S4NR (R = Methyl, n-Octyl) as Novel Chelating Ligands in Titanocene Complexes and First Synthesis of Small Sulfurimide Heterocycles SnNR (n = 5, 6)

Angewandte Chemie - International Edition

Volumn 37, Issue 4, 1998, Pages 492-494

  Steudel, Ralf ^a   Schumann, Oliver ^a   Buschmann, Jürgen ^b   Luger, Peter ^b  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

Author keywords

Heterocycles; Nitrogen; Sulfur; Titanium

Indexed keywords

EID: 0032473365     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19980302)37:4<492::aid-anie492>3.3.co;2-1     Document Type: Article

References (25)

1. a) K. Bergemann, M. Kustos, P. Krüger, R. Steudel, Angew. Chem. 1995, 107, 1481; Angew. Chem. Int. Ed. Engl. 1995, 34, 1330.
2. a) K. Bergemann, M. Kustos, P. Krüger, R. Steudel, Angew. Chem. 1995, 107, 1481; Angew. Chem. Int. Ed. Engl. 1995, 34, 1330.
3. b) R. Steudel, M. Kustos, V. Münchow, U. Westphal, Chem. Ber. 1997, 130, 757.
4. R. Steudel, K. Bergemann, J. Buschmann, P. Luger, Angew. Chem. 1996, 108, 2641; Angew. Chem. Int. Ed. Engl. 1996, 35, 2537.
5. R. Steudel, K. Bergemann, J. Buschmann, P. Luger, Angew. Chem. 1996, 108, 2641; Angew. Chem. Int. Ed. Engl. 1996, 35, 2537.
6. Reviews on cyclic S-N compounds: H. G. Heal, The Inorganic Heterocyclic Chemistry of Sulfur, Nitrogen and Phosphorus, Academic Press, London, 1980; T. Chivers in The Chemistry of Inorganic Homo- and Heterocycles, Vol. 2, (Eds.: I. Haiduc, D. B. Sowerby), Academic Press, London 1987, p. 793.
7. Reviews on cyclic S-N compounds: H. G. Heal, The Inorganic Heterocyclic Chemistry of Sulfur, Nitrogen and Phosphorus, Academic Press, London, 1980; T. Chivers in The Chemistry of Inorganic Homo- and Heterocycles, Vol. 2, (Eds.: I. Haiduc, D. B. Sowerby), Academic Press, London 1987, p. 793.
8. Reviews on sulfur homocycles: R. Steudel, Top. Curr. Chem. 1982, 102, 149; R. Laitinen, P. Pekonen, R. J. Suontamo, Coord. Chem. Rev. 1994, 130, 1.
9. Reviews on sulfur homocycles: R. Steudel, Top. Curr. Chem. 1982, 102, 149; R. Laitinen, P. Pekonen, R. J. Suontamo, Coord. Chem. Rev. 1994, 130, 1.
10. Review on organic polysulfides: R. Steudel, M. Kustos, Encyclopedia of Inorganic Chemistry, Vol. 7 (Ed.: B. King), Wiley, Chichester, 1994, p. 4009.
11. 2 and primary amines in tert-bulyl methyl ether.
12. 2], containing a six-membered metallacycle with the sequence TiSSNSN: C. G. Marcellus, R. T. Oakley, W. T. Pennington, A. W. Cordes, Organometallics 1986, 5, 1395;
13. b) review on transition metal complexes of inorganic sulfur-nitrogen ligands: T. Chivers, F. Edelmann, Polyhedron 1986, 5, 1661.
14. -3. Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany (fax: (+49) 7247-808-666 (Frau S. Höhler-Schlimm); e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository number CSD-407339.
15. E. F. Epstein, I. Bernal, J. Organomet. Chem. 1971, 26, 229.
16. R. Steudel, B. Holz, J. Pickardt, Angew. Chem. 1989, 101, 1301; Angew. Chem. Int. Ed. Engl. 1989, 28, 1269.
17. R. Steudel, B. Holz, J. Pickardt, Angew. Chem. 1989, 101, 1301; Angew. Chem. Int. Ed. Engl. 1989, 28, 1269.
18. 9NH: ref. [1a].
19. Y. Drozdova, R. Steudel, Phosphorus, Sulfur, Silicon, in press.
20. On the HPLC analysis of sulfur-nitrogen heterocycles see: R. Steudel, D. Rosenbauer, J. Chromatogr. 1981, 216, 399.
21. 7NMe: B. A. Olsen, F. P. Olsen, Inorg. Chem. 1969, 8, 1739.
22. M. Schmidt, B. Block, H. D. Block, H. Köpf, E. Wilhelm, Angew. Chem. 1968, 80, 660; Angew. Chem. Int. Ed. Engl. 1968, 7, 660; reviews on ligand transfer reactions: R. Steudel, M. Kustos, M. Pridöhl, U. Westphal, Phosphorus, Sulfur, Silicon 1994, 93/94, 61; R. Steudel in The Chemistry of Inorganic Ring Systems, (Ed.: R. Steudel), Elsevier, Amsterdam 1992, p. 233
23. M. Schmidt, B. Block, H. D. Block, H. Köpf, E. Wilhelm, Angew. Chem. 1968, 80, 660; Angew. Chem. Int. Ed. Engl. 1968, 7, 660; reviews on ligand transfer reactions: R. Steudel, M. Kustos, M. Pridöhl, U. Westphal, Phosphorus, Sulfur, Silicon 1994, 93/94, 61; R. Steudel in The Chemistry of Inorganic Ring Systems, (Ed.: R. Steudel), Elsevier, Amsterdam 1992, p. 233
24. M. Schmidt, B. Block, H. D. Block, H. Köpf, E. Wilhelm, Angew. Chem. 1968, 80, 660; Angew. Chem. Int. Ed. Engl. 1968, 7, 660; reviews on ligand transfer reactions: R. Steudel, M. Kustos, M. Pridöhl, U. Westphal, Phosphorus, Sulfur, Silicon 1994, 93/94, 61; R. Steudel in The Chemistry of Inorganic Ring Systems, (Ed.: R. Steudel), Elsevier, Amsterdam 1992, p. 233
25. M. Schmidt, B. Block, H. D. Block, H. Köpf, E. Wilhelm, Angew. Chem. 1968, 80, 660; Angew. Chem. Int. Ed. Engl. 1968, 7, 660; reviews on ligand transfer reactions: R. Steudel, M. Kustos, M. Pridöhl, U. Westphal, Phosphorus, Sulfur, Silicon 1994, 93/94, 61; R. Steudel in The Chemistry of Inorganic Ring Systems, (Ed.: R. Steudel), Elsevier, Amsterdam 1992, p. 233