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See, for example: (a) McLain, S. J.; Schrock, R. R.; Sharp, P. R.; Churchill, M. R.; Youngs, W. J. J. Am. Chem. Soc. 1979, 101, 263. (b) Bennett, M. A.; Hambley, T. W.; Roberts, N. K.; Robertson, G. B. Organometallics 1985, 4, 1992. (c) Buchwald, S. L.; Watson, B. T.; Huffman, J. C. J. Am. Chem. Soc. 1986, 108, 7411. (d) Buchwald, S. L.; Nielsen, R. B. Chem. Rev. 1988, 88, 1047.
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See, for example: (a) McLain, S. J.; Schrock, R. R.; Sharp, P. R.; Churchill, M. R.; Youngs, W. J. J. Am. Chem. Soc. 1979, 101, 263. (b) Bennett, M. A.; Hambley, T. W.; Roberts, N. K.; Robertson, G. B. Organometallics 1985, 4, 1992. (c) Buchwald, S. L.; Watson, B. T.; Huffman, J. C. J. Am. Chem. Soc. 1986, 108, 7411. (d) Buchwald, S. L.; Nielsen, R. B. Chem. Rev. 1988, 88, 1047.
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See, for example: (a) McLain, S. J.; Schrock, R. R.; Sharp, P. R.; Churchill, M. R.; Youngs, W. J. J. Am. Chem. Soc. 1979, 101, 263. (b) Bennett, M. A.; Hambley, T. W.; Roberts, N. K.; Robertson, G. B. Organometallics 1985, 4, 1992. (c) Buchwald, S. L.; Watson, B. T.; Huffman, J. C. J. Am. Chem. Soc. 1986, 108, 7411. (d) Buchwald, S. L.; Nielsen, R. B. Chem. Rev. 1988, 88, 1047.
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0001663347
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Triple-decker complexes typically contain between 30 and 34 valence electrons. For a treatment of their MO schemes, see: Lauher, J. W.; Elian, M.; Summerville, R. H.; Hoffman, R. J. Am. Chem. Soc. 1976, 98, 3219.
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17344362189
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A structure search of the Cambridge Structure Database on the B = N fragment revealed a mean distance for this bond of 1.38(4) Å.
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A structure search of the Cambridge Structure Database on the B = N fragment revealed a mean distance for this bond of 1.38(4) Å.
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34
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