Platinum catalyzed oxidation of carbon monoxide as a model reaction in mass transfer measurements

Chemical Engineering Science

Volumn 53, Issue 19, 1998, Pages 3355-3366

  Venderbosch, R H ^a   Prins, W ^a   Van Swaaij, W P M ^a  

^a UNIVERSITY OF TWENTE   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CATALYSIS; CHEMICAL VARIABLES CONTROL; HYDRODYNAMICS; MASS TRANSFER; MATHEMATICAL MODELS; OXIDATION; PLATINUM; TEMPERATURE;

LANGMUIR-HINSHELWOOD KINETICS; MASS TRANSFER MEASUREMENT; REACTION RATE CONTROL; SHERWOOD NUMBER;

CARBON MONOXIDE;

CARBON MONOXIDE; FLUIDIZED BED; OXIDATION; PACKED BED; PLATINUM;

EID: 0032476196     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(98)00151-1     Document Type: Article

References (33)

1. Aris, R. (1975) The Mathematical Theory of Diffusion and Reaction in Permeable Catalysts, Clarendon Press, Oxford.
2. Beusch, H., Fieguth, P. and Wicke, E. (1972) Thermisch und kinetisch verursachte instabilitäten im reaktionsverhalten einzelner katalysatorkörner. Chemie Ing. Technol. 44, 445.
3. Bischoff, K. B. (1965) Effectiveness factors for general reaction rate forms. A.I.Ch.E. J. 11, 352.
4. Burban, P. M., Schuit, G. C. A., Koch T. A. and Bischoff, K. B. (1990) Kinetics and characterization of bismuth molybdate catalysts. J. Catal. 126, 317.
5. Campman, M. (1996) Kinetics of carbon monoxide oxidation over supported platinum catalysts: the role of steam in the presence of ceria. Thesis University of Eindhoven, the Netherlands.
6. Cant, N. W., Hicks, P. C. and Lennon, B.S. (1978) Steady state oxidation of carbon monoxide over supported noble metals with particular reference to platinum. J. Catal. 54, 372.
7. Froment, G. F. and Bischoff, K. B. (1990) Chemical Reactor Analysis and Design. Wiley, New York.
8. 3. Ind. Engng. Chem. Res. 26, 2099.
9. Hegedus, L. L., Oh, S. H. and Baron, K. (1977) Multiple steady states in an isothermal, integral reactor: the catalytic oxidation of carbon monoxide over platinum-alumina. A.I.Ch.E. J. 23, 632.
10. Herskowitz, M. and Kenny, C. N. (1983) Kinetics and multiple steady states. Can. J. Chem. Engng. 61, 194.
11. Hlavácek, V. and Votruba, J. (1974) Experimental study of multiple steady states in adiabatic catalytic systems. Advances in Chemistry Series, Chemical Reaction Engineering II, Evaston.
12. Hsiung, T. H. and Thodos, G. (1977) Mass-transfer in gas-fluidized beds: measurement of actual driving forces. Chem. Engng. Sci. 32, 581.
13. Kumar, H. B., Sublette, K. L. and Shah, Y. T. (1993) Effect of high voidage on mass transfer coefficients in a fluidized bed. Chem. Engng. Comm. 121, 157.
14. Kunii, D. and Levenspiel, O. (1990) Fluidization Engineering. Wiley, New York.
15. 2 catalysts: rapid FTIR Transient studies. J. Catal. 110, 319.
16. Morbidelli, M. and Varma, A. (1983) Isothermal diffusion-reaction in a slab catalyst with bimolecular Langmuir-Hinshelwood kinetics. Chem. Engng Sci. 38, 289.
17. Nicholas, D. M. and Shah, Y. T. (1976) Carbon monoxide oxidation over a platinum-porous fiber glass supported catalyst. Ind. Engng. Chem. Prod. Res. Dev. 15, 35.
18. Oh, S. H. and Cavendish, J. C. (1982) Transients of monolithic catalytic converters: response to step changes in feedstream temperature as related to controlling automobile emissions. Ind. Engng. Chem. Prod. Res. Dev. 21, 29.
19. Petersen, E. E. (1965) Chemical Reaction Analysis, Prentice-Hall, Englewood Cliffs, NJ, p. 194.
20. Psyllos, A., Papayannakos, N. and Philippopoulos, C. (1994) CO oxidation in a Carberry reactor: manifestation of reaction kinetics by controlled reaction/transport. J. Chem. Engng Japan 27, 693.
21. Resnick, W. and White, R.R (1949) Mass transfer in systems of gas and fluidized solids. Chem. Engng Prog. 45, 377.
22. Roberts, G. W. and Satterfield, C. N. (1966) Effectiveness factor for porous catalysts. Ind. Engng Chem. Fundam. 5, 317.
23. 2O system. Ind. Engng Chem. Prod. Res. Dev. 24, 512.
24. Van der Ham, A. G. J., Prins, W. and van Swaaij, W. P. M. (1991) Hydrodynamics and mass transfer in a regularly packed circulating fluidized bed, in Circulating Fluidized Bed Technology III, Pergamom Press, New York, p. 605.
25. Van der Ham, A. G. J., Prins, W. and van Swaaij, W. P. M. (1994) Regenerative, high temperature desulfurization of coal gas in a circulating fluidized bed, in Circulating Fluidized Bed Technology IV, Pennsylvania, Engineering Foundation, p. 657.
26. Venderbosch, R. H., Prins, W. and van Swaaij, W. P. M. (1998a). The role of clusters in gas-solids reactors: an experimental study. Thesis Twente University, Enschede, ISBN 9036510945, The Netherlands. Available at the internet site http://www.ub. utwente.nl/webdoc/docs/ct.shtml..
27. Venderbosch, R. H., Prins, W. and van Swaaij, W. P. M. (1998b) Influence of the local catalyst activity on the conversion in a riser reactor. Proceedings of the Ninth Engineering Foundation Conference on Fluidization, 16-23 May, Durango, Col., p. 669.
28. Venderbosch, R. H., Prins, W. and van Swaaij, W. P. M. (1997) Mass transfer in the riser of a small circulating fluidized bed reactor. Preprints of the Proceedings of the first European Congress on Chemical Engineering ECCE-1, 4-7 May, Firenze.
29. Vollert, J. and Werther, J. (1994) Mass transfer and reaction behaviour of a circulating fluidized bed reactor. Chem. Engng. Technol. 17, 201.
30. Voltz, S. E., Morgan, C. R., Liederman, D. and Jacob, S. M. (1973) Kinetic study of carbon monoxide and propylene oxidation on platinum catalysts. Ind. Engng. Chem. Prod. Res. Dev. 21, 294.
31. Weisz, P. B. and Hicks, J. S. (1962) The behavior of porous catalyst particles in view of internal mass and heat diffusion effects. Chem. Engng. Sci. 17, 265.
32. Westerterp, K. R., van Swaaij, W. P. M. and Beenackers A.A.C.M. (1987) Chemical reactor design and operation, Wiley, New York.
33. Yu Yao, Y.-F. (1984) The oxidation of CO and Hydrocarbons over noble metal catalysts. J. Catal. 87, 152.