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2+ (L = bpy, tmbpy) display broad band emission spectra in aqueous solution, with λ ∼ 650 nm; the luminescence decay lifetimes are 20 and 54 ns, respectively.
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3+/2+ reduction potential. The rates we have measured for the slow phase are insensitive to the complexes used, although we did not examine a large driving-force range. Thus the results do not allow us conclusively to rule out an oxidation/rearrangement mechanism.
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