Redox control of sulfur degassing in silicic magmas

Journal of Geophysical Research: Solid Earth

Volumn 103, Issue 10, 1998, Pages 23937-23949

  Scaillet, Bruno ^a   Clemente, Béatrice ^a   Evans, Bernard W ^b   Pichavant, Michel ^a  

^a CNRS   (France)

^b UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEGASSING; MAGMA; REDOX CONDITIONS; SILICATE MELT; SULFUR;

EID: 0032505852     PISSN: 21699313     EISSN: 21699356     Source Type: Journal    
DOI: 10.1029/98jb02301     Document Type: Article

References (90)

1. Albarède, A., Introduction to Geochemical Modeling, Cambridge Univ. Press, New York, 1995.
2. 2, Cl, and gas in Plinian and ash-flow Bishop rhyolite, Geology, 17, 221-225, 1989.
3. Andres, R.J., W.I. Rose, P.R. Kyle, S. DeSilva, P. Francis, M. Gardeweg, and H. Moreno Roa, Excessive sulfur dioxide emissions from Chilean volcanoes, J. Volcanol. Geotherm. Res., 46, 323-329, 1991.
4. Baker, L.L., and M.J. Rutherford, Sulfur diffusion in rhyolitic melts, Contrib. Mineral. Petrol., 123, 335-344, 1996.
5. Beddoe-Stephens, B., J.A. Aspden, and T.J. Sheperd. Glass inclusions and melt compositions of the Toba Tuffs, northern Sumatra, Contrib. Mineral. Petrol., 83, 278-287, 1983.
6. Bernard, A., D. Demaiffc, N Mattieli, and R. Punongbayan, Anhydritebearing pumice from Mount Pinatubo: Further evidence for the existence of sulphur rich silicic magmas, Nature, 354, 139-140, 1991.
7. Blake, S., C.N.J. Wilson, I.E.M. Smith, and G.P.L. Walker. Petrology and dynamics of the Waimihia mixed magma eruption, Taupo volcano, New Zealand, J. Geol. Soc. London, 149, 193-207, 1992.
8. Bluth, G.J.S., C.C. Schnetzer, A.J. Krueger, and L.S. Walter, The contribution of explosive volcanism to global atmospheric sulphur dioxide concentrations, Nature, 366, 327-329, 1993.
9. 2 clouds from the June, 1991 Mount Pinatubo eruptions, Geophys. Res. Lett., 21, 2833-2836, 1994.
10. Carmichael, I S.E., The iron-titanium oxides of salic volcanic rocks and their associated ferromagnesian silicates, Contrib. Mineral. Petrol., 14, 36-64, 1967.
11. Carroll, M.R., and M.J. Rutherford. The stability of igneous anhydrite: Experimental results and implications for sulfur behavior in the 1982 El Chichón trachyandesite and other evolved magmas, J. Petrol., 28, 781-801, 1987.
12. Carroll, M.R., and M.J. Rutherford, Sulfur speciation in hydrous experimental glasses of varying oxidation states. Results from measured wavelength shifts of sulfur x-rays, Am. Mineral., 73, 845-849, 1988.
13. Casadevall, T.J., M.P. Doukas, C.A. Neal. R.G. McGimsey, and C.A. Gardner. Emission rates of sulfur dioxide from Redoubt volcano. Alaska during the 1989-1990 eruptions, J. Volcanol. Geotherm. Res., 62, 519-530, 1994.
14. Chesner. C.A., Petrogenesis of the Toba Tuffs, Sumatra, Indonesia, J. petrol., 39, 397-438, 1998.
15. Chesner, C.A., W.I. Rose, A. Deino, R. Drake, and J.A. Westgate, Eruptive history of Earth's largest Quaternary caldera (Toba, Indonesia) clarified, Geology, 19, 200-203, 1991.
16. Clemente B., B. Scaillet, and M. Pichavant, Sulfur solubility in arcmagmas, Terra Nova, 9, 473, 1997.
17. Devine. J.D., H Sigurdsson. and A.N. Davis. Estimates of sulfur and chlorine yield to the atmosphere from volcanic eruptions and potential climatic effects, J. Geophys. Res., 89, 6309-6325, 1984.
18. 2O contents of silicic volcanic glasses. Am. Mineral., 73, 845-859, 1995.
19. Dunbar. N. W., P.R. Kyle, and C.N.J. Wilson. Evidence for limited zonation in silicic magma systems, Taupo volcanic zone, New Zealand, Geology, 17, 234-236, 1989
20. Evans, B.W., and M. Ghiorso. Thermodynamics and petrology of cummingtonite, Am. Mineral., 80, 649-663, 1995.
21. Evans, B. W.. and B. Scaillet, The redox state of Pinatubo dacite and the ilmenite-hematite solvus, Am. Mineral., 82, 625-629, 1997.
22. Fierstein, J., and W. Hildreth, The Plinian eruptions of 1912 at Novarupta, Katmai National Park, Alaska, Bull. Volcanol., 54, 646-684, 1992
23. Fournelle, J., Anhydrite in Nevado del Ruiz November 1985 pumice: Relevance to the sulfur problem, J. Volcanol. Geotherm. Res., 42, 189-201, 1990
24. 2, and S during eruptive episodes at Kilauea volcano, Hawaii, J. Geophys. Res., 91, 12177-12185, 1986.
25. Gerlach, T.M., and K.A. McGee, Total sulfur dioxide emissions and pre-eruption vapor-saturated magma at Mount St. Helens, 1980-88, Geophys. Res. Lett., 21, 2833-2836, 1994.
26. Gerlach, T.M., H.R. Westrich, T.J. Casadcvall, and D.L. Finnegan, Vapor saturation and accumulation in magmas of the 1989-1990 eruption of Redoubt volcano, Alaska. J. Volcanol. Geotherm., Res. 62, 317-337, 1994.
27. Gerlach, T.M., H.R. Westrich. and R.B Symonds, Pre-eruption vapor in magma of the climactic Mount Pinatubo eruption: Source of the giant stratospheric sulfur dioxide cloud, in Fire and Mud. Eruptions and Lahars of Mount Pinatubo, edited by C.G. Newhall and R. Punongbayan. pp. 415-434 , Univ. of Wash. Press, Seattle, 1996.
28. Ghiorso, M.S., and R.O. Sack, Fe-Ti oxide geothermometry: Thermodynamic formulation and the estimation of intensive variables in silicic magmas, Contrib. Mineral. Petrol., 108, 485-510, 1991.
29. Gourgaud, A., and J.C. Thouret, Magma mixing and petrogenesis of the 13 November 1985 eruptive products at Nevado del Ruiz (Colombia), J. Volcanol. Geotherm. Res., 42, 79-96, 1990.
30. Hammer, C. U., H.B Clausen, and W. Dansgaard, Greenland ice sheet evidence of post-glacial volcanism and its climatic impact, Nature, 288, 230-235, 1980.
31. Hansen, J., A. Lacis, R. Ruedy, and M. Sato, Global surface temperature in 1995: Return to pre-Pinatubo level, Geophys. Res. Lett., 23, 1665-1668, 1996.
32. Harington. C.R., The Year Without a Summer? World Climate in 1816, 576 pp., Can. Mus. Of Nat., Ottawa, 1992.
33. Haughton, D.R., P.L. Roeder. and B.J. Skinner, Solubility of sulfur in mafic magmas, Econ. Geol., 69, 451-467, 1974.
34. Hildreth, W., The Bishop Tuff: Evidence for the origin of compositional Zonation in silicic magma chambers, Spec. Pap. Geol. Soc. Am., 180, 43-75, 1979.
35. Hildreth, W., The compositionally zoned eruption of 1912 in the valley of Ten Thousand Smokes, Katmai National Park, Alaska, J. Volcanol. Geotherm. Res., 18, 1-56, 1983.
36. Holloway, J.R., Fugacity and activity of molecular species in supercritical fluids, in Thermodynamics in Geology, edited by D.G. Fraser, pp. 161-181, D. Reidel, Norwell, Mass., 1977.
37. Johnson, M. C., and M.J. Rutherford, Experimentally determined conditions in the Fish Canyon tuff, Colorado, magma chamber, J. Petrol., 30, 711-737, 1989.
38. Kress, V., Magma mixing as a source for Pinatubo sulfur, Nature , 389, 591-593, 1997.
39. Krueger, A.J., L.S. Walter, P.K. Bhartia, C.C. Schnetzler, N.A. Krotkov, I. Sprod, and G.J.S. Bluth, Volcanic sulfur dioxide measurements from the total ozone mapping spectrometer instruments, J. Geophys. Res., 100, 14057-14076, 1995.
40. 4 in the Antarctic ice sheet. Nature, 327, 671-676, 1987.
41. Luhr, J.F., Experimental phase relations of water- and sulfur-saturated arc magmas and the 1982 eruptions of El Chichón volcano, J. Petrol., 31, 1071-1114, 1990.
42. Luhr. J.F., Volcanic shade causes cooling, Nature, 354, 104-105, 1991.
43. Luhr. J.F., I.S.E. Carmichael, and J.C. Varekamp. The 1982 eruptions of El Chichón volcano, Chiapas. Mexico: Mineralogy and petrology of the anhydrite-bearing pumices, J. Volcanol. Geotherm. Res., 23, 69-108, 1984.
44. Mandeville, C. W., S. Carey. and H. Sigurdsson, Magma mixing. fractional crystallization and volatile degassing during the 1883 eruption of Krakatau volcano, Indonesia, J. Volcanol. Geotherm. Res., 74, 243-274, 1996.
45. Matthews. S.J., A.P. Jones, and C.S. Bristow, A simple magma mixing model for sulphur behaviour in calc-alkaline volcanic rocks: Mineralogical evidence from Mount Pinatubo 1991 eruption, J. Geol. Soc. London, 149, 863-866, 1992.
46. Metrich, N., and R. Clochiatti, Sulfur abundance and its specialion in oxidized alkaline melts. Geochim. Cosmochim. Acta, 60, 4151-4160, 1996.
47. 2 and sulfur degassing,Contrib. Mineral. Petrol., 107, 435-447 1991.
48. Moore, J.G., and B.P. Fabbi, An estimate of the juvenile sulfur content of basalt, Contrib. Mineral. Petrol., 33, 118-127, 1971.
49. Nilsson, K., and C.L. Peach, Sulfur speciation, oxidation state, and sulfur concentration in backarc magmas, Geochim. Cosmochim. Acta, 57, 3807-3813, 1993.
50. Palais, J. M., and H. Sigurdsson. Petrologic evidence of volatile emissions from major historic and pre-historic volcanic eruptions, in Understanding Climate Change, Geophys. Monog. Ser. vol. 52, edited by A.L. Berger, R.E. Dickinson, and J. Kidson. pp. 31-53, AGU, Washington, D.C.., 1989.
51. Pallister. J.S., R.P. Hoblitt, and A.G. Reyes, A basalt trigger for the 1991 eruptions of Pinatubo volcano, Nature, 356, 426-428, 1992.
52. Pallister, J.S., R.P. Hoblitt, G.P. Meeker, C.G Newhall, R.J. Knight, and D.F. Siems, 1996. Magma mixing at Mount Pinatubo volcano: Petrographical and chemical evidence from the 1991 deposits, in Fire and Mud: Eruptions and Lahars of Mount Pinatubo, edited by C.G. Newhall and R. Punongbayan, pp. 687-732 , Univ. of Wash. Press, Seattle, 1996.
53. Rampino, M. R., and S. Self, Sulphur-rich volcanic eruptions and stratospheric aerosols, Nature, 310, 677-679, 1984.
54. Rampino, M. R., and S. Self, Volcanic winter and accelerated glaciation following the Toba super-eruption, Nature, 359, 50-52, 1992.
55. Rampino, M.R., R.B. Stothers, and S. Self, Climatic effects of volcanic eruptions, Nature, 313, 272, 1985.
56. Rampino, M.R., S. Self, and R.B. Stothers, Volcanic winters. Annu. Rev. Earth Planet. Sci., 16, 73-99, 1988.
57. Rose, W. I., Santa Maria, Guatemala: Bimodal, soda-rich calc-alkalic stratovolcano, J. Volcanol. Geotherm. Res., 33, 109-129, 1987.
58. Rose, W. I., and C.A. Chesner, Dispersal of ash in the great Toba eruption, 75 ka, Geology, 15, 913-917, 1987.
59. Rutherford, M. J., and J. Devine, The May 18, 1980, eruption of Mount St. Helens, 3, Stability and chemistry of amphibole in the magma chamber, J. Geophys. Res., 93, 11949-11959, 1988.
60. Rutherford. M.J., and J. Devine, Pre-eruption pressure-temperature conditions and volatiles in the 1991 dacitic magma of Mount Pinatubo, in Fire and Mud: Eruptions and Lahars of Mount Pinatubo, edited by C. Newhall and R. Punongbayan, pp.751-766 , Univ. of Wash. Press, Seattle, 1996.
61. 2O conditions of the dacite magma, J. Petrol., in press, 1998.
62. 2 at high temperatures and pressures, Am. Mineral., 77, 647-655, 1992.
63. 2, in cold seal pressure vessels with the Shaw membrane technique, Eur. J. Mineral., 7, 893-903, 1995.
64. Schnetzer, C.C., G.J.S. Bluth, A.J. Krueger, and L.S. Walter, A proposed volcanic sulfur index (VSI), J. Geophys. Res., 102, 20087-20091, 1997.
65. Self, S., and A.J. King, Petrology and sulfur and chlorine emissions of the 1963 eruption of Gunung Agung, Bali, Indonesia, Bull. Volcanol., 58, 263-285, 1996.
66. Self, S., Rampino, M.R., Newton, M.S., and Wolff, J.A., Volcanological study of the great Tambora eruption of 1815, Geology, 12, 659-663, 1984.
67. Sigurdsson, H., S. Carey, J.M. Palais, and J. Devine, Pre-eruption compositional gradients and mixing of and andesite and dacite erupted from Nevado del Ruiz volcano, Colombia in 1985, J. Volcanol. Geotherm. Res., 42, 127-151, 1990.
68. 2O in calc-alkaline differentiation and subduction zone magmatism, Contrib. Mineral Petrol., 113, 143-166, 1993.
69. Stothers R.B., The great Tambora eruption and its aftermath, Science, 224, 1191-1198, 1984.
70. Swanson, S. E., C.J. Nye, T.P. Miller, and V.F. Avery, Geochemistry of the 1989-1990 eruption of Redoubt volcano, II, Evidence from mineral and glass chemistry, J. Volcanol Geotherm. Res., 62, 453-468, 1994.
71. Symmonds, R. B., W.I. Rose, G.J.S. Bluth, and T.M. Gerlach, Volcanicgas studies: Methods, results, and applications, inVolatiles in Magmas, Rev. Mineral., vol. 30, edited by M.R. Carroll and J.R. Holloway, pp. 1-66, Am. Mineral. Soc., Washington, D.C., 1994.
72. Toulmin, P., and P.B. Barton Jr., A thermodynamic study of pyrite and pyrrhotite, Geochim. Cosmochim. Acta. 28, 641-671, 1964.
73. Tracy, R.J., and P. Robinson. Silicate-sulfide-oxide-fluid reactions in granulite-grade pelitic rocks, central Massachusetts, Am. J. Sci., 288-A, 45-74, 1988.
74. Varekamp, J.C., J.F. Luhr, and K.L. Prestegaard, The 1982 eruptions of El Chichón volcano (Chiapas, Mexico): Character of the eruptions, ash-fall deposits, and gasphase, J. Volcanol. Geotherm. Res., 23, 39-68, 1984.
75. Walker, G. P. L., The Taupo pumice: Product of the most powerful (ultra-Plinian) eruption?, J. Volcanol. Geotherm. Res., 8, 69-94, 1980.
76. Wallace, P.J., and I.S.E. Carmichael, S speciation in submarine basaltic glasses as determined by measurements of SKa X-ray wavelength shifts, Am. Mineral., 79, 161-167, 1994.
77. Wallace, P.J., and T.M. Gerlach, Magmatic vapor source for sulfur dioxide released during volcanic eruptions: Evidence from Mount Pinatubo, Science, 265, 497-499, 1994.
78. Wallace, P.J., A.T. Anderson, and A.M. Davis, Quantification of preemptive exsolved gas contents in silicic magmas. Nature, 377, 612-615, 1995.
79. Warshaw, C. M., and R.L. Smith, Pyroxenes and fayalites in the Bandelier tuff, New Mexico: Temperatures and comparison with other rhyolites, Am. Mineral., 73, 1025-1037, 1990.
80. Watson. E.B., Diffusion in volatile-bearing magmas, in Volatiles in Magmas, Rev. Mineral., vol. 30, edited by MR. Carroll and J.R. Holloway, pp. 371-411, Am. Mineral. Soc., Washington. D.C., 1994.
81. 2 cloud from the June 15, 1991, eruption of Mount Pinatubo, Geology , 20, 867-870, 1992.
82. Westrich, H.R., H.W. Stockman, and J.C. Eichelberger, Degassing of rhyolitic magma during ascent and emplacement, J. Geophys. Res., 93, 6503-6511, 1988.
83. Westrich, H.R., J.C. Eichelberger, and R.L. Hervig, Degassing of the 1912 Katmai magmas, Geophys. Res. Lett., 18, 1561-1564, 1991.
84. Williams, S.T., N.C. Sturchio. M.L. Calvache, F. Ricardo Mendez, C. Adela Londoflo, and P. Nestor Garcia, Sulfur dioxide from Nevado del Ruiz volcano, Colombia: Total flux and isotopic constraints on its origin, J. Volcanol. Geotherm. Res., 42, 53-68, 1990.
85. Williams, S, N., S.J. Schaefer. M.L. Calvache, and D. Lopez, Global carbon dioxide emission to the atmosphere by volcanoes, Geochim. Cosmochim. Acta, 56, 1765-1770, 1992.
86. Wilson, C. N. J., B.F. Houghton, M.O. McWilliams. M.A. Lanphere, S.D. Weaver, and R.M. Briggs, Volcanic and structural evolution of the Taupo volcanic zone: A review and synthesis. J. Volcanol. Geotherm. Res., 68, 1-28, 1995.
87. Zielinski, G. A., Stratospheric loading and optical depth estimates of explosive volcanism over the last 2100 years derived from the Greenland Ice Sheet Project 2 ice core, J. Geophys. Res., 100, 20937-20955, 1995.
88. Zielinski, G. A., P.A. Mayewski, L.D. Meeker, S. Whitlow, M.S. Twickler, M. Morrison. D.A. Meese, A.J, Gow, and R.B. Alley, Record of volcanism since 7000 B.C. from the GISP2 Greenland Ice Core and implications for the volcano-climate system, Science, 264, 948-952, 1994.
89. Zielinski, G.A., P.A. Mayewski. L.D. Meeker, S. Whitlow, M.S. Twickler, and K. Taylor, Potential atmospheric impact of the Toba mega-eruption 71,000 years ago, Geophys. Res. Lett., 23, 837-840, 1996a.
90. Zielinski, G.A., P.A. Mayewski, L.D. Meeker, S. Whitlow, and M.S. Twickler, A 110000-yr record of explosive volcanism from the GISP2 (Greenland) ice core, Quat. Res., 45, 109-118, 1996b.