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2642633351
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note
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The g anisotropy was not considered in the simulation.
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2642623167
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note
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∓3/2′. tan 2ω = √3E/D. (16) The phosphorescence decays at 80 K were reproduced by a sum of two exponential decays for both the para and the meta complexes. The two lifetimes were 0.38/4 and 0.27/0.8 ms for the para and meta complexes, respectively.
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27
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2642664085
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note
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-3/2″ = 0:1:1:0, the simulation spectra were the same as those in Figures 5 and 6.
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28
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2642693280
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note
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-3/2″ = 1:2:1:0, the simulation spectra were the same as those in Figures 7a and 7b, respectively.
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29
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2642661028
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note
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0 state due to the radical - triplet pair mechanism cannot occur, unlike in solution.
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30
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2642667050
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note
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1 state in the ZnTPP - nitpy systems, where the interaction between the doublet and triplet spins was weaker than that in Cu porphyrins, was observable by TREPR.
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0000407656
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61
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2642686194
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note
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D,-1/2‡, would be large enough to observe.
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62
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2642589590
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note
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D,-1/2‡) are small.
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