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85034479977
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In ref 8 an alternative fluorescence method obtained a partition coefficient of pyrene in similar PS-PMA micelles approximately twice that obtained in this study.
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buffer = 3.7 ± 0.4 mM, both of which are slightly different than the values in Table 1. These differences illustrate the accuracy of our method when applied to very dilute solutions.
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85034474722
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This is also found in the independent experiments reported in ref 8.
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85034463781
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85034484813
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2} from ref 25, eq 6.20, where M(t) corresponds to the total amount of probe inside the sphere.
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56
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85034486254
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note
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Of course pyrene and phenathrene are not what one would normally think of as good solvents. Undoubtedly very significant plasticization would be observed with species such as benzene.
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57
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85034471273
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85034460356
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2/s. The micelle loading procedure for the present studies was different from that for the earlier work, but it is not clear why this would affect the diffusion constant.
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