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1
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0029087780
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and references therein
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Wei, A.; Boy, K. M.; Kishi, Y. J. Am. Chem. Soc. 1995, 117, 9432 and references therein.
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Wei, A.1
Boy, K.M.2
Kishi, Y.3
-
2
-
-
3643132242
-
-
note
-
The term exo-anomeric conformation is used to describe the conformation of O-or C-glycosidic bond with the glycosidic oxygen or carbon being anti-periplanar to the C.1-C.2 bond.
-
-
-
-
3
-
-
0029085163
-
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(a) Espinosa, J.-F.; Martín-Pastor, M.; Asensio, J. L.; Dietrich, H.; Martín-Lomas, M.; Schmidt, R. R.; Jiménez-Barbero, J. Tetrahedron Lett. 1995, 36, 6329.
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Tetrahedron Lett.
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Espinosa, J.-F.1
Martín-Pastor, M.2
Asensio, J.L.3
Dietrich, H.4
Martín-Lomas, M.5
Schmidt, R.R.6
Jiménez-Barbero, J.7
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4
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-
33748219796
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(b) Espinosa, J.-F.; Cañada, F. J.; Asensio, J. L.; Dietrich, H.; Martín-Lomas, M.; Schmidt, R. R.; Jiménez-Barbero, J. Angew. Chem., Int. Ed. Engl. 1996, 35, 303.
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Angew. Chem., Int. Ed. Engl.
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Espinosa, J.-F.1
Cañada, F.J.2
Asensio, J.L.3
Dietrich, H.4
Martín-Lomas, M.5
Schmidt, R.R.6
Jiménez-Barbero, J.7
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5
-
-
0029846624
-
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(c) Espinosa, J.-F.; Cañada, F. J.; Asensio, J. L.; Martín-Pastor, M.; Dietrich, H.; Martín-Lomas, M.; Schmidt, R. R.; Jiménez-Barbero, J. J. Am. Chem. Soc. 1996, 118, 10862.
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Espinosa, J.-F.1
Cañada, F.J.2
Asensio, J.L.3
Martín-Pastor, M.4
Dietrich, H.5
Martín-Lomas, M.6
Schmidt, R.R.7
Jiménez-Barbero, J.8
-
6
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-
0032542581
-
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(d) Espinosa, J.-F.; Montera, E.; Vian, A.; García, J. L.; Dietrich, H.; Schmidt, R. R.; Martín-Lomas, M.; Imberty, A.; Cañada, F. J.; Jiménez-Barbero, J. J. Am. Chem. Soc. 1998, 120, 1309.
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Espinosa, J.-F.1
Montera, E.2
Vian, A.3
García, J.L.4
Dietrich, H.5
Schmidt, R.R.6
Martín-Lomas, M.7
Imberty, A.8
Cañada, F.J.9
Jiménez-Barbero, J.10
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7
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4043060026
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Rubinstenn, G.; Sinäy, P.; Berthault, P. J. Phys. Chem. A 1997, 101, 2536.
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Rubinstenn, G.1
Sinäy, P.2
Berthault, P.3
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8
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0001032715
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(a) Goekjian, P. G.; Wu, T.-C.; Kishi, Y. J. Org. Chem. 1991, 56, 6412.
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(1991)
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Goekjian, P.G.1
Wu, T.-C.2
Kishi, Y.3
-
10
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0023612869
-
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Babirad, S. A.; Wang, Y.; Goekjian, P. G.; Kishi, Y. J. Org. Chem. 1987, 52, 4825.
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-
Babirad, S.A.1
Wang, Y.2
Goekjian, P.G.3
Kishi, Y.4
-
11
-
-
84988099658
-
-
All dihedral angles are defined according to the IUPAC Joint Commission on Biochemical Nomenclature (JCBN), symbols for specifying the conformation of polysaccharide chains, 1981 recommendation. Reproduced in Eur. J. Biochem. 1983, 131, 5; φ = O.5′-C.1′-O.4-C.4 and ψ = C.1′-O.4-C.4-C.3.
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(1983)
Eur. J. Biochem.
, vol.131
, pp. 5
-
-
-
12
-
-
3643055079
-
-
note
-
The single-axial-like interaction of C.2′-O.2′/C.a-H is not included in Table 1 because it exists in all the three staggered conformers A-C.
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-
-
-
13
-
-
5844327067
-
-
With an imaginative six-membered ring including O.5′-C.1′-C.a-C.4 on the conformer C, it is seen that the C.5 and C.6 carbons correspond to the quaternary and primary carbons of the terr-butyl group of tert-butylcyclohexane. Thus, the single-axial-like interaction between the C.1′-H and the C.4-C.5-C.6-C.6-H (or OH) is assumed to be roughly represented by 1/2 of the A-value (4.9 kcal/mol) of terf-butylcyclohexane reported by Manoharan, M.; Eliel, E. L. Tetrahedron Lett. 1984, 25, 3267. The single-axial-like interaction of C.4-C.a-C.1′-C.1′-H/C.6-H is the same type of interaction as this. However, since this interaction involves the same protons as the single-axial-like interaction of C.4-C.5/C.1′-H, the steric destabilization is counted only once.
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(1984)
Tetrahedron Lett.
, vol.25
, pp. 3267
-
-
Manoharan, M.1
Eliel, E.L.2
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15
-
-
3643088586
-
-
note
-
5a
-
-
-
-
19
-
-
20444483055
-
-
Haasnoot, C. A. G.; de Leeuw, F. A. A. M.; Altona, C. Tetrahedron 1980, 36, 2783.
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(1980)
Tetrahedron
, vol.36
, pp. 2783
-
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Haasnoot, C.A.G.1
De Leeuw, F.A.A.M.2
Altona, C.3
-
21
-
-
0001531293
-
-
Wang Y.; Goekjian, P. G.; Ryckman, D. M.; Miller, W. H.; Babirad, S. A.; Kishi, Y. J. Org. Chem. 1992, 57, 482.
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J. Org. Chem.
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-
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Wang, Y.1
Goekjian, P.G.2
Ryckman, D.M.3
Miller, W.H.4
Babirad, S.A.5
Kishi, Y.6
-
22
-
-
3643095839
-
-
note
-
2 are an additional example for this general observation.
-
-
-
-
23
-
-
3643094797
-
-
note
-
3OD, 7/3) δ 2.37 (H.4) 3.84. (H.1′), 3.9 (H.5′) 3.96 (H.2), 3.99 (H.3′), 4.11 (H.6), 4.17 (H.6′), 4.20 (H.5), 4.21 (H.2′), 4.29 (H.3), 4.34 (H.6), 4.37 (H.6′), 4.40 (H.4′), 5.11 (H.1).
-
-
-
-
24
-
-
3643066626
-
-
note
-
4 for the conformational study of the aglyconic bond. The synthesis of these substrates and the NOESY spectrum are included in Supporting Information.
-
-
-
-
26
-
-
0027511368
-
-
For example, see: Peters, T.; Meyer, B.; Stuike-Prill, R.; Somorjai, R.; Brisson, I.-R. Carbohydr. Res. 1993, 243, 49.
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Carbohydr. Res.
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, pp. 49
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Peters, T.1
Meyer, B.2
Stuike-Prill, R.3
Somorjai, R.4
Brisson, I.-R.5
-
27
-
-
3643093655
-
-
note
-
3OD, 7/3) δ 4.02 (H.2), 4.06 (H.5), 4.07 (H.3′), 4.08 (H.5′), 4.15 (H.4), 4.29 (H.6′), 4.35 (H.6), 4.38 (H.6′), 4.4 (H.2′), 4.41 (H.3), 4.43 (H.6), 4.43 (H.4′), 5.0 (H.1′), 5.04 (H.1).
-
-
-
-
28
-
-
3643062426
-
-
For example, see the discussion given in ref 4
-
For example, see the discussion given in ref 4.
-
J. Phys. Chem. A
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-
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29
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0029997826
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(a) Banerjee, R.; Das, K.; Ravishankar, R.; Suguna, K.; Surolia, A.; Vijayan M. J. Mol. Biol. 1996, 259, 281.
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Banerjee, R.1
Das, K.2
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Suguna, K.4
Surolia, A.5
Vijayan, M.6
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30
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0027958144
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(b) Liao, D. I.; Kapadia, G.; Ahmed, H.; Vasta, G. R.; Herzberg, O. Proc. Natl. Acad. Sci. U.S.A. 1994, 91, 1428.
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Liao, D.I.1
Kapadia, G.2
Ahmed, H.3
Vasta, G.R.4
Herzberg, O.5
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31
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0027754166
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(c) Lobsanov, Y. D.; Gitti, M. A.; Leffler, H.; Barondes, S. H.; Rini, J. M. J. Biol. Chem. 1993, 268, 27034.
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Rini, J.M.5
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32
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0026598947
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(d) Sixma, T. K.; Pronk, S. E.; Kalk, K. H.; van Zanten, B. A. M.; Berghuis, A. M.; Hol, W. G. J. Nature 1992, 355, 561.
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Sixma, T.K.1
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Kalk, K.H.3
Van Zanten, B.A.M.4
Berghuis, A.M.5
Hol, W.G.J.6
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33
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0026337737
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(e) Shaanan, B.; Lis, H.; Sharon, N. Science 1991, 254, 862.
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Science
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Shaanan, B.1
Lis, H.2
Sharon, N.3
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34
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0023654540
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-
(f) Montfort, W.; Villafranca, J. E.; Monzingo, A. F.; Ernst, S. R.; Katzin, B.; Rutenber, E.; Xuong, N. H.; Hamlin, R.; Robertus, J. D. J. Biol. Chem. 1987, 262, 5398.
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Montfort, W.1
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Monzingo, A.F.3
Ernst, S.R.4
Katzin, B.5
Rutenber, E.6
Xuong, N.H.7
Hamlin, R.8
Robertus, J.D.9
-
35
-
-
3643086465
-
-
note
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24b
-
-
-
-
36
-
-
3643124951
-
-
note
-
24a
-
-
-
-
37
-
-
3643131215
-
-
note
-
The φ and ψ values given here are averaged over the four subunits of the protein.
-
-
-
-
38
-
-
3643079156
-
-
note
-
4 searched for the best agreement between experimental and back-calculated NOE distances, resulting in two refined structures with φ = 295°/ψ = 130° and φ = 295°/ψ = 300°.
-
-
-
-
39
-
-
0000667775
-
-
The conformation of O-lactose bound to peanut lectin is well compared with the crystal structure (φ = 266°; ψ = 95°) of O-lactose monohydrate: Beevers, C. A.; Hans, N. H. Acta Crystallogr. 1971, B27, 1323-1325.
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(1971)
Acta Crystallogr.
, vol.B27
, pp. 1323-1325
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Beevers, C.A.1
Hans, N.H.2
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43
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0002444999
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Diamond, R., Ramaseshan, S., Venkatesan, K., Eds.; Indian Academy of Sciences: Bangalore
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Vijayan, M. In Computing in Crystallography; Diamond, R., Ramaseshan, S., Venkatesan, K., Eds.; Indian Academy of Sciences: Bangalore, 1980, 19.01-19.26.
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Computing in Crystallography
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Vijayan, M.1
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46
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0000243829
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Laskowski, R. A.; MacArthur, M. W.; Moss, D. S.; Thornton, J. M. J. Appl. Crystallogr. 1993, 26, 283-291.
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Laskowski, R.A.1
MacArthur, M.W.2
Moss, D.S.3
Thornton, J.M.4
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