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3
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0000662343
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It is reported that electron donating substituents on Cp rings tend to increase the catalytic activity of the group IV metallocene olefin polymerization catalysts. For example, see
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It is reported that electron donating substituents on Cp rings tend to increase the catalytic activity of the group IV metallocene olefin polymerization catalysts. For example, see W. Kaminsky, Macromol. Chem. Phys. 197 (1996) 3907-3945.
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9
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11
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12
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(e) W. Kaminsky, O. Rabe, A.-M. Schauwienold, G. U. Schupfner, J. Hanss, J. Kopf, J. Organomet. Chem. 497 (1995) 181-193.
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14
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(g) S.T. Chacon, E.B. Coughlin, L.M. Henling, J.E. Bercaw, J. Organomet. Chem. 497 (1995) 171-180.
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(c) R.P. Hughes, J.R. Lomprey, A.L. Rheingold, B.S. Haggerty, G.P.A. Yap, J. Organomet. Chem. 517 (1996) 89-99.
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21
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0010162378
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It is possible that these NMR spectra represent one isomer 12-out. However, the NMR spectra of 12 did not change at 50°C in THF in 3 h and signals assignable to the isomers were not observed
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It is possible that these NMR spectra represent one isomer 12-out. However, the NMR spectra of 12 did not change at 50°C in THF in 3 h and signals assignable to the isomers were not observed.
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22
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0029954535
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s-symmetric ansa-zirconocene complex that has vicinal two trimethylsilyl groups on its Cp ring
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s-symmetric ansa-zirconocene complex that has vicinal two trimethylsilyl groups on its Cp ring. T.A. Herzog, D.L. Zubris, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 11988-11989.
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0010104106
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US Patent 5 500 398, Chem. 1996
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(b) T.J. Marks, X. Yang, US Patent 5 500 398, Chem. 1996.
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Marks, T.J.1
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27
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0010165324
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2 of similar structure to 1 produced essentially atactic polypropylene. See [12]. Complex 5 also gave atactic polyhexene
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2 of similar structure to 1 produced essentially atactic polypropylene. See [12]. Complex 5 also gave atactic polyhexene.
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28
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0010161807
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31
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4243833068
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We previously described the preparation of 5 and the propylene polymerization with it in a patent. JP93-202124 (Kokai Tokkyo Koho)
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We previously described the preparation of 5 and the propylene polymerization with it in a patent. JP93-202124 (Kokai Tokkyo Koho); Chem. Abstr. 120: 55292y.
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Chem. Abstr.
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University of York
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P. Main, S.E. Hull, L. Lessinger, G. Germain, J.P. Decerq, M.M. Woolfson, MULTAN 78, University of York, 1978.
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