Effect of laser intensity on the determination of intermolecular electron transfer rate constants - Observation of Marcus inverted region in photoinduced back electron transfer reactions

Journal of Chemical Physics

Volumn 109, Issue 14, 1998, Pages 5948-5956

  Weng, Yu Xiang ^a   Chan, Kwok Chu ^a   Tzeng, Biing Chiau ^a   Che, Chi Ming ^a  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; COPPER COMPOUNDS; ELECTRON TRANSITIONS; ELECTRONS; EMISSION SPECTROSCOPY; GOLD COMPOUNDS; GROUND STATE; MOLECULES; PHOTOLYSIS; PHOTONS; PULSED LASER APPLICATIONS; QUANTUM EFFICIENCY;

INTERMOLECULAR ELECTRON TRANSFER; LASER FLASH PHOTOLYSIS; MARCUS INVERTED REGION; MONOPHOTONIC PROCESS; PHOTOINDUCED ELECTRON TRANSFER;

CHARGE TRANSFER;

EID: 0032497468     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.477219     Document Type: Article

References (51)

1. R. A. Marcus, J. Chem. Phys. 24, 966 (1956).
2. R. A. Marcus and N. Sutin, Biochim. Biophys. Acta 811, 265 (1985).
3. D. Rehm and A. Weller, Isr. J. Chem. 8, 259 (1970).
4. C. Creutz and N. Sutin, J. Am. Chem. Soc. 99, 241 (1977).
5. J. K. Nagle, W. J. Dressick, and T. J. Meyer, J. Am. Chem. Soc. 101, 3993 (1979).
6. J. R. Miller, L. T. Calcaterra, and G. L. Closs, J. Am. Chem. Soc. 106, 3047 (1984).
7. J. R. Miller, J. V. Beitz, and R. K. Huddleston, J. Am. Chem. Soc. 106, 5057 (1984).
8. G. L. Closs, L. T. Calcaterra, N. J. Green, K. W. Penfield, and J. R. Miller, J. Phys. Chem. 90, 3673 (1986).
9. G. L. Closs and J. R. Miller, Science 240, 440 (1988).
10. G. Mclendon and R. J. Miller, J. Am. Chem. Soc. 107, 7811 (1985).
11. M. R. Wasielewski, M. P. Niemczyk, W. A. Svec, and E. B. Pewitt, J. Am. Chem. Soc. 107, 1080 (1985).
12. S. Nishitani, N. Kurata, Y. Sakata, S. Misumi, A. Karen, T. Okada, and T. Mataga, J. Am. Chem. Soc. 105, 7771 (1983).
13. L. S. Fox, M. Kozik, J. R. Winkler, and H. B. Gray, Science 247, 1069 (1990).
14. R. S. Farid, I.-J Chang, J. R. Winkler, and H. B. Gray, J. Phys. Chem. 98, 5176 (1994).
15. I. R. Gould, D. Ege, S. L. Mattes, and S. Farid, J. Am. Chem. Soc. 109, 3794 (1987).
16. I. R. Gould, J. E. Moser, B. Armitage, S. Farid, J. L. Goodman, and M. S. Herman, J. Am. Chem. Soc. 111, 1917 (1989).
17. I. R. Gould, J. E. Moser, D. Ege, and S. Farid, J. Am. Chem. Soc. 110, 199 (1988).
18. I. R. Gould and S. Farid, J. Am. Chem. Soc. 110, 1991 (1988).
19. G. Grampp and G. Hetz, Ber. Bunsenges. Phys. Chem. 96, 198 (1992).
20. T. M. McCleskey, J. R. Winkler, and H. B. Gray, J. Am. Chem. Soc. 114, 6935 (1992).
21. K. C. Cho, C. M. Che, K. M. Ng, and C. L. Choy, J. Phys. Chem. 91, 3690 (1987).
22. T. Ohno, A. Yoshimura, and N. Mataga, J. Phys. Chem. 90, 3295 (1986).
23. C. Turro, J. M. Zaleski, Y. M. Karabatsos, and D. G. Nocera, J. Am. Chem. Soc. 118, 6060 (1996).
24. R. M. Noyes, J. Am. Chem. Soc. 77, 2042 (1955).
25. R. M. Noyes, J. Am. Chem. Soc. 78, 5468 (1956).
26. C. M. Che, H. L. Kwong, C. K. Poon, and V. W. W. Yam, J. Chem. Soc. Dalton Trans. 3215 (1990).
27. L. A. Kelly and M. A. J. Rodgers, J. Phys. Chem. 99, 13132 (1995).
28. R. Castro, M. L. Duran, J. A. Garcia-Vazquez, J. Romero, A. Sousa, E. E. Castellano, and J. Zukerman-Schpector, J. Chem. Soc. Dalton Trans. 2559 (1992).
29. S. Seth, A. K. Das, and T. C. W. Mak, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 51, 2529 (1995).
30. U. Lachish, A. Shafferman, and G. Stein, J. Chem. Phys. 64, 4205 (1976).
31. E. Pitts, G. C. Terry, and F. W. Willets, Trans. Faraday. Soc. II 62, 2858 (1966).
32. H. S. Pilloff and A. C. Albrecht, J. Chem. Phys. 49, 4891 (1968).
33. N. I. Avdievich, A. S. Jeevarajan, and M. D. E. Forbes, J. Phys. Chem. 100, 5334 (1996).
34. F. Scandola, V. Balzani, and G. B. Schuster, J. Am. Chem. Soc. 103, 2519 (1981).
35. V. Balzani and A. Juries, Coord. Chem. Rev. 84, 85 (1988).
36. G. N. Lewis and M. Kasha, J. Am. Chem. Soc. 66, 2100 (1944).
37. K. D. Cadogan and A. C. Albrecht, J. Phys. Chem. 72, 929 (1968).
38. S. Kitagawa, M. Munakata, H. Shimono, S. Matsuyama, and H. Masuda, J. Chem. Soc. Dalton Trans. 2105 (1990).
39. C. M. Che, H. L. Kwong, C. K. Poon, V. W.-W. Yam, and K. C. Cho, J. Chem. Soc. Chem. Commun. 885 (1989).
40. C. King, J.-C. Wang, Md. N. I. Khan, and J. P. Fackler, Jr., Inorg. Chem. 28, 2145 (1989).
41. J. N. Demas and G. A. Crosby, J. Phys. Chem. 75, 991 (1971).
42. J. P. Simons, Photochemistry and Spectroscopy (Wiley-Interscience, London, 1971).
43. R. Potashnik, M. Ottolenghi, and R. Bensasson, J. Phys. Chem. 73, 1912 (1969).
44. K. C. Cho and C. M. Che, Chem. Phys. Lett. 124, 313 (1986).
45. B. S. Brunschwig and N. Sutin, Comments Inorg. Chem. 6, 209 (1987).
46. J. Ulstrup and J. Jortner, J. Chem. Phys. 63, 4358 (1975).
47. D. N. Beratan, J. N. Onuchic, J. R. Winkler, and H. B. Gray, Science 258, 1740 (1992).
48. T. Watanabe and K. Honda, J. Phys. Chem. 86, 2617 (1982).
49. J. Hermolin, M. Levin, and E. M. Kosower, J. Am. Chem. Soc. 103, 4808 (1981).
50. J. A. Farrington, M. Ebert, and E. J. Land, J. Chem. Soc., Faraday Trans. 1 665 (1978).
51. J. Hermolin, M. Levin, and E. M. Kosower, J. Am. Chem. Soc. 103, 4808 (1981).