Syntheses of (-)-(2R,3R,6S)-irnigaine and (+)-(2R,3R,6S)-N- methylirnigaine

Tetrahedron Letters

Volumn 39, Issue 15, 1998, Pages 2095-2096

  Pahl, Axel ^a   Wartchow, Rudolf ^a   Meyer, Hartmut H ^a  

^a LEIBNIZ UNIVERSITY HANNOVER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALOID DERIVATIVE; IRNIGAINE; N METHYLIRNIGAINE; UNCLASSIFIED DRUG;

ARTICLE; CHIRALITY; DRUG ISOLATION; DRUG STRUCTURE; DRUG SYNTHESIS; X RAY ANALYSIS;

EID: 0032499153     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00297-4     Document Type: Article

References (8)

1. 1. Melhaoui, A.; Bodo, B. Natural Prod. Lett. 1995, 7, 101.
2. 2. Pahl, A.; Oetting, J.; Holzkamp, J.; Meyer, H.H. Tetrahedron 1997, 53(21), 7255.
3. 3. Oetting, J.; Holzkamp, J.; Pahl, A.; Meyer, H.H. Tetrahedron Asymm. 1997, 8(3), 477.
4. 35NO: 317.2719; found: 317.2720.
5. 2 and reference cited therein.
6. 6. All synthetic intermediates were fully characterized and gave satisfactory analytical and spectroscopic data.
7. 2= 0.0548; Flack x: -0.10(6); Complete crystallographic data were deposited as supplementary publication no. CCDC-101053 and can be obtained under the following address from the Cambridge Crystallographic Data Centre in Great Britain: The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK, fax: +(1223) 336-033; deposit@ccdc.cam.ac.uk.
8. 8. Rice, W.Y.jr.; Coke J.L. J. Org. Chem. 1966, 31, 1010.