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25. Rubottom reported that a small quantity of lead(II) acetate promoted the rapid conversion of 1 to 2, and the fragmentation process was actually an oxidation reaction involving 2. However, 1 was not hydrolyzed immediately in acetic acid in the presence of PIDA. It is not sure that PIDA reacts with 1 directly, or reacts with a hydrolyzed compound 2.
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26
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27
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30. In aprotic solvents, the reaction of 1 with PIDA in the presence of TfOH afforded complex mixtures.
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