Formal stereoselective synthesis of (±)-akagerine

Chemical Communications

Volumn , Issue 23, 1998, Pages 2639-2640

  Bennasar, M Lluïsa ^a   Vidal, Bernat ^a   Sufi, Bilal A ^a   Bosch, Joan ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

AKAGERINE; INDOLE ALKALOID; UNCLASSIFIED DRUG;

ARTICLE; DRUG STRUCTURE; DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0032495038     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a807868h     Document Type: Article

References (17)

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12. All yields are from material purified by column chromatography. Satisfactory spectral, analytical and/or HRMS data were obtained for all new compounds.
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14. 3) 18.4 (C-18), 29.3 (C-15), 30.7 (C-6), 32.3 (C-14), 44.4 (C-5), 47.7 (C-16), 56.9 (C-3), 96.7 (C-20), 112.5 (C-7), 115.5 (C-12), 120.6 (C-9), 123.7 (C-10), 125.8 (C-11), 126.3 (Ph), 129.2 (Ph), 129.5 (C-8), 135.0 (Ph), 135.2 (C-2), 138.4 (C-13), 168.9 (C-19), 171.7, 172.7 (C-17, C-21).
15. K. Ritter, Synthesis, 1993, 735.
16. K. Cardwell, B. Hewitt, M. Ladlow and P. Magnus, J. Am. Chem. Soc., 1988, 110, 2242.
17. 3) 14.3 (C-18), 20.0 (C-6), 27.6 (C-15), 27.3 (C-14), 42.4 (C-5), 47.0 (C-16), 51.9 (C-3), 115.2 (C-12), 117.8 (C-9), 120.1 (C-7), 123.9 (C-10), 125.2 (C-211), 132.6 (C-20), 135.8 (C-2), 136.8 (C-13), 138.1 (C-19), 166.1 (C-21), 172.1 (C-17).