Long-range N→Si interactions in organosilicon compounds with hepta- and octacoordinate silicon centers

Angewandte Chemie - International Edition

Volumn 37, Issue 22, 1998, Pages 3163-3166

  Bock, Hans ^a   Havlas, Zdenek ^b   Krenzel, Volker ^a  

^a GOETHE UNIVERSITY   (Germany)

^b INSTITUTE OF ORGANIC CHEMISTRY AND BIOCHEMISTRY   (Czech Republic)

Author keywords

Density functional calculations; Donor acceptor systems; Hypercoordinate compounds; Silicon

Indexed keywords

ORGANOSILICON DERIVATIVE; SILICON; SILICON DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; MOLECULAR INTERACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 0032484169     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19981204)37:22<3163::aid-anie3163>3.0.co;2-%23     Document Type: Article

References (34)

1. H. Bock, Angew. Chem. 1989, 101, 1659; Angew. Chem. Int. Ed. Engl. 1989, 28, 1627.
2. H. Bock, Angew. Chem. 1989, 101, 1659; Angew. Chem. Int. Ed. Engl. 1989, 28, 1627.
3. See, for example, a) W. Sheldrick in The Chemistry of Organosilicon Compounds (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1989, pp. 227-303; b) R. J. P. Corriu, J. C. Young in The Chemistry of Organosilicon Compounds (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1989, pp. 1241-1288.
4. See, for example, a) W. Sheldrick in The Chemistry of Organosilicon Compounds (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1989, pp. 227-303; b) R. J. P. Corriu, J. C. Young in The Chemistry of Organosilicon Compounds (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1989, pp. 1241-1288.
5. a) Cambridge Structural Database (Version 5.10);
6. b) G. Klebe, J. W. Bats, H. Fuess, J. Am. Chem. Soc. 1984, 106, 5202;
7. c) F. Carré, R. J. P. Corriu, A. Kroton, M. Poirier, G. Royo, Y. C. Young, C. Belin, J. Organomet. Chem. 1994, 470, 43;
8. d) C. Brelière, F. Carré, R. J. P. Corriu, G. Royo, M. W. C. Man, Organometallics 1994, 13, 307.
9. N. Auner, R. Probst, F. Hahn, E. Herdtweck, J. Organomet. Chem. 1993, 459, 25, and references therein.
10. F. Carré, C. Chuit, R. J. P. Corriu, A. Mehdi, C. Reyé, Angew. Chem. 1994, 106, 1152; Angew. Chem. Int. Ed. Engl. 1994, 93, 1097, and references therein.
11. F. Carré, C. Chuit, R. J. P. Corriu, A. Mehdi, C. Reyé, Angew. Chem. 1994, 106, 1152; Angew. Chem. Int. Ed. Engl. 1994, 93, 1097, and references therein.
12. 2 units and the phenyl group substituents of considerably different bulk.
13. 2 units and the phenyl group substituents of considerably different bulk.
14. 2 units and the phenyl group substituents of considerably different bulk.
15. 2 units and the phenyl group substituents of considerably different bulk.
16. 2 units and the phenyl group substituents of considerably different bulk.
17. 2 units and the phenyl group substituents of considerably different bulk.
18. 2 units and the phenyl group substituents of considerably different bulk.
19. 2 units and the phenyl group substituents of considerably different bulk.
20. 3NA, has been calculated using fourth-order Møller-Plesset perturbation theory (MP4) and a correlation consistent basis set with polarized valence "double-zeta" functions(aug-cc-pVDZ) (D. E. Woon, T. H. Dunning, Jr., J. Chem. Phys. 1993, 98, 1358; R. A. Kendall, T. H. Dunning Jr., R. J. Harrison, J. Chem. Phys. 1992, 96, 6796). The same basis set also was employed in the geometry optimization at the MP2 level.
21. 3NA, has been calculated using fourth-order Møller-Plesset perturbation theory (MP4) and a correlation consistent basis set with polarized valence "double-zeta" functions(aug-cc-pVDZ) (D. E. Woon, T. H. Dunning, Jr., J. Chem. Phys. 1993, 98, 1358; R. A. Kendall, T. H. Dunning Jr., R. J. Harrison, J. Chem. Phys. 1992, 96, 6796). The same basis set also was employed in the geometry optimization at the MP2 level.
22. a) A. Schäfer, M. Weidenbruch, K. Peters, H. G. von Schnering, Angew. Chem. 1984, 96, 311; Angew. Chem. Int. Ed. Engl. 1984, 23, 302;
23. a) A. Schäfer, M. Weidenbruch, K. Peters, H. G. von Schnering, Angew. Chem. 1984, 96, 311; Angew. Chem. Int. Ed. Engl. 1984, 23, 302;
24. b) M. Weidenbruch, B. Flintjer, K. Peters, H. G. von Schnering, Angew. Chem. 1986, 98, 1090; Angew. Chem. Int. Ed. Engl. 1986, 25, 1129.
25. b) M. Weidenbruch, B. Flintjer, K. Peters, H. G. von Schnering, Angew. Chem. 1986, 98, 1090; Angew. Chem. Int. Ed. Engl. 1986, 25, 1129.
26. H. Bock, J. Meuret, K. Ruppert, Angew. Chem. 1993, 105, 413; Angew. Chem Int. Ed. Engl. 1993, 32, 414; see also H. Bock, J. Meuret, C. Näther, K. Ruppert, Organosilicon Chemistry - From Molecules to Materials, VCH, Weinheim, 1994, p. 11.
27. H. Bock, J. Meuret, K. Ruppert, Angew. Chem. 1993, 105, 413; Angew. Chem Int. Ed. Engl. 1993, 32, 414; see also H. Bock, J. Meuret, C. Näther, K. Ruppert, Organosilicon Chemistry - From Molecules to Materials, VCH, Weinheim, 1994, p. 11.
28. H. Bock, J. Meuret, K. Ruppert, Angew. Chem. 1993, 105, 413; Angew. Chem Int. Ed. Engl. 1993, 32, 414; see also H. Bock, J. Meuret, C. Näther, K. Ruppert, Organosilicon Chemistry - From Molecules to Materials, VCH, Weinheim, 1994, p. 11.
29. "The Crystal as a Supramolecular Entity" in Perspectives in Supramolecular Chemistry, Vol. 2 (Ed.: G. R. Desiraju), Wiley, Chichester, 1995.
30. H. Bock, Z. Havlas, A. Rauschenbach, C. Näther, M. Kleine, Chem. Commun. 1996, 1529; see also: H. Bock, N. Nagel, A. Seibel, Liebigs Ann. 1997, 2151.
31. H. Bock, Z. Havlas, A. Rauschenbach, C. Näther, M. Kleine, Chem. Commun. 1996, 1529; see also: H. Bock, N. Nagel, A. Seibel, Liebigs Ann. 1997, 2151.
32. G. A. Jeffrey, W. Saenger, Hydrogen Bonding in Biological Structures, Springer, Berlin, 1991.
33. N. W. Mitzel, U. Losehand, Angew. Chem. 1997, 109, 2897; Angew. Chem. Int. Ed. Engl. 1997, 36, 2807.
34. N. W. Mitzel, U. Losehand, Angew. Chem. 1997, 109, 2897; Angew. Chem. Int. Ed. Engl. 1997, 36, 2807.