A bridged spiro[6.6]silatridecane via double 7-endo radical cyclisation

Tetrahedron

Volumn 54, Issue 36, 1998, Pages 10699-10702

  Teng, Zhu ^a   Keese, Reinhart ^a   Stoeckli Evans, Helen ^b  

^a UNIVERSITY OF BERN   (Switzerland)

^b UNIVERSITY OF NEUCHÂTEL   (Switzerland)

Author keywords

Disilacycloheptanes; Radical cyclisations; Si heterocycles; Silacyclopentadiene

Indexed keywords

DECANE; SILANE; SPIRO[6.6]SILATRIDECANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CYCLIZATION; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; X RAY ANALYSIS;

EID: 0032480399     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(98)00620-6     Document Type: Article

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16. 3, Z. = 8 (two independent molecules per asymmetric unit), R1 = 0.032, wR2 = 0.059 (7020 obsd, reflections). Stoe Image Plate Diffraction System; Structure solution and refinement: SHELXS & SHELXL (G. Sheldrick, 1997, University of Göttingen). The full data for the X-ray crystal structure have been deposited at the Cambridge Crystallographic Data Centre.