Alkene complexes of divalent and trivalent ruthenium stabilized by chelation. Dependence of coordinated alkene orientation on metal oxidation state

Journal of the American Chemical Society

Volumn 120, Issue 5, 1998, Pages 932-941

  Bennett, Martin A ^a   Heath, Graham A ^a   Hockless, David C R ^a   Kovacik, Ivan ^a   Willis, Anthony C ^a  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; AMALGAM; ANILINE DERIVATIVE; DIVALENT CATION; IRON DERIVATIVE; METAL OXIDE; RUTHENIUM; SILVER; VINYL DERIVATIVE; ZINC;

ARTICLE; CHELATION; CYCLIC POTENTIOMETRY; DIASTEREOISOMER; MOLECULAR STABILITY; OXIDATION; TEMPERATURE; ULTRAVIOLET SPECTROSCOPY;

EID: 0032506986     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973282k     Document Type: Article

References (72)

1. Gates, B. C.; Katzer, J. R.; Schuit, G. C. A. Chemistry of Catalytic Processes; McGraw-Hill: New York, 1979; p 160.
2. Boor, J., Jr. Ziegler-Natta Catalysts and Polymerizations; Academic: New York, 1979; p 266.
3. Gavens, P. D.; Bottrill, M.; Kelland, J. W.; McMeeking, J. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, 1982; pp 488-502.
4. Interrante, L. V.; Nelson, G. V. J. Organomet. Chem. 1970, 25, 153.
5. Fachinetti, G.; Del Nero, S.; Floriani, C. J. Chem. Soc., Dalton Trans. 1976, 1046.
6. Fachinetti, G.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1979, 18, 2282.
7. Morán, M.; Santos-Garcia, J. J.; Masaguer, J. R.; Fernández, V. J. Organomet. Chem. 1985, 295, 327.
8. Hoberg, H.; Jenni, K.; Angermund, K.; Krüger, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 153.
9. Klein, H.-F. Angew Chem., Int. Ed. Engl. 1980, 19, 362.
10. Klein, H.-F.; Gross, J.; Bassett, J.-M.; Schubert, U. Z. Naturforsch. B 1980, 35, 614.
11. Klein, H.-F.; Gross, J.; Witty, H.; Neugebauer, D. Z. Naturforsch. B 1984, 39, 643.
12. Kubo, Y.; Pu, L.-S.; Yamamoto, A.; Ikeda, S. J. Organomet. Chem. 1975, 84, 369.
13. Agnes, G.; Bassi, I. W.; Benedicenti, C.; Intrito, R.; Calcaterra, M.; Santini, C. J. Organomet. Chem. 1977, 129, 401.
14. Porri, L.; Vitulli, G.; Gallazzi, M. C. Angew. Chem., Int. Ed. Engl. 1967, 6, 452.
15. Hoberg, H.; Radine, K.; Krüger, C.; Romão, M. J. Z. Naturforsch. B 1985, 40, 607.
16. (a) Bennett, M. A.; Bruce, M. I.; Matheson, T. W. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, 1982; Vol. 4, p 741.
17. (b) Bennett, M. A. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Shriver, D. F., Bruce, M. I., Vol. Ed.; Pergamon: Oxford, 1995; Vol. 7, p 441.
18. Lehmann, H.; Schenk, K. J.; Chapuis, G.; Ludi, A. J. Am. Chem. Soc. 1979, 101, 6197.
19. Elliott, M. G.; Shepherd, R. E. Inorg. Chem. 1988, 17, 3332.
20. Elliott, M. G.; Zhang, S.; Shepherd, R. E. Inorg. Chem. 1989, 28, 3036.
21. Harman, W. D.; Taube, H. J. Am. Chem. Soc. 1988, 110, 7906.
22. Laurenczy, G.; Merbach, A. E. J. Chem. Soc., Chem. Commun. 1993, 187.
23. Novak, B. M.; Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542.
24. McGrath, D. V.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1991, 113, 3611.
25. Bennett, M. A.; Chung, G.; Neumann, H., to be published.
26. Wallace, L. Ph.D. Thesis, Australian National University, Canberra; 1991.
27. Hall, D. I.; Ling, J. H.; Nyholm, R. S. Struct. Bonding 1973, 15, 3.
28. Duff, C. M.; Heath, G. A. Inorg. Chem. 1991, 30, 2528;
29. J. Chem. Soc., Dalton Trans. 1991, 2401.
30. Brauer, G. Handbook of PreparatiVe Inorganic Chemistry; Academic: New York, 1965; Vol. 2, p 1806.
31. Brauer, G. Handbuch der Präparativen Anorganischen Chemie; Ferdinand Enke: Stuttgart, 1981; Vol. 3, p 1845.
32. Gordon, J. G. II; O'Connor, M. J.; Holm, R. H. Inorg. Chim. Acta 1971, 5, 381.
33. Earley, J. E.; Base, R. N.; Berrie, B. H. Inorg. Chem. 1983, 22, 1836.
34. Knowles, T. S.; Howells, M. E.; Howlin, B.; Smith, G. W.; Amodio, C. A. Polyhedron 1994, 13, 2197.
35. Booth, H.; King, F. E.; Parrick, J. J. Chem. Soc. 1958, 2302.
36. Angermund, K.; Bogdanovic, B.; Koppetsch, G.; Krüger, C.; Mynott, R.; Schwickardi, M.; Tsay, Y. H. Z. Naturforsch., B 1986, 41, 455.
37. (a) Troyanowsky, C. Bull. Soc. Chim. Fr. 1955, 420.
38. (b) Yingst, R. E.; Douglas, B. E. Inorg. Chem. 1964, 3, 1177.
39. (c) Israeli, M.; Laing, D. K.; Pettit, L. D. J. Chem. Soc., Dalton Trans. 1974, 2194.
40. (d) Heaton, B. T.; McCaffrey, D. J. A. J. Chem. Soc., Dalton Trans. 1979, 1078.
41. Stross, F. H.; Monger, J. M.; Finch, H. de V. J. Am. Chem. Soc. 1947, 69, 1627.
42. Redeuilh, G.; Rumpf, P.; Viel, C. Bull. Soc. Chim. Fr. 1973, 2665.
43. Atkinson, C. M.; Simpson, J. C. E. J. Chem. Soc. 1947, 808.
44. Baeyer, A. Ber. 1905, 38, 2759.
45. teXsan: Single-Crystal Structure Analysis Software, Versions 1.6c and 1.7; Molecular Structure Corp.: The Woodlands, TX, 1993 and 1995.
46. Cromer, D. T.; Waber, J. T. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1974; Vol IV.
47. International Tables for Crystallography; Kluwer Academic: Boston, MA, 1992; Vol. C, Tables 4.2.4.3 and 4.2.6.8.
48. Fan, Hai-Fu. SAPI 91. Structure Analysis Programs with Intelligent Control; Rigaku Corporation, Tokyo, Japan, 1991.
49. Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.; Garcia-Granda, S.; Gould, R. O.; Smits, J. M. M.; Smykalla, C. The DIRDIF-92 Program System. Technical Report of the Crystallography Laboratory; University of Nijmegen, The Netherlands, 1992.
50. Kobayashi, T.; Nishina, Y.; Shimizu, K.; Sato, G. P. Chem. Lett. 1988, 1137.
51. Ernst, R. D.; Meléndez, E.; Stahl, L.; Ziegler, M. L. Organometallics 1991, 10, 3635.
52. Meléndez, E.; Ilarraza, R.; Yap, G. P. A.; Rheingold, A. L. J. Organomet. Chem. 1996, 522, 1.
53. Bennett, M. A.; Neumann, H.; Willis, A. C.; Ballantini, V.; Pertici, P.; Mann, B. E. Organometallics 1997, 16, 2868.
54. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd ed.; Wiley: New York, 1978; p 249.
55. Parshall, G. W.; Wilkinson, G. Inorg. Chem. 1962, 1, 896.
56. Gillard, R. D.; Heaton, B. T.; Pilbrow, M. F. J. Chem. Soc. A 1970, 353.
57. Paiaro, G.; Panunzi, A. J. Am. Chem. Soc. 1964, 86, 5148.
58. Figgis, B. N.; Lewis, J.; Mabbs, F. E.; Webb, G. A. J. Chem. Soc. A 1966, 422.
59. Buschbeck, C.; Hartmann, H. Z. Phys. Chem. (Frankfurt) 1957, 11, 120.
60. De Simone, R. E. J. Am. Chem. Soc. 1973, 95, 6238.
61. Matsuzawa, H.; Ohashi, Y.; Kaizu, Y.; Kobayashi, H. Inorg. Chem. 1988, 27 2981.
62. Knowles, T. S.; Howlin, B. J.; Jones, J. R.; Povey, D. C.; Amodio, C. A. Polyhedron 1993, 12, 2921.
63. Smith, D. E. Electroanal. Chem. 1966, 1, 1.
64. (a) Taube, H. Pure Appl. Chem. 1979, 51, 901; 1991, 63, 651.
65. (b) Taube, H. Comments Inorg. Chem. 1981, 1, 17.
66. Connelly, N. G.; Metz, B.; Orpen, A. G.; Rieger, P. H. Organometallics 1996, 15, 729.
67. Harman, W. D.; Wishart, J. F.; Taube, H. Inorg. Chem. 1989, 28, 2411.
68. Bartlett, I. M.; Connelly, N. G.; Orpen, A. G.; Quayle, M. J.; Rankin, J. C. Chem. Commun. 1996, 2583.
69. Wang, L.-S.; Fettinger, J. C.; Poli, R. J. Am. Chem. Soc. 1997, 119, 4453.
70. Bennett, M. A.; Heath, G. A.; Kovacik, I.; Willis, A. C. unpublished work.
71. Yamamoto, A. Organotransition Metal Chemistry: Fundamental Concepts and Applications; Wiley: New York, 1986; pp 312-315.
72. Suzuki, T.; Takegami, Y. Bull. Chem. Soc. Jpn. 1970, 43, 1484.