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(l) Although levoglucosenone is commercially available from Yuki Kogyo Co., Ltd., we conducted all our experiments on "self-made" material, prepared by pyrolysis of acid-treated newspaper or cellulose.
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15444352165
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note
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Some transfer of the acetate functionality from the 2-to the 3-hydroxyl occurred in this step as well as partial hydrolysis to the diol.
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49
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15444346523
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note
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We believe that the less hindered hydroxyl group at C-2 could be selectively protected to allow deoxygenation at C-3 and then an application of the synthesis described for 7a to the resulting azido alcohol would afford the ring-expanded AZT analogue.
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