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Volumn 560, Issue 1-2, 1998, Pages 55-61

A kinetic and spectroscopic study of the interaction between a M(CO)5 (M=Cr, W) fragment and ethyl diazoacetate

Author keywords

Laser flash photolysis; Ligand; Pentacarbonyl fragment

Indexed keywords


EID: 0032525596     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00511-7     Document Type: Article
Times cited : (6)

References (37)
  • 12
    • 0010156129 scopus 로고    scopus 로고
    • 6] is valid
    • 6] is valid.
  • 17
    • 0010150173 scopus 로고    scopus 로고
    • This value is extrapolated to 20°C from the activation parameters given in Ref. [9]
    • This value is extrapolated to 20°C from the activation parameters given in Ref. [9].
  • 29
    • 0010211130 scopus 로고    scopus 로고
    • 2
    • 2.
  • 30
    • 0010156131 scopus 로고    scopus 로고
    • 2O) complex in both liquid Xe and hexane at -78°C are similar
    • 2O) complex in both liquid Xe and hexane at -78°C are similar.
  • 33
    • 0010094256 scopus 로고    scopus 로고
    • -1 band may be due to the diazo stretch of a nitrogen bound metal-eda adduct (type I). However, because the metal carbonyl ligand stretching frequencies are close to those observed for the acetone and water complexes (both of which are oxygen bound), we favor assignment of the observed frequencies to a type III structure. Furthermore, as discussed later, there is some evidence that the nitrogen bound adduct is generated at lower temperatures
    • -1 band may be due to the diazo stretch of a nitrogen bound metal-eda adduct (type I). However, because the metal carbonyl ligand stretching frequencies are close to those observed for the acetone and water complexes (both of which are oxygen bound), we favor assignment of the observed frequencies to a type III structure. Furthermore, as discussed later, there is some evidence that the nitrogen bound adduct is generated at lower temperatures.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.