Elimination reaction over solid supports under microwave irradiation: Synthesis of functionalized alkenes

Tetrahedron Letters

Volumn 39, Issue 23, 1998, Pages 4035-4038

  Saoudi, Aicha ^b   Hamelin, Jack ^a   Benhaoua, Hadj ^a  

^a UNIVERSITÉ DE RENNES 1   (France)

^b NONE

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE;

ARTICLE; CHEMICAL REACTION; MICROWAVE RADIATION; REACTION ANALYSIS; SYNTHESIS;

EID: 0032482526     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00690-X     Document Type: Article

References (16)

1. 1 Smith, K., Ed., Solid Supports and Catalysts in Organic Synthesis ; Ellis Horwood Prentice Hall, New York, 1992.
2. 2 a) Gedye, R. N.; Smith, F. E.; Westaway, K. C. Can. J. Chem., 1988, 66, 17-27.
3. b) Gutierrez, E.; Loupy, A.; Bram, G.; Ruiz-Hitzky, E. Tetrahedron Lett. 1989, 30, 245-248.
4. c) Caddick, S. Tetrahedron 1995, 51, 10403-10432.
5. 3 Saoudi, A.; Hamelin, J.; Benhaoua, H. J. Chem. Res. (S) 1996, 492-493.
6. 4 Padwa, A.; 1,3 Dipolar Cycloaddition Chemistry, Vol 1, John Wiley & sons, New York, 1984.
7. 13C NMR and compared with the literature data.
8. 6 a) Wartski, L.; Wakselman, C. Bull. Soc. Chim. Fr. 1972, 1478-1482.
9. b) Martin A.R.; Mallick, S.K.; Caputo, J.F. J. Org. Chem. 1974, 39, 1808-1814.
10. c) Kayser, M.M.; Zhu, J.; Hooper, D.L.; Can. J. Chem. 1997, 75, 1315-1321.
11. 7 Dufraisse, C.; Moureu, H. Bull. Soc. Chim. Fr. 1927, 41, 464-473.
12. 8 Cromwell, N.H.; Cram, D.J. J.Amer.Chem.Soc. 1947, 65, 301-308.
13. 9 Lawesson, S.O. Tetrahedron 1974, 30, 3481-3492.
14. 10 Parham, W.E; Bleasdale J.L. J. Amer.Chem. Soc. 1951, 73, 4664-4666.
15. end Ed.; Mc Graw Hill Internationnal; New York, 1977, p 946-7 and references cited therein.
16. -3 mole of dibromocompound 1 are mixed with bentonite (2g) and triethylamine (1eq) is added at room temperature. The reaction mixture was stirred for 30 minutes, under microwave irradiation. After usual work up, the products were identified by their spectroscopic data.