Review of occurrences and carbon isotope geochemistry of oxalate minerals: implications for the origin and fate of oxalate in diagenetic and hydrothermal fluids

Chemical Geology

Volumn 149, Issue 1-2, 1998, Pages 127-146

  Hofmann, Beda A ^a   Bernasconi, Stefano M ^b  

^a NATURHISTORISCHES MUSEUM DER BURGERGEMEINDE BERN   (Switzerland)

^b GEOLOGICAL INSTITUTE   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; DIAGENESIS; GEOCHEMISTRY; HYDROTHERMAL FLUID; ISOTOPE; OXALATE;

EID: 0032504271     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2541(98)00043-6     Document Type: Review

References (135)

1. Alaimo R., Montana G. Study of calcium oxalates bearing patinas of altered calcareous artifacts by BSEI technique. N. Jb. Mineral. Abh. 165:1993;143-153.
2. Armbruster Th. Minerale in menschlichen Harnkonkrementen Teil II, Oxalate, Urate und andere kristalline organische Verbindungen. Aufschluss. 32:1981;313-321.
3. Baco P., Pacindova N. Whewellite and dawsonite - epigenetic minerals in joints of sandstones near Cigel'ka (Eastern Slovakia). Mineralia Slovaca. 25:1993;277-281. in Slovakian, with English Abstr.
4. Bannister F.A., Hey M.H. Report on some crystalline components of the Weddell sea deposits. Discovery Rep. 13:1936;60-69.
5. Becke F. Whewellit von Brüx. Mineral. Petrogr. Mitt. 19:1900;166.
6. Bellon H., Perthuisot V. Ages radiométriques (K/Ar) de feldspaths potassiques et de micas néoformés du Trias diapirique vocontien. C.R. Acad. Sci. (Paris). 290:1980;1241-1244.
7. Benezeth P., Castet S., Dandurand J.-L., Gout R., Schott J. Experimental study of aluminum-acetate complexing between 60 and 200°C. Geochim. Cosmochim. Acta. 58:1994;4561-4571.
8. Blair N.E., Carter W.D. Jr. The carbon isotope biogeochemistry of acetate from a methanogenic marine sediment. Geochim. Cosmochim. Acta. 56:1992;1247-1258.
9. Blair N.E., Leu A., Munoz E., Olsen J., Kwong E., Des Marais D. Carbon isotopic fractionation in heterotrophic bacterial metabolism. Appl. Environ. Microbiol. 50:1985;996-1001.
10. Bøggild O.B. The mineralogy of Greenland. Meddelelser om Grønland. 149:1953;1-442.
11. Briscoe J.F., Moore C.B. Determination of formic and acetic acid in chondritic meteorites. Meteoritics. 28:1993;330.
12. Brooke H.J. On crystallized native oxalate of lime. Phil. Mag. S. 3(16):1840;449-450.
13. Bugaenko L.T., Juranskaj M.B., Zubarev V.E., Kaljazin E.P., Rudnev A.V., Uspensky V.A. Natural radioactivity and formation of whewellite in uranium hydrothermal deposits. Rep. Acad. Sci. U.S.S.R. 271:1983;962-963.
14. Campbell T.C., Roberts W.L. Whewellite from South Dakota and review of other North American localities. Mineral. Record. 17:1986;131-133.
15. Carothers W.W., Kharaka Y.K. Aliphatic acid anions in oil field waters - implications for the origin of natural gas. Assoc. Am. Petrol. Geol. Bull. 62:1978;2441-2453.
16. 2. Geochim. Cosmochim. Acta. 44:1980;323-332.
17. Chernykh N.V., Piloyan G.O. Whewellite in a hydrothermal uranium deposit. Doklady Akad. Nauk. SSSR. 201:1971;188-191.
18. Cipriani C., Franchi L. Sulla presenza di whewellite fra le croste di alterazione di monumenti Romani. Boll. Servizio Geologico d'Italia. 79:1958;555-564.
19. Clarke R.M., Williams I.R. Moolooite, a naturally occurring hydrated copper oxalate from Western Australia. Mineral. Mag. 50:1986;295-298.
20. Cowgill U.M. A naturally occurring alpha magnesium oxalate dihydrate from the northern Jordan Valley (Israel). Mineral. Mag. 53:1989;505-507.
21. Craig H. The geochemistry of the stable carbon isotopes. Geochim. Cosmochim. Acta. 3:1953;53-92.
22. Crossey L.J. Thermal degradation of aqueous oxalate species. Geochim. Cosmochim. Acta. 55:1991;1515-1527.
23. Cuney, 1974.
24. Cuney M. Geologic environment, mineralogy and fluid inclusions of the Bois Noirs-Limouzat Uranium vein, Forez, France. Econ. Geol. 73:1978;1567-1610.
25. Del Monte M., Sabbioni C., Zappia G. The origin of calcium oxalates on historical buildings, monuments and natural outcrops. Sci. Total Environ. 67:1987;17-39.
26. Dondi M., Puggioli G. Minerali organici, 1a parte. Riv. Mineral. Ital. 13:1990;189-206.
27. Dondi M., Puggioli G. Minerali organici, 2a parte. Riv. Mineral. Ital. 14:1991;35-57.
28. Drummond S.E., Palmer D.A. Thermal decarboxylation of acetate: Part II. Boundary conditions for the role of acetate in the primary migration of natural gas and the transportation of metals in hydrothermal systems. Geochim. Cosmochim. Acta. 50:1986;825-833.
29. Fein J.B. Experimental study of aluminum-oxalate complexing at 80°C: Implications for the formation of secondary porosity within sedimentary reservoirs. Geology. 19:1991;1037-1040.
30. Fein J.B., Brady P.V. Mineral surface controls on the diagenetic transport of oxalate and aluminum. Chem. Geol. 121:1995;11-18.
31. Fein J.B., Yane L., Handa T. The effect of aqueous complexation on the decarboxylation rate of oxalate. Geochim. Cosmochim. Acta. 58:1994;3975-3981.
32. Frenzel A. Whewellit von Zwickau. Tschermaks Mineral. Petrogr. Mitt. 11:1889;83-84.
33. Friedman, I., O'Neil, J.R., 1977. Compilation of stable isotope fractionation factors of geochemical interest. U.S. Geol. Surv. Prof. Pap., 440-KK.
34. Fritz P., Smith D.C.W. The isotopic composition of secondary dolomites. Geochim. Cosmochim. Acta. 34:1970;1161-1173.
35. Frondel C. Notes on arcanite, ammonian aphtitalite and oxammite. Am. Mineral. 35:1950;596-598.
36. Frondel C., Prien E.L. Carbonate-apatite and hydroxyl-apatite in urinary calculi. Science. 95:1942;431.
37. Fuchs, L.H., Olsen, E., Jensen, K.J., 1973. Mineralogy, Mineral-Chemistry, and Composition of the Murchison (C2) Meteorite. Smithsonian Contr. Earth Sci., 10, 39 p.
38. Gaillard C., Bourseau J.P., Boudeulle M., Pailleret P., Rio M., Roux M. Les pseudobiohermes de Beauvoisin (Drôme): un site hydrothérmal sur la marge téthysienne à l' Oxfordien? Bull. Soc. Géol. France. 1:1985;69-78.
39. Gaillard C., Rio M., Rolin Y., Roux M. Fossil chemosynthetic communities related to vents or seeps in sedimentary basins: the pseudobioherms of southeastern France compared to other world examples. Palaios. 7:1992;451-465.
40. Galimov, E.M., 1985. The Biological Fractionation of Isotopes. Academic Press, 261 pp.
41. Galimov E.M., Tugarinov A.I., Nikitin A.A. On the origin of whewellite in a hydrothermal uranium deposit. Geochem. Int. 1975:1975;31-37.
42. Garavelli C.L. Un nuovo minerale tra i prodotti secondari del giacimento di Capo Calamita (Isola d'Elba). Atti accad. nazl. Lincei, Rend. classe sci fis. mat. e nat. 18:1955;392-402.
43. Gault C.D. Weddellite: a new occurrence. Mineral. Mag. 50:1986;738-739.
44. Gestsdottir, K., Manning, D.A.C., 1992. An experimental study of the dissolution of albite in the presence of organic acids. In: Kharaka, Y.K., Maest, A.E. (Eds.), Water-Rock Interaction. Balkema, Rotterdam, pp. 315-318.
45. Giordano, T.H., Kharaka, Y.K., 1994. Organic ligand distribution and speciation in sedimentary basin brines, diagenetic fluids and related ore solutions. In: Parnell, J. (Ed.), Geofluids: Origin, Migration and Evolution of Fluids in Sedimentary Basins. Geol. Soc. Spec. Publ., 78, pp. 75-202.
46. Graustein W.C., Cromack K., Sollins P. Calcium oxalate: occurrence in soils and effect on nutrient and geochemical cycles. Science. 198:1977;1252-1254.
47. Griffin G.M., Sawyer R.K., Melkote S.R. Weddellite occurrence in peats and other organic-rich sediments of Florida. J. Sediment. Petrol. 54:1984;861-868.
48. Gude A.J., Young E.J., Kennedy V.C., Riley L.B. Whewellite and celestite from a fault opening in San Juan County, Utah. Am. Mineral. 45:1960;1257-1265.
49. Guilhaumou N., Jouaffre D., Velde B., Beny C. Raman microprobe analysis on gaseous inclusions from the diageneticallly altered Terres Noires (S-E France). Bull. Minéral. 111:1988;577-585.
50. Hajash, A., Franklin, S.P., Reed, C.L., 1992. Experimental feldspar dissolution in acetic and oxalic acids at 100°C, 345 bars. In: Kharaka, Y.K., Maest, A.E. (Eds.), Water-Rock Interaction. Balkema, Rotterdam, pp. 325-328.
51. Hansley P.L. Petrologic and experimental evidence for the etching of garnets by organic acids in the Upper Jurassic Morrison Formation, Northwestern New Mexico. J. Sediment. Petrol. 57:1987;666-681.
52. Harrison W.J., Thyne G.D. Predictions of diagenetic reactions in the presence of organic acids. Geochim. Cosmochim. Acta. 56:1992;565-586.
53. Hasselstrom T., Henry M.C. New synthesis of oxalic acid. Science. 123:1956;1038-1039.
54. Hennet R.J.-C., Crerar D.A., Schwartz J. Organic complexes in hydrothermal systems. Econ. Geol. 83:1988;742-764.
55. Hentschel G. Ungewöhnliche Hohlraumminerale mit natürlichem Calciumsulfit (Hanebachit) in der Lava der Hanebacher Ley (Eifel). Aufschluss. 37:1986;37-54.
56. Hibsch, J.E., 1934. Die Minerale des Böhmischen Mittelgebirges. Gustav Fischer Verlag, Jena.
57. Hoefs J. Natural calcium oxalate with heavy carbon. Nature. 223:1969;396.
58. Hoefs J. Kohlenstoff- und Sauerstoff-Isotopenuntersuchungen an Karbonatkonkretionen und umgebenden Gesteinen. Contrib. Mineral. Petrol. 27:1970;66-79.
59. Hoefs J., Armbruster Th. 13C/12C-Verhältnisse in menschlichen Harnkonkrementen. Naturwissenschaften. 65:1978;586-589.
60. Hofmann F. Die Whewellit-Vorkommen in Sachsen und Thüringen. Lapis. 16/5:1991;34-37.
61. Hyde C., Landy R.A. Whewellite from septarian concretions near Milan, Ohio. Am. Mineral. 51:1966;228-229.
62. Kalyuzhnyi B.A. Whewellite from southern Timan. C.R. Acad. Sci. USSR. 59:1948;1631-1633. in Russian.
63. Kawamura K., Kaplan I.R. Dicarboxylic acids generated by thermal alteration of kerogen and humic acids. Geochim. Cosmochim. Acta. 51:1987;3201-3207.
64. Kharaka Y.K., Carothers W.W., Rosenbauer R.J. Thermal decarboxylation of acetic acid: implications for origin of natural gas. Geochim. Cosmochim. Acta. 47:1983;397-402.
65. Kharaka, Y.K., Law, L.M., Carothers, W.W., Goerlitz, D.F., 1986. Role of organic species dissolved in formation waters from sedimentary basins in mineral diagenesis. In: Gauthier, D.L. (Ed.), Roles of organic matter in sediment diagenesis. Soc. Econ. Paleontol. Mineral. Spec. Publ., 38, pp. 111-122.
66. Kharaka Y.K., Ambats G., Thordsen J.J. Distribution and significance of dicarboxylic acid anions in oil-field waters. Chem. Geol. 107:1993;499-501.
67. 4 - a new mineral. Proc. Russ. Miner. Soc. 75(N1):1996;126-132. in Russian, with English Abstr.
68. Kribek, B., 1991. Organic matter of syngenetic and epigenetic uranium deposits in the Bohemian Massif. In: Pagel, M., Leroy, J.L. (Eds.), Source, Transport and Deposition of Metals. Balkema, Rotterdam, pp. 539-544.
69. 4 (s) at 298 K and 1 bar. Geochim. Cosmochim. Acta. 60:1996;1283-1289.
70. Leavens P.B. New data on whewellite. Am. Mineral. 53:1968;455-463.
71. Lebedev, L.M., Nikitina, J.B., 1983. The Cheleken ore forming system. Russ. Acad. Sci., Moscow (in Russian).
72. Lewan, M.D., Pittman, E.D., 1994. Introduction to the role of organic acids in geological processes. In: Pittman, E.D., Lewan, M.D. (Eds.), Organic Acids in Geological Processes. Springer, Berlin, pp. 1-21.
73. Lindsay J.G., McElcheran D.E., Thode H.G. The isotope effect in the decomposition of oxalic acid. J. Chem. Phys. 17:1949;589.
74. Lippmann F. Ton, Geoden und Minerale des Barrême von Hoheneggelsen. Geol. Rundsch. 43:1955;475-503.
75. Lorenz J. Mineralisationen aus dem Rhyolith-Steinbruch von Sailauf einschliesslich der Neufunde von ged. Arsen, Bertrandit, Humboldtin und Tilasit. Aufschluss. 46:1995;105-122.
76. Lowenstam H.A. Weddellite in a marine gastropode and in Antarctic sediments. Science. 162:1968;1129-1130.
77. Lundegard, P.D., Kharaka, Y.K., 1994. Distribution and occurrence of organic acids in subsurface waters. In: Pittman, E.D., Lewan, M.D. (Eds.), Organic Acids in Geological Processes. Springer, Berlin, pp. 40-69.
78. Lyon T.D.B., Baxter M.S. Stable carbon isotopes in human tissues. Nature. 273:1978;750-751.
79. MacGowan D.B., Surdam R.C. Difunctional carboxylic acid anions in oilfield waters. Org. Geochem. 12:1988;245-259.
80. MacGowan D.B., Surdam R.C. Carboxylic acid anions in formation waters, San Joaquin Basin and Louisiana Gulf Coast, U.S.A. - implications for clastic diagenesis. Appl. Geochem. 5:1990;687-701.
81. Mandarino J.A. Weddellite from Lutterworth Township, Haliburton County, Ontario. Can. Mineral. 21:1983;509-511.
82. Mandarino J.A., Witt N.V. Weddellite from Biggs, Oregon, U.S.A. Can. Mineral. 21:1983;503-508.
83. Marlowe J.I. Weddellite in bottom sediment from the St. Lawrence and Saguenay rivers. J. Sediment. Petrol. 40:1970;499-506.
84. Martin R. Der Whewellit von Condorcet (Drôme, F) 1. Teil. Schweiz. Strahler. 8:1989;301-333.
85. Martin R. Der Whewellit von Condorcet (Drôme, F) 2. Teil. Schweiz. Strahler. 8:1990;406-432.
86. Martin R., Mullis J., Nungässer W., Von Raumer J. La tunisite des 'Terres Noires' de la Drôme (France). Schweiz. Mineral. Petrogr. Mitt. 59:1979;223-238.
87. Martin R., Mullis J., Nungässer W., Galetti G. La whewellite des terres noires de la Drôme (France). Schweiz. Mineral. Petrogr. Mitt. 62:1982;1-13.
88. Means J.L., Hubbard N. Short-chain aliphatic acid anions in deep subsurface brines: a review of their origin, occurrence, properties, and importance and new data on their distribution and geochemical implications in the Palo Duro Basin, Texas. Org. Geochem. 11:1987;177-191.
89. Meinschein W.G., Rinaldi G.G.L., Hayes J.M., Schoeller D.A. Intramolecular isotopic order in biologically produced acetic acid. Biomed. Mass Spectrom. 1:1974;172-174.
90. Morse G. The minerals of Writhlington Geological Nature Reserve. Proc. Geol. Assoc. 105:1994;297-303.
91. Naumov G.B., Nikitin A.A., Naumov V.B. The origin of hydrothermal whewellite from fluorite veins in Transbaykalia. Geochem. Int. 1971:1971;107-112.
92. O'Leary M.H., Madhavan S., Paneth P. Physical and chemical basis of carbon isotope fractionation in plants. Plant, Cell Environ. 15:1992;1099-1104.
93. Palmer D.A., Drummond S.E. Thermal decarboxylation of acetate: Part I. The kinetics and mechanism of reaction in aqueous solution. Geochim. Cosmochim. Acta. 50:1986;813-823.
94. Paull C.K., Chanton J.P., Neumann A.C., Coston J.A., Martens C.S., Showers W. Indicators of methane-derived carbonates and chemosynthetic organic carbon deposits: examples from the florida escarpment. Palaios. 7:1992;361-375.
95. Pecora W.T., Kerr J.H. Whewellite from a septarian limestone concretion in marine shale near Havre, Montana. Am. Mineral. 39:1954;208-214.
96. Pel'dyakov N.I., Karpenko M.V. Whewellite from the Kuznetsk basin. Zapiski Vsesoyuznogo Mineralogicheskogo Obshestva. 113:1984;83-85. in Russian.
97. Perthuisot V., Guilhaumou N. Les diapirs triasiques du domaine vocontien: phases diapyriques et hydrothermales en domaine périalpin. Bull. Soc. Géol. France. 25:1983;379-410.
98. Povondra P., Slansky E. New occurrences of dickite in Czechoslovakia. Acta Univ. Carolinae, Geol. 1:1964;25-42. in Czech, with English Abstr.
99. Quellmalz, W., 1989. The calcium oxalate whewellite - mineralogy and natural occurrences. In: Le pellicole ad ossalati: origine e significato nella conservatione delle opere d'arte. Milano, 25-26 October 1989, pp. 103-112.
100. Rivera E.R., Smith B.N. Crystal morphology and 13carbon/12carbon composition of solid oxalate in cacti. Plant Physiol. 64:1979;966-970.
101. Rolin Y., Gaillard C., Roux M. Ecologie des pseudobiohermes des Terres Noires jurassiques liés à des paléo-sources sous-marines. Le site oxfordien de Beauvoisin (Drôme Bassin du Sud-Est, France). Palaeogeogr. Palaeoclim. Palaeoecol. 80:1990;79-105.
102. Rost R. Mineralogicke zpravy z Kladenska. Rozpravy II Tridy Ceske Akademie. 26:1942;1-8. in Czech.
103. 2O, a natural sodium copper salt of oxalic acid. Am. Mineral. 71:1986;1240-1242.
104. Russ J., Palma R.L., Loyd D.H., Boutton T.W., Coy M.A. Origin of the whewellite-rich rock crust in the Lower Pecos Region of Southwest Texas and its significance to paleoclimate reconstructions. Quart. Res. 46:1996;27-36.
105. Rust S.A. Weddellite - a new British mineral species from Derbyshire. Miner. Realm. 3:1983;22.
106. Rust S.A. The minerals of Milltown Quarry, Ashover, Derbyshire. UK J. Mines Miner. 10:1991;14-19.
107. Ryback G., Tandy P.C. Eight supplementary list of British Isles minerals (English). Mineral. Mag. 56:1992;261-275.
108. Sarf J. Minerale der Kohleflöze aus der Umgebung von Kladno (Mittelböhmen, CSSR). Aufschluss. 32:1981;469-481.
109. Schröder B., Lipp U. Der Uranerzbergbau der SDAG-Wismut im Raum Schneeberg-Aue-Schlema und seine Mineralien (II). Mineralienwelt. 1:1990;21-44.
110. Sharp Z.D., Kirschner D.L. Quartz-calcite oxygen isotope thermometry: a calibration based on natural isotopic variations. Geochim. Cosmochim. Acta. 58:1994;4491-4502.
111. Sheppard, S.M.F., 1986. Characterization and isotopic variations in natural waters. In: Valley, J.W., Taylor, H.P, O'Neil, J.R. (Eds.), Stable Isotopes in High Temperature Geological Processes. Rev. Mineral., 16, pp. 165-184.
112. Shock E.L. Organic acids in hydrothermal solutions: standard molal thermodynamic properties of carboxylic acids and estimates of dissociation constants at high temperatures and pressures. Am. J. Sci. 295:1995;496-580.
113. Stoessell R.K., Pittman E.D. Secondary porosity revisited: The chemistry of feldspar dissolution by carboxylic acids and anions. Assoc. Am. Petrol. Geol. Bull. 74:1990;1795-1805.
114. Surdam R.C., Crossey L.J. Organic-inorganic reactions during progressive burial: key to porosity and permeability enhancement and preservation. Phil. Trans. R. Soc. London A. 315:1985;135-156.
115. Surdam R.C., Crossey L.J., Hagen E.S., Heasler H.P. Organic-inorganic interactions and sandstone diagenesis. Assoc. Am. Petrol. Geol. Bull. 73:1989;1-23.
116. Tait, C.D., Janecky, D.R., Clark, D.L., Bennett, P.C., 1992. Oxalate complexation with aluminum(III) and iron(III) at moderately elevated temperatures. In: Kharaka, Y.K., Maest, A.E. (Eds.), Water-Rock Interaction. Balkema, Rotterdam, pp. 349-352.
117. Taylor, B.E., 1986. Magmatic volatiles: isotopic variation of C, H and S. In: Valley, J.W., Taylor, H.P., O'Neil, J.R. (Eds.), Stable Isotopes In High Temperature Geological Processes. Rev. Mineral., 16, pp. 185-225.
118. Thalheim, K., Reichel, W., Witzke, T., 1991. Die Minerale des Döhlener Beckens. Schriften des staatl, Museums für Mineralogie und Geologie zu Dresden, 3, 131 p.
119. Thyne, G.D., Harrison, W.J., Alloway, M.D., 1992. Experimental study of the stability of the Al-oxalate complexation at 100°C and calculations of the effects of complexation on clastic diagenesis. In: Kharaka, Y.K., Maest, A.E. (Eds.), Water-Rock Interaction. Balkema, Rotterdam, pp. 353-357.
120. Tirelli G. Weddellite e Whewellite dell'Appennino modenese. Mineral. Petrogr. Acta. 21:1977;93-100.
121. Ungemach M.H. Note sur des cristaux de whewellite rencontrés dans un filon métallifère alsacien. Bull. Soc. Franç. Minéral. 32:1909;20-26.
122. Vasseyevicz N.B., Razumovsky N.K. Whewellite from the Tertiary strata of the Maikop region, northern Caucasus. Mem. Soc. Russ. Mineral. 57:1928;275-300. in Russian, with English Abstr.
123. Verrecchia E.P. Litho-diagenetic implications of the calcium oxalate-carbonate biogeochemical cycle in semiarid calcretes, Nazareth, Israel. Geomicrobiol. J. 8:1990;87-99.
124. Verrecchia E.P., Dumont J.-L., Verreccia K.E. Role of calcium oxalate biomineralization by fungi in the formation of calcretes: a case study from Nazareth, Israel. J. Sediment. Petrol. 63:1993;1000-1006.
125. von Gaertner H.-R. Petrographische Untersuchungen am nordwestdeutschen Posidonienschiefer. Geol. Rdsch. 43:1958;447-463.
126. Weiner K.-L., Hochleitner R. Steckbrief Whewellit. Lapis. 21:1996;8-10.
127. Weisbach A. Ein neuer Fund von Whewellit. N. Jb. Mineral. Paläont. 2:1884;48-49.
128. Weisbach, 1886.
129. Welch, S.A., Ullman, W.J., 1992. Dissolution of feldspars in oxalic acid solutions. In: Kharaka, Y.K., Maest, A.E. (Eds.), Water-Rock Interaction. Balkema, Rotterdam, pp. 127-130.
130. Wilson M.J., Jones D., Russell J.D. Glushinskite, a naturally occurring magnesium oxalate. Mineral. Mag. 43:1980;837-840.
131. 2O) from different geological environments and its significance. Chem. Geol. Isotope Geosci. Sect. 106:1993;123-131.
132. Zatsikha B.V., Didenko A.V., Dolishnij B.V., Iorish Z.I., Skulskaj L.I. Morphology and formation conditions of whewellite at the Slavyanks mercury ore show. Mineralogicheskiy Zh. 7:1985;74-78. in Russian, with English Abstr.
133. Zielinski M., Zielinska A., Papiernik-Zielinska H., Städter W., Kasprzyk G., Czarnota G., Gehre M., Hofling R., Strauch G. A contribution to carbon-13 and carbon-14 kinetic isotope effect studies in the decarboxylation of oxalic acid in sulphuric and in phosphoric acids. Nukleonika. 39:1994;51-61.
134. Zielinski M., Zielinska A., Papiernik-Zielinska H., Städter W., Gehre M., Czarnota G., Kasprzyk G. Carbon-13 kinetic isotope effect of the decarboxylation of oxalic acid. J. Radioanal. Nucl. Chem. 191:1995;369-380. Articles.
135. Zsivny V. Mineralogical notes from Recsk. Ann. Museui Nationalis Hungarici. 19:1922;147-149. in Hungarian.