; HARDNESS; PHYSICAL CHEMISTRY; POLYMERIZATION; PROSTHESIS MATERIAL; TENSILE STRENGTH;

BIOCOMPATIBLE MATERIALS; MATERIALS TESTING; METHACRYLATES; MICROSCOPY, ELECTRON, SCANNING; POLYMERS;

EID: 0032531283     PISSN: 00219304     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-4636(19980915)41:4<549::AID-JBM6>3.0.CO;2-C     Document Type: Conference Paper

References (46)

1. R.P. Kusy and K. C. Kennedy, "Novel Pultruded Fiber-Reinforced Plastic and Related Apparatus and Method," U.S. Patent 08/295,540 pending.
2. K. C. Kennedy and R. P. Kusy, "UV-cured pultrusion processing of glass-reinforced polymer composites," J. Vinyl Additive Technol., 1, 182-186 (1995).
3. K. C. Kennedy, T. Chen, and R. P. Kusy, "Mechanical properties of micron-sized pultruded composite profiles," in Advanced Composites X, ASM International®, Materials Park, Ohio, 1994, pp. 191-200.
4. K. C. Kennedy, T. Chen, and R. P. Kusy, "Behavior of photopolymerized silicate glass fiber-reinforced dimethacrylate composites subjected to hydrothermal aging. I. Steady-state sorption characteristics," J. Mater. Sci. Mater. Med., 9, 243-248 (1998).
5. K. C. Kennedy, T. Chen, and R. P. Kusy, "Behavior of photopolymerized silicate glass fiber-reinforced dimethacrylate composites subjected to hydrothermal aging. II. Hydrolytic stability of mechanical properties," J. Mater. Sci. Mater. Med., to appear.
6. W. B. Goldsworthy, "Apparatus and Method for Producing Reinforced Plastic Composite Articles of Non-Uniform Shape and Non-Uniform Volume," U.S. Patent 04/462,946, 1984.
7. A. K. Liskey, "Pultrusion on a fast track," Adv. Mater. Processes, 135, 31-35 (1989).
8. P. J. Flory, Principles of Polymer Chemistry, Cornell University Press, Ltd., London, 1953, pp. 114-115.
9. G. Oster and N. L. Yang, "Photopolymerization of vinyl monomers," Chem. Rev., 68, 125-151 (1968).
10. A. Ledwith, "Photoinitiation of polymerization," Pure Appl. Chem., 49, 431-441 (1977).
11. A. Peutzfeldt and E. Asmussen, "Hardness of restorative resins: Effect of camphorquinone, amine, and inhibitor," Acta Odontol. Scand., 47, 229-231 (1989).
12. J. L. Ferrecane and E. H. Greener, "The effect of resin formulation on the degree of conversion and mechanical properties of dental restorative resins," J. Biomed. Mater. Res., 20, 121-131 (1986).
13. F. A. Rueggenberg and R. G. Craig, "Correlation of parameters used to estimate monomer conversion in a light-cured composite," J. Dent. Res., 67, 932-937 (1988).
14. E. Asmussen, "Restorative resins: Hardness and strength vs. quantity of remaining double bonds," Scand. J. Dent. Res., 90, 484-489 (1982).
15. G. C. Eliades, G. J. Vougiouklakis, and A. A. Caputo, "Degree of double bond conversion in light-cured composites," Dent. Mater., 3, 19-25 (1987).
16. K. Yoshida and E. H. Greener, "Effects of two amine reducing agents on the degree of conversion and physical properties of an unfilled light-cured resin," Dent. Mater., 9, 246-251 (1993).
17. J. Ferracane, "Correlation between hardness and degree of conversion during the setting reaction of unfilled dental restorative resins," Dent. Mater., 1, 11-14 (1985).
18. S. Hirabayashi, J. A. A. Hood, and T. Hirasawa, "Extent of polymerization of class II light-cured composite resin restorations effects of incremental placement technique, exposure time and heating for resin inlays," Dent. Mater. J., 12, 159-170 (1993).
19. J. Hutchinson and A. Ledwith, "Photoinitiation of vinyl polymerization by aromatic carbonyl compounds," in Advances in Polymer Science, Vol. 14, H.-J. Cantow (ed.), Springer-Verlag, Berlin, 1974, pp. 49-86.
20. S.-Y. Lee and E. H. Greener, "Effect of excitation energy on dentine bond strength and composite properties," J. Dent., 22, 175-181 (1994).
21. W. D. Cook, "Photopolymerization kinetics of dimethacrylates using the camphorquinone/amine initiator system," Polymer, 33, 600-609 (1992).
22. F. A. Rueggeberg, W. F. Caughman, J. W. Curtis, Jr., and H. C. Davis, "A predictive model for the polymerization of photoactivated resin composites," Int. J. Prosthodont., 7, 159-166 (1994).
23. R.G. Craig, "Chemistry, composition, and properties of composite resins," Dent. Clin. N. Am., 25, 219 (1981).
24. M. Kawaguchi, T. Fukushima, and K. Miyazaki, "The relationship between cure depth and transmission coefficient of visible-light-activated resin composites," J. Dent. Res., 73, 516-521 (1994).
25. S. Venz and J. M. Antonucci, "Effect of photoaccelerators on curing and discoloration of composites," J. Dent. Res., 66, 246 (1987).
26. M. Taira, H. Urabe, T. Hirose, K. Wakasa, and M. Yamaki, "Analysis of photoinitiators in visible-light-cured dental composite resins," J. Dent. Res., 67, 24-28 (1988).
27. K. Yoshida and E. H. Greener, "Effect of photoinitiator on degree of conversion of unfilled light-cured resin," J. Dent., 22, 296-299 (1994).
28. M. Taira, H. Urabe, K. Wakasa, and M. Yamaki, "The effects of the photoinitiator concentrations on the curing behaviors of Bis-GMA monomer," Hiroshima Diagaku Shigaku Zasshi, 21, 382-386 (1989).
29. T. Chen and R. P. Kusy, "Effect of methacrylic acid:methyl methacrylate monomer ratios on polymerization rates and properties of polymethyl methacrylates," J. Biomed. Mater. Res., 36, 190-199 (1997).
30. R. P. Kusy and A. M. Stush, "Geometric and material parameters of a nickel-titanium and a beta titanium orthodontic archwire alloy," Dent. Mater., 3, 207-217 (1987).
31. E. P. Popov, Introduction to Mechanics of Solids, Prentice Hall, Englewood Cliffs, New Jersey, 1968, pp. 99, 183, 397.
32. J. B. Park and R. S. Lakes, Biomaterials an Introduction, 2nd ed., Plenum, New York, 1992, pp. 170-171.
33. J. F. Shackelford, Introduction to Materials Science for Engineers, 2nd ed., Macmillan, New York, 1988, pp. 473.
34. F. P. Beer and E. R. Johnston, Jr., Vector Mechanics For Engineers: Statics, McGraw-Hill, New York, 1977, pp. 361.
35. S. W. Zufall and R. P. Kusy, unpublished work.
36. I. E. Ruyter and P. Györösi, "An infrared spectroscopic study of sealants," Scand. J. Dent. Res., 84, 396-400 (1984).
37. G. R. Finnegan and A. D. Shine, "Modeling the cure kinetics of crosslinking free radical polymerizations using the Avrami theory of phase transformation," Polymer Preprints, 36, 833-834 (1995).
38. G. V. Korolev and A. A. Berlin, "Polymerization in highly viscous media and three-dimensional polymerization. III. The mechanism of auto-acceleration in the initial and middle stages of the polymerization of polyester-acrylates," Polym. Sci. USSR., 4, 500-506 (1963).
39. A. R. Schultz, P. I. Roth, and G. B. Rathmann, "Light scattering and viscosity study of electron-irradiated polystyrene and polymethacrylates," J. Polym. Sci. 22, 495-507 (1956).
40. R. P. Kusy and D. T. Turner, "Influence of the molecular weight of poly(methyl methacrylate) on fracture surface energy in notched tension," Polymer, 17, 161-166 (1976).
41. E. Asmussen and A. Peutzfeldt, "Mechanical properties of heat-treated restorative resins for use in the inlay/onlay technique," Scand. J. Dent. Res., 98, 564-567 (1990).
42. K. J. Reinharde, "Die extraorale vergütung von kompositinlays," Dtsch. Zahnärztl Z., 46, 342-345 (1991).
43. J. Vaidyanathan, T. K. Vaidyanathan, Y. Wang, and T. Viswanadhan, "Thermoanalytical characterization of visible light cure dental composites," J. Oral Rehab., 19, 49-64 (1992).
44. A. Maffezzoli, R. Terzi, and L. Nicolais, "Cure behavior of visible light activated dental composites. I. Isothermal kinetics," J. Mater. Sci. Mater. Med., 6, 155-160 (1995).
45. K. Chung and E. H. Greener, "Degree of conversion of seven visible light-cured posterior composites," J. Oral Rehab., 15, 555-560 (1988).
46. J. L. Ferracane and E. H. Greener, "Fourier transform infrared analysis of degree of polymerization in unfilled resins - Methods of comparison," J. Dent. Res., 63, 1093-1095 (1984).