Microscopic solvent structure of supercritical carbon dioxide and its mixtures with methanol in the cybotactic region of the solute molecule

Journal of Chemical Physics

Volumn 108, Issue 10, 1998, Pages 3915-3921

  Bulgarevich, Dmitry S ^a,c   Sako, Takeshi ^a   Sugeta, Tsutomu ^a   Otake, Katsuto ^a   Sato, Masahito ^a   Uesugi, Masayuki ^b   Kato, Masahiro ^b  

^a NATL INST OF MAT AND CHEM RES   (Japan)

^b NIHON UNIVERSITY   (Japan)

^c NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; CARBON DIOXIDE; COMPOSITION; HYDROGEN BONDS; LIGHT ABSORPTION; METHANOL; MIXTURES; MOLECULAR DYNAMICS; PERMITTIVITY; REFRACTIVE INDEX; SOLUBILITY; ULTRAVIOLET SPECTROSCOPY;

CYBOTACTIC REGION; DIPOLE MOMENT; NITROANISOLE; SOLVATOCHROMISM; SOLVENT POLARITY; SUPERCRITICAL CARBON DIOXIDE;

MOLECULAR STRUCTURE;

EID: 0032495649     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.475794     Document Type: Article

References (28)

1. J. M. Dobbs, J. M. Wong, and K. P. Johnston, J. Chem. Eng. Data 31, 303 (1986).
2. C. R. Yonker and R. D. Smith, Anal. Chem. 59, 727 (1987).
3. C. Reichardt, in Solvent Effects in Organic Chemistry, edited by E. Wentrup-Byrne (Chemie, Weinheim, New York, 1979), and references therein.
4. K. P. Johnston, S. Kim, and J. Combes, in Supercritical Fluid Science and Technology, edited by K. P. Johnston and J. M. L. Penninger (American Chemical Society, Washington, 1989), Chap. 5, and references therein.
5. J. M. Dobbs, J. M. Wong, R. J. Lahiere, and K. P. Johnston, Ind. Eng. Chem. Res. 26, 56 (1987).
6. O. Kajimoto, M. Futakami, T. Kobayashi, and K. Yamasaki, J. Phys. Chem. 92, 1347 (1988).
7. S. Angus, B. Armstrong, and K. M. de Reuck, in IUPAC: International Thermodynamics Tables of the Fluid State Carbon Dioxide (Pergamon, New York, 1976).
8. J. R. Lakowicz, in Principles of Fluorescence Spectroscopy (Plenum, New York, 1983).
9. L. Onsager, J. Am. Chem. Soc. 58, 1486 (1936).
10. B. N. Solomonov, A. I. Konovalov, V. B. Novikov, V. B. Gorbachuk, and S. A. Neklyudov, Zh. Obshch. Kim. 55, 1899 (1985).
11. M. H. Abraham, J. Am. Chem. Soc. 101, 5477 (1979).
12. S. B. Bulgarevich and D. Ya. Movshovich, Mendeleev Commun. 16 (1992).
13. S. B. Bulgarevich and D. Ya. Movshovich, Zh. Obshch. Kim. 62, 2187 (1992).
14. S. Kim and K. P. Johnston, Ind. Eng. Chem. Res. 26, 1206 (1987).
15. A. Morita and O. Kajimoto, J. Phys. Chem. 94, 6420 (1990).
16. R. D. Schulte and J. F. Kauffman, J. Phys. Chem. 98, 8793 (1994).
17. M. J. Kamlet, J.-L. M. Abboud, M. H. Abraham, and R. W. Taft, J. Org. Chem. 48, 2877 (1983).
18. C. R. Yonker, S. L. Frye, D. R. Kalkwarf, and R. D. Smith, J. Phys. Chem. 90, 3022 (1986).
19. C. R. Yonker and R. D. Smith, J. Phys. Chem. 92, 2374 (1988).
20. M. J. Kamlet, J.-L. M. Abboud, and R. W. Taft, J. Am. Chem. Soc. 99, 6027 (1977).
21. M. J. Kamlet and R. W. Taft, J. Am. Chem. Soc. 98, 377 (1976).
22. R. W. Taft and M. J. Kamlet, J. Am. Chem. Soc. 98, 2886 (1976).
23. G. S. Gurdial, N. R. Foster, S. L. J. Yun, and K. D. Tilly, in Supercritical Fluid Engineering Science: Fundamentals and Applications, edited by E. Kiran and J. F. Brennecke (American Chemical Society, Washington, 1993), Chap. 3.
24. J. O. Hirschfelder, C. F. Curtiss, and R. B. Bird, in Molecular Theory of Gases and Liquids, edited by M. G. Mayer (Wiley, New York, 1954), p. 988.
25. K.-H. Lee, S. I. Sandler, and N. C. Patel, Fluid Phase Equilibria 25, 31 (1986).
26. S. Kim and K. P. Johnston, AIChE. J. 33, 1603 (1987).
27. J. B. Ellington, K. M. Park, and J. F. Brennecke, Ind. Eng. Chem. Res. 33, 965 (1994).
28. Can be roughly estimated by the method of Eisenlohr, W. J. Lyman, W. F. Reehl, and D. H. Rosenblatt, in Handbook of Chemical Property Estimation Methods (American Chemical Society, Washington, 1990), Chap. 15.