Triphenylphosphine/scandium(III) trifluoromethanesulfonate: A new agent for the reformatsky reaction of α-bromo carboxylic acid derivatives with aldehydes

Tetrahedron Letters

Volumn 39, Issue 46, 1998, Pages 8465-8466

  Kagoshima, Hirotaka ^a   Hashimoto, Yukihiko ^a   Saigo, Kazuhiko ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; CARBOXYLIC ACID DERIVATIVE; FLUOROFORM; SCANDIUM;

CHEMICAL REACTION; DIASTEREOISOMER; HYPOTHESIS; PROTON NUCLEAR MAGNETIC RESONANCE; REVIEW; STEREOCHEMISTRY;

EID: 0032512028     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)01862-0     Document Type: Article

References (7)

1. 1. Kagoshima, H.; Hashimoto, Y.; Oguro, D.; Kutsuna, T.; Saigo, K. Tetrahedron Lett. 1998, 39, 1203-1206.
2. 2. Rathke, M. W.; Weipert, P. In Comprehensive Organic Synthesis; Heathcock, C. H. Ed.; Pergamon Press: Oxford, 1991; Vol. 2, pp. 277-299 and references therein.
3. 3. Gage, J. R.; Evans, D. A. Org. Synth. 1990, 68, 83-91.
4. 2, resulted in the formation of the corresponding adduct 5a only in low yields (0-22%) under the condition A.
5. 6
6. 6. (a) Fujita, M.; Hiyama, T. J. Org. Chem. 1988, 53, 5405-5415.
7. (b) Fujita, M.; Hiyama, T. J. Org. Chem. 1988, 53, 5415-5421.