Iterative Nucleophilic and Electrophilic Additions to Coordinated Cyclooctatetraene: An Efficient Route to cis-5,7-Disubstituted 1,3-Cyclooctadienes

Angewandte Chemie - International Edition

Volumn 37, Issue 4, 1998, Pages 520-522

  Heck, Jürgen ^a   Lange, Gerhard ^a   Reimelt, Oliver ^a  

^a UNIVERSITY OF HAMBURG   (Germany)

Author keywords

Cyclooctadiene; Cyclooctatetraene; Nucleophilic additions; Ruthenium; Stereoselective synthesis

Indexed keywords

EID: 0032473372     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980302)37:4<520::AID-ANIE520>3.0.CO;2-5     Document Type: Article

References (29)

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27. a) For isomers which differ only in the order, but not in the number of connectivities of the ligand atoms to the central atom, we suggest the term hapticity isomers (haptomers). We were able to demonstrate the formation of 1,2,3-η:6,7-η-haptomers based on the crystal structure analysis of a vinyl-substituted cyclooctatrienyl Ru complex; [12b] the half-life of 2 a in solution at 60°C is about 15 h;
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