Synthesis and properties of lanthanum-pyrene complexes - Structure of [Cp*La)3(μ-Cl)3(thf)(μ-η2:η6:η6-C16H10)], the first complex with a pyrene trianion

Angewandte Chemie - International Edition

Volumn 37, Issue 20, 1998, Pages 2886-2888

  Thiele, Karl Heinz ^a   Bambirra, Sergio ^a   Sieler, Joachim ^a   Yelopek, Svea ^a  

^a MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

Author keywords

Arene complexes; Lanthanum; Metallocenes; Structure elucidation

Indexed keywords

LANTHANUM; PYRENE DERIVATIVE;

ARTICLE; CHEMICAL BINDING; COMPLEX FORMATION; CRYSTAL STRUCTURE; ORGANIC CHEMISTRY; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 0032476791     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19981102)37:20<2886::AID-ANIE2886>3.0.CO;2-G     Document Type: Article

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21. 3, ω-0 scans, 7409 measured reflections in the range 0 = 1.69-25.02°, of which 7409 were independent and used for refinement. All C, O, Cl, and La layers were refined anisotropically, the H centers in calculated positions isotropically, R values: for [F > 2σ(F)] R1 = 0.0397, wR2 = 0.1413. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100445. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: int. code+ (44) 1223-336033; e-mail: deposit@ccdc.cam.ac.uk).
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