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Volumn 31, Issue 9, 1998, Pages 2797-2803

Anionic polymerization of monomers containing functional groups. 12. Anionic equilibrium polymerization of 4-cyano-α-methylstyrene

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ANIONIC POLYMERIZATION; ENTHALPY; ENTROPY; INITIATORS (CHEMICAL); MOLECULAR STRUCTURE; MOLECULAR WEIGHT DISTRIBUTION; MONOMERS; OLIGOMERS; ORGANOMETALLICS; POTASSIUM COMPOUNDS; REACTION KINETICS;

EID: 0032485684     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma971822s     Document Type: Article
Times cited : (14)

References (48)
  • 1
    • 0025592628 scopus 로고
    • For a review, see: Nakahama, S.; Hirao, A. Prog. Polym. Sci. 1990, 15, 299. For a recent publication of this series, see: Ishizone, T.; Tominaga, T.; Kitamura, K.; Hirao, A.; Nakahama, S. Macromolecules 1995, 28, 4829.
    • (1990) Prog. Polym. Sci. , vol.15 , pp. 299
    • Nakahama, S.1    Hirao, A.2
  • 37
    • 3843119412 scopus 로고
    • The anionic living polymerizations of 4-(trimethylsilyl)-α-methylstyrene (Herz, J.; Beinert, G. Eur. Polym. J. 1982, 18, 875) and 4-(1-((tert-butyldimethylsilyl)oxy)ethenyl)-α-methylstyrene (Hirao, A.; Kato, K.; Nakahama, S. Macromolecules 1992, 25, 535.) have been reported, while no information is available on the equilibrium characters.
    • (1982) Eur. Polym. J. , vol.18 , pp. 875
    • Herz, J.1    Beinert, G.2
  • 38
    • 0026747401 scopus 로고
    • The anionic living polymerizations of 4-(trimethylsilyl)-α-methylstyrene (Herz, J.; Beinert, G. Eur. Polym. J. 1982, 18, 875) and 4-(1-((tert-butyldimethylsilyl)oxy)ethenyl)-α-methylstyrene (Hirao, A.; Kato, K.; Nakahama, S. Macromolecules 1992, 25, 535.) have been reported, while no information is available on the equilibrium characters.
    • (1992) Macromolecules , vol.25 , pp. 535
    • Hirao, A.1    Kato, K.2    Nakahama, S.3
  • 40
    • 85034471892 scopus 로고    scopus 로고
    • note
    • n = 1.48 (Table 2) while it maintained a unimodal curve. This indicates that the reversible polymerization of the living poly(1) and residual monomer unequivocally takes place even at -30°C when the polymerization system is allowed to react for a long period.
  • 41
    • 85034477874 scopus 로고    scopus 로고
    • note
    • 0 values might be quite small or negligible in our experiment.
  • 48
    • 85034466525 scopus 로고    scopus 로고
    • Reference 33, p II 275
    • Reference 33, p II 275.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.