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Volumn 120, Issue 13, 1998, Pages 3152-3158

General simulations of excited quartet spectra with electron-spin polarizations: The excited multiplet states of (tetraphenylporphinato)zinc(II) coordinated by p- or m-pyridyl nitronyl nitroxides

Author keywords

[No Author keywords available]

Indexed keywords

NITROXIDE DERIVATIVE; PYRIDINE DERIVATIVE; TETRAPHENYLPORPHYRIN DERIVATIVE; ZINC ION;

EID: 0032495789     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973146f     Document Type: Article
Times cited : (86)

References (62)
  • 22
    • 2642633351 scopus 로고    scopus 로고
    • note
    • The g anisotropy was not considered in the simulation.
  • 26
    • 2642623167 scopus 로고    scopus 로고
    • note
    • ∓3/2′. tan 2ω = √3E/D. (16) The phosphorescence decays at 80 K were reproduced by a sum of two exponential decays for both the para and the meta complexes. The two lifetimes were 0.38/4 and 0.27/0.8 ms for the para and meta complexes, respectively.
  • 27
    • 2642664085 scopus 로고    scopus 로고
    • note
    • -3/2″ = 0:1:1:0, the simulation spectra were the same as those in Figures 5 and 6.
  • 28
    • 2642693280 scopus 로고    scopus 로고
    • note
    • -3/2″ = 1:2:1:0, the simulation spectra were the same as those in Figures 7a and 7b, respectively.
  • 29
    • 2642661028 scopus 로고    scopus 로고
    • note
    • 0 state due to the radical - triplet pair mechanism cannot occur, unlike in solution.
  • 30
    • 2642667050 scopus 로고    scopus 로고
    • note
    • 1 state in the ZnTPP - nitpy systems, where the interaction between the doublet and triplet spins was weaker than that in Cu porphyrins, was observable by TREPR.
  • 34
    • 0002312013 scopus 로고
    • Dolphin, D., Ed.; Academic: New York
    • Gouterman, M. In The Porphyrins; Dolphin, D., Ed.; Academic: New York, 1978; Vol. III, pp 1-165.
    • (1978) The Porphyrins , vol.3 , pp. 1-165
    • Gouterman, M.1
  • 35
    • 2642625227 scopus 로고    scopus 로고
    • note
    • 16
  • 61
    • 2642686194 scopus 로고    scopus 로고
    • note
    • D,-1/2‡, would be large enough to observe.
  • 62
    • 2642589590 scopus 로고    scopus 로고
    • note
    • D,-1/2‡) are small.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.