Use of allylic trifiones for allylation of C-H bonds

Tetrahedron Letters

Volumn 39, Issue 24, 1998, Pages 4163-4166

  Xiang, Jason ^a   Evarts, Jerry ^a   Rivkin, Alexey ^b   Curran, Dennis P ^b   Fuchs, P L ^a  

^a PURDUE UNIVERSITY   (United States)

^b UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; CYCLOHEXANE; RADICAL; TETRAHYDROFURAN; TRIFLONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; DRUG SYNTHESIS; ELECTRON; REACTION ANALYSIS;

EID: 0032508091     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00775-8     Document Type: Article

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24. 12. The impure triflone from the reaction with the potassium salt seems to contain an inhibitor. Its reactions are very slow and provide large amounts of the non-chain adduct derived from addition of isobutyronitrile radical (from the AIBN). Distillation followed by flash chromatography gives pure 6, which is well behaved in the additions.
25. 13. The following alkenes provided no adducts in reactions with cyclohexane: (Formula Presented)