Highly enantioselective one-pot synthesis of chiral tri- and tetrasubstituted ferrocenes from 1,1'-ferrocenedicarbaldehyde

Angewandte Chemie - International Edition

Volumn 37, Issue 12, 1998, Pages 1698-1701

  Iftime, Gabriel ^a   Daran, Jean Claude ^a   Manoury, Eric ^a   Balavoine, Gilbert G A ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

Asymmetric synthesis; Chirality; Iron; Metallocenes; Metallocenophanes

Indexed keywords

EID: 0032479521     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980703)37:12<1698::AID-ANIE1698>3.0.CO;2-D     Document Type: Article

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30. max -0.37/0.56; Flack's parameter = 0.00(3). The structures of 5 and 8 were solved with the programs SIR92 and CRYSTALS. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100 607. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+ 44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
31. 2-symmetric disubstituted ferrocenophanes have already been described: a) J. A. Winstead, R. R. McGuire, R. E. Cochoy, A. D. Brown, Jr., G. J. Gauthier, J. Org. Chem. 1972, 37, 2055; b) R. C. Fetter, C. I. Milberg, Tetrahedron Lett. 1989, 3, 5085; c) D. L. Compton, T. B. Rauchfuss. Organometallics 1994, 73, 4367.
32. 2-symmetric disubstituted ferrocenophanes have already been described: a) J. A. Winstead, R. R. McGuire, R. E. Cochoy, A. D. Brown, Jr., G. J. Gauthier, J. Org. Chem. 1972, 37, 2055; b) R. C. Fetter, C. I. Milberg, Tetrahedron Lett. 1989, 3, 5085; c) D. L. Compton, T. B. Rauchfuss. Organometallics 1994, 73, 4367.
33. 2-symmetric disubstituted ferrocenophanes have already been described: a) J. A. Winstead, R. R. McGuire, R. E. Cochoy, A. D. Brown, Jr., G. J. Gauthier, J. Org. Chem. 1972, 37, 2055; b) R. C. Fetter, C. I. Milberg, Tetrahedron Lett. 1989, 3, 5085; c) D. L. Compton, T. B. Rauchfuss. Organometallics 1994, 73, 4367.
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