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(b) R.J.P. Corriu, C. Guérin, J.J.E. Moreau, in: E.L. Eliel, S.H. Wielen, N.L. Allinger (Eds.) Topics in Stereochemistry, vol. 15, 1984, pp 43-198;
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(d) E.F. Perozzi, R.S. Michalak, G.D. Figuly, W.H. Stevenson, D.B. Dess, M.R. Ross, J.C. Martin, J. Org. Chem. 46 (1981) 1049-1053.
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(b) Academic Press, Butterworths, New York
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(b) C. Eaborn, Organosilicon Compounds, Academic Press, Butterworths, New York, 1960;
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Eaborn, C.1
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(f) J.Y. Corey, E.R. Corey, V.H.T. Chang, M.A. Hauser, M.A. Leiber, T.E. Reinsel, M.E. Riva, Organometallics 3 (1984) 1051;
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(g) R.L. Kreeger, P.R. Menard, E.A. Sans, H. Shechter, Tetrahedron Lett. 26 (1985) 1115-1118;
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16
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0002348766
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(a) For reviews, see: in: G.L. Larson (Ed.) Jai Press, Greenwich
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For reviews, see: (a) P.F. Hudrlik, A.H. Hudrlik, in: G.L. Larson (Ed.), Advances in Silicon Chemistry, vol. 2, Jai Press, Greenwich, 1993, p. 1;
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Advances in Silicon Chemistry
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Hudrlik, P.F.1
Hudrlik, A.H.2
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0001329712
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(b) in: S. Patai, Z. Rappoport (Eds.) John Wiley, Chichester
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(b) A.R. Bassindale, P.G. Taylor, in: S. Patai, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds, John Wiley, Chichester, 1989, p. 893-964. P. Jankowski, S. Marczak, M. Masnyk, J. Wicha, J. Organomet. Chem. 403 (1991) 49-62.
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Bassindale, A.R.1
Taylor, P.G.2
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18
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0010195670
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(b)
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(b) A.R. Bassindale, P.G. Taylor, in: S. Patai, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds, John Wiley, Chichester, 1989, p. 893-964. P. Jankowski, S. Marczak, M. Masnyk, J. Wicha, J. Organomet. Chem. 403 (1991) 49-62.
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Jankowski, P.1
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(a) P.F. Hudrlik, D. Ma, R.S. Bhamidipati, A.M. Hudrlik, J. Org. Chem. 61 (1996) 8655-8658;
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Hudrlik, P.F.1
Ma, D.2
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22
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0000698550
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(b) P.F. Hudrlik, Y.M. Abdallah, A.K. Kulkarni, A.H. Hudrlik, J. Org. Chem. 57 (1992) 6552-6556.
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Hudrlik, P.F.1
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Hudrlik, A.H.4
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23
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0025837982
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(a) An alkyl group migration has been noted in a silacyclobutane
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(a) An alkyl group migration has been noted in a silacyclobutane, K. Matsamuto, Y. Takeyama, K. Oshima, K. Utimoto, Tetrahedron Lett. 32 (1991) 4545-4548;
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Tetrahedron Lett.
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Matsamuto, K.1
Takeyama, Y.2
Oshima, K.3
Utimoto, K.4
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24
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37049096701
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(b) For an example of acid-catalysed migration of the phenyl group from silicon to carbon in α,β-epoxysilanes, see
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(b) For an example of acid-catalysed migration of the phenyl group from silicon to carbon in α,β-epoxysilanes, see: I. Fleming, T.W. Newton, J. Chem Soc. Perkin Trans. 1 (1984) 119-123.
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J. Chem Soc. Perkin Trans.
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Fleming, I.1
Newton, T.W.2
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27
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0010094716
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A Chiracel® OD-H analytical column, 0.46(I.D.)×25 cm with a precolumn 0.46×5 cm of Daicel Chemical Industries, Tokyo, Japan, has been used
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A Chiracel® OD-H analytical column, 0.46(I.D.)×25 cm with a precolumn 0.46×5 cm of Daicel Chemical Industries, Tokyo, Japan, has been used.
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28
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18844410382
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(a)
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(a) Y. Gao, R.M. Hanson, J.M. Klunder, S.Y. Ko, H. Masamune, K.B. Sharpless, J. Am. Chem. Soc. 109 (1987) 5765-5780;
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Gao, Y.1
Hanson, R.M.2
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Ko, S.Y.4
Masamune, H.5
Sharpless, K.B.6
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29
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0000830825
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(b) For a review on non-racemic glycidols, see
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(b) For a review on non-racemic glycidols, see: R.M. Hanson, Chem. Rev. 91 (1991) 437-475.
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Chem. Rev.
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Hanson, R.M.1
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30
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0010094492
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20=+38.7
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20=+38.7.
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35
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0002767217
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(e)
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(e) Y. Kobayashi, T. Ito, I. Yamakawa, H. Urabe, F. Sato, Synlett (1991) 811-813.
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Synlett
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Kobayashi, Y.1
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Urabe, H.4
Sato, F.5
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36
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0001524306
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For examples of desilylation in acetonitrile, see: and ref. 11a
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For examples of desilylation in acetonitrile, see: D.R. Boyd, G.A. Berchtold, J. Org. Chem. 44 (1979) 468-470 and ref. 11a.
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(1979)
J. Org. Chem.
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Boyd, D.R.1
Berchtold, G.A.2
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37
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0010103327
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Origin of allyl alcohol is not quite clear at the present. Supplementary experiment has shown that γ-(triphenylsily)allyl alcohol undergoes partial desilylation under the applied conditions (in acetonitrile) although, in principle, vinylsilanes are desilylated much slower then epoxysilenes, see ref. 14
-
Origin of allyl alcohol is not quite clear at the present. Supplementary experiment has shown that γ-(triphenylsily)allyl alcohol undergoes partial desilylation under the applied conditions (in acetonitrile) although, in principle, vinylsilanes are desilylated much slower then epoxysilenes, see ref. 14.
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38
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0010094016
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13C NMR spectra, while elemental composition was confirmed by combustion analysis
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13C NMR spectra, while elemental composition was confirmed by combustion analysis.
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41
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0010198159
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20=-34.4
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20=-34.4.
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43
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0010154937
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(b) Please note that in transforming of 12 (R) into 14 (R) inversion of configuration around the silicon atom has occurred
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(b) R.J.P. Corriu, G. Royo, Bull. Soc. Chim. Fr. (1972) 1497-1510. Please note that in transforming of 12 (R) into 14 (R) inversion of configuration around the silicon atom has occurred.
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(1972)
Bull. Soc. Chim. Fr.
, pp. 1497-1510
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Corriu, R.J.P.1
Royo, G.2
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44
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0001892002
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in: J.D. Morrison (Ed.) Academic Press, Orlando Chapter 8
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B.E. Rossiter, in: J.D. Morrison (Ed.), Asymmetric Synthesis, vol. 5, Academic Press, Orlando, 1985, Chapter 8.
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(1985)
Asymmetric Synthesis
, vol.5
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Rossiter, B.E.1
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