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Volumn 14, Issue 1, 1998, Pages 113-123

Surface-confined monomers on electrode surfaces. 4. Electrochemical and spectroscopic characterization of undec-10-ene-1-thiol self-assembled monolayers on Au

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; CYCLIC VOLTAMMETRY; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; GOLD; INFRARED SPECTROSCOPY; MONOMERS; NANOSTRUCTURED MATERIALS; SYNTHESIS (CHEMICAL);

EID: 0032488528     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la970823a     Document Type: Article
Times cited : (50)

References (89)
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    • Porter, M.D.1
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    • Unpublished results
    • (d) Lin, S.; McCarley, R. L. Unpublished results, 1997.
    • (1997)
    • Lin, S.1    McCarley, R.L.2
  • 47
    • 85088001295 scopus 로고    scopus 로고
    • note
    • 20b regarding the voltammetric blocking behavior of ω-substituted alkanethiol SAMs indicated similar results.
  • 56
    • 11644324200 scopus 로고    scopus 로고
    • note
    • Fricke dosimetry was used as described at the Nuclear Science Center, Louisiana State University; Max Scott - Director.
  • 82
    • 11644289534 scopus 로고    scopus 로고
    • Private communication
    • Zhong, C.-J. Private communication, 1997.
    • (1997)
    • Zhong, C.-J.1
  • 83
    • 85088003246 scopus 로고    scopus 로고
    • note
    • 2) modes upon irradiation.
  • 87
    • 85088002589 scopus 로고    scopus 로고
    • note
    • 2) mode as an internal reference to account for variations in sample positioning in the IR spectrometer.
  • 88
    • 11644319477 scopus 로고    scopus 로고
    • note
    • E modes) indicating the presence of chain end-gauche defects are found for undec-10-ene-1-thiol monolayers on the 1.3 nm Au crystals. These bands are also present for monolayers on the 3.4 nm crystals. A calculation of the percent population of chain end-gauche defects in the monolayers yields values of roughly 5-15% for both the 1.3 and 3.4 nm clusters. The presence of such a small number of defects should not greatly affect the probability of oligomerization, unless the majority of these defects is found in regions where there is no interdigitation of chains from neighboring clusters.
  • 89
    • 85088002090 scopus 로고    scopus 로고
    • note
    • 2) mode.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.