Arsenic in fumarolic gases of Vulcano (Aeolian Islands, Italy) from 1978 to 1993: Geochemical evidence from multivariate analysis

Geochemical Journal

Volumn 32, Issue 6, 1998, Pages 367-382

  Signorelli, Stefano ^a   Buccianti, Antonella ^a   Martini, Marino ^a   Piccardi, Giovanni ^a  

^a UNIVERSITY OF FLORENCE   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ARSENIC; FUMAROLE; GEOCHEMISTRY; MONITORING; MULTIVARIATE ANALYSIS; VOLCANIC GAS;

ITALY; SICILY; VULCANO;

EID: 0032455910     PISSN: 00167002     EISSN: None     Source Type: Journal    
DOI: 10.2343/geochemj.32.367     Document Type: Article

References (65)

1. Aitchison, J. (1981) A new approach to null correlations of proportions. J. Math. Geol. 13, 175-189.
2. Aitchison, J. (1982) The statistical analysis of compositional data (with discussion). Jour. Roy. Stat. Soc. 44, 139-177.
3. Ballantyne, J. M. and Moore, J. N. (1988) Arsenic geochemistry in geothermal systems. Geochim. Cosmochim. Acta 52, 475-483.
4. Barberi, F., Innocenti, F., Ferrara, G., Keller, J. and Villari, L. (1974) Evolution of Aeolian arc volcanism (Southern Tyrrhenian Sea). Earth Planet. Sci. Lett. 21, 269-276.
5. Bettinelli, M., Baroni, U. and Pastorelli, N. (1988) Determination of As, Cd, Pb, Sb, Se and T1 in coal fly ash using STPF and Zeeman-effect background correction. J. Anal. At. Spectrom. 3, 1005-1011.
6. Boyle, R. W. and Jonasson, I. R. (1973) The geochemistry of arsenic and its use as an indicator element in geochemical prospecting. J. Geochem. Expl. 2, 251-296.
7. Brondi, M. and Dall'Aglio, M. (1991) Evolution of mercury, arsenic, antimony, radon and helium contents in ground waters and fumaroles since 1983 through 1989 at vulcano Island (Southern Italy). Acta Vulcanol. 1, 233-241.
8. Brondi, M., Dall'Aglio, M. and Ghiara, E. (1986a) Elementi in traccia di interesse geochimico e tossicologico nei fluidi termali e geotermici dei Campi Flegrei e di Larderello. Acqua-Aria 10, 1103-1111.
9. Brondi, M., Dall'Aglio, M. and Ghiara, E. (1986b) Mercury, arsenic, lithium, radon and helium in geothermal fluids from the Larderello and Campi Flegrei areas. I.A.C.C. Proceedings of 5th International Symposium on Water Rock Interaction, Reykjavik, Iceland, August 8-10, 84-87.
10. Buccianti, A. and Martini, M. (1994) Techniques of multivariate analysis to investigate volcanic systems. Papers and Estended Abstracts of the International Association for Mathematical Geology, Mont Tremblant, Canada, 44-49.
11. Carapezza, M., Nuccio, P. M. and Valenza, P. M. (1981) Genesis and evolution of the fumaroles of Vulcano (Aeolian Islands, Italy): a geochemical model. Bull. Volcanol. 44, 547-564.
12. Cavarretta, G., Giannelli, G., Scandiffio, G. and Tecce, F. (1985) Evolution of the Latera geothermal system. II. Metamorphic, hydrothermal mineral assemblages and fluid chemistry. J. Volcanol. Geother. Res. 26, 337-367.
13. Cellini Legittimo, P. and Martini, M. (1989) The ecological significance of the coexistence of sulphur dioxide and hydrogen sulphide in volcanic fumaroles. Chem. Ecol., 4, 15-20.
14. Chayes, F. (1960) On correlation between variables of constant sum. J. Geophys. Res. 65, 4185-4193.
15. Chiodini, G., Cioni, R., Falsaperla, S., Montalto, A., Marini, L. and Guidi, M. (1992). Geochemical and seismological investigations at Vulcano (Aeolian Islands) during 1978-1989. J. Geophys. Res. 97, 11025-11032.
16. Cioni, R. and D'Amore, F. (1984) A genetic model for the crater fumaroles of Vulcano Island (Sicily, Italy). Geothermics 13, 375-384.
17. Cullen, W. R. and Reimer, K. J. (1989) Arsenic speciation in the environment. Chem. Rev. 89, 713-764.
18. Dillon, W. R. and Goldstein, M. (1984) Multivariate Analysis, Methods and Applications. John Wiley & Sons, 587 pp.
19. Francis, P., Maciejewski, A., Oppenheimer, C. and Chaffin, C. (1996) New methods make volcanology research less hazardous. EOS 77(41), 393-397.
20. Gemmel, B. J. (1987) Geochemistry of metallic trace elements in fumarolic condensates from nicaraguan and costa rican volcanoes. J. Volcanol. Geotherm. Res. 33, 161-181.
21. Giggenbach, W. F. (1975) A simple method for the collection and analysis of volcanic gas samples. Bull. Volcanol. 39, 132-145.
22. Gnanadesikan, R. (1977) Methods for Statistical Data Analysis of Multivariate Observations. John Wiley, New York, 311 pp.
23. Greenland, L. P. and Aruscavage, P. (1986) Volcanic emission of Se, Te, and As from Kilauea volcano, Hawaii. J. Volcanol. Geotherm. Res. 27, 195-201.
24. Harako, A. (1986) Arsenic in environment around the Osorezan volcano region. III As in soil. Hirosaki Igaku 38, 232-243.
25. Ingle, J. D., Jr. (1974) Sensitivity and limit of detection in quantitative spectrometric methods. J. Chem. Education 51, 100-105.
26. Kabata-Pendias, A. and Pendias, H. (1985) p. 171-176. Trace Elements in Soils and Plants. CRC Press, Inc., Boca Raton, Florida.
27. Kanamori, S. and Sugawara, K. (1965) Geochemical study of arsenic in natural water. I. Arsenic in rain and snow. J. Earth Sci., Nagoya Univ. 13, 23-35.
28. Koga, A. and Noda, T. (1975) Geochemical prospecting in vapour-dominated fields for geothermal exploration. Proc. 2nd U.N. Simp. Development and Use of Geothermal Resources, 761-766.
29. Krzanowski, W. J. (1988) Principles of Multivariate Analysis, a User's Perspective. Oxford statistical science series 3, Oxford Science Publications, 563 pp.
30. Lacroix, A. M. (1907) Les minéraux des fumerolles de l'éruption du Vésuve en Avril 1906. Bull. Soc. Fr. Min. 30, 219-266.
31. Long, G. L. and Winefordner, J. D. (1983) Limit of detection, a closer look of the IUPAC definition. Anal. Chem. 55, 712A-724A.
32. Long-Zhu, J., Xiao-Quan, S. and Zhe-Ming, N. (1981) Matrix modification of volatile elements of As, Se, Te, Ag, Sb, and Bi by graphite furnace atomic absorption spectrometry. Huaxue Xuebao 39, 575-578.
33. Mambo, V. S. and Yoshida, M. (1993) Behaviour of arsenic in volcanic gases. Geochem. J. 27, 351-359.
34. Mambo, V. S., Yoshida, M. and Matsuo, S. (1991) Partition of arsenic and phosphorus between volcanic gases and rock. Part I: analytical data and magmatic conditions of Mt. Usu, Japan. J. Volcanol. Geother. Res. 46, 37-47.
35. Martini, M. (1980) Geochemical survey on the phreatic waters of Vulcano (Aeolian Islands, Italy). Bull. Volcanol. 43, 265-274.
36. Martini, M. (1993) Water and fire: Vulcano island from 1977 to 1991. Geochem. J. 4/5, 297-303.
37. Martini, M., Piccardi, G. and Cellini Legittimo, P. (1980) Geochemical surveillance of active volcanoes: data on the fumaroles of Vulcano (Aeolian Islands, Italy). Bull. Volcanol. 44, 109-113.
38. Mazor, E., Cioni, R., Corazza, E., Fratta, M., Magro, G., Matsuo, S., Hirabayashi, J., Shinohara, H., Martini, M., Piccardi, G. and Cellini-Legittimo, P. (1988) Evolution of fumarolic gases-boundary conditions set by measured parameters: case study at Vulcano, Italy. Bull. Volcanol. 50, 71-85.
39. Menyailov, I. A. and Nikitina, L. P. (1980) Chemistry and metal contents of magmatic gases: the new Tolbachik volcanoes case (Kamchatka). Bull. Volcanol. 43, 197-205.
40. Menyailov, I. A., Nikitina, L. P. and Schapar, V. N. (1980) Geokhimicheskie osobebennosti eksalatsii bolschogo treschchinnogo Tol' bachinskogo izverwheniya. Nauka Moskow.
41. Menyailov, I. A., Nikitina, L. P., Schapar, V. N. and Miklishanskii, A. Z. (1982) The role of active volcanism in enrichment of the atmosphere in chalcophile elements. J. Geophys. Res. 87, 11113-11118.
42. Miklishanskii, A. Z., Yakvlev, Yu. V., Menyailov, I. A., Nikitina, L. P. and Savel'ev, B. V. (1979) Geochemical role of the entry of chemical elements with the volatile component of active volcanism. Geochem. Int. 16, 33-40.
43. Montalto, A. (1996) Signs of potential renewal of eruptive activity at La Fossa (Vulcano, Aeolian Islands). Bull. Volcanol. 57, 483-492.
44. Murata, K. J. (1966) The 1959-60 eruption of Kilauea volcano, Hawaii. An acid fumarolic gas from Kilauea Iki, Hawaii. U.S. Geol. Surv. Prof. Pap. 537-C, C1-C6.
45. Norusis, M. J. (1994) SPSS Professional Statistics 6.1 Reference Manual, 47-81.
46. Nriagu, J. O. (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338, 47-49.
47. Nriagu, J. O. and Pacyna, J. M. (1988) Quantitative assessment of worldwide contamination of air, water and soils by trace metals. Nature 333, 134-139.
48. Ozawa, T., Yoshida, M. and Jiwadi, P. (1974) Minor composition of volcanic gases from Satsuma-Iwojima. Part 1: content of alkali metals, iron and arsenic. Annual Meeting of the Geochemical Society of Japan, Gakushuin University, Tokyo.
49. Pearson, K. (1897) On a form of spurious correlation which may arise when indices are useed in the measurement of organs. Royal Soc., London, Proc. 60, 489-502.
50. Penrose, W. R., Conacher, H. B. S., Black, R., Meraner, J. C., Miles, W., Cunningham, H. M. and Squires, W. R. (1977) Implications of inorganic/organic interconversion on fluxes of arsenic in marine food webs. Environ. Health Perspect 19, 53-59.
51. Piccardi, G. (1982) Fumaroles gas collection and analysis. Bull. Volcanol. 45, 257-260.
52. Quisefit, J. P., Toutain, J. P., Bergametti, G., Javoy, M., Cheynet, B. and Person, A. (1989) Evolution versus cooling of gaseous volcanic emission from Momotombo Volcano, Nicaragua: thermochemical model and observations. Geochim. Cosmochim. Acta 53, 2591-2608.
53. Reed, M. J. and Campbell, G. E. (1975) Environmental impact of development in The Geysers geothermal field, U.S.A. Proc. 2nd U.N. Symp. Development and Use of Geohermal Resources 2, 1399-1410.
54. Robertson, D. E., Fruchter, J. S., Lundwick, J. D., Wilkenson, C. L., Crecelius, E. A. and Evans, J. C. (1978) Chemical characterisation of gases and volatile heavy metals in geothermal effluents. A Novelty Becomes a Resource: Geothermal Resource Council Trans. 2, 579-582.
55. Sakamoto, H. (1985) The distribution of mercury, arsenic, and antimony in sediments of Kagoshima bay. Bull. Chem. Soc. Jpn. 58, 580-587.
56. Schlemmer, G. and Welz, B. (1986) Palladium and magnesium nitrates, a more universal modifier for graphite furnace atomic absorption spectrometry. Spectrochim. Acta 41B, 1157-1165.
57. Signorelli, S. (1993) Distribuzione di arsenico in aree di vulcanismo attivo. Tesi di Laurea, Universita' di Firenze, 152 pp.
58. Signorelli, S. (1997) Arsenic in volcanic gases. Environ. Geol. 32(4), 239-244.
59. Sugiura, T., Mizutani, Y. and Oana, S. (1963) Fluorine, chlorine, bromine and iodine in volcanic gases. J. Earth Sci. Nagoya Univ. 11, 272-278.
60. Symonds, R. B., Rose, W. I., Reed, M. H., Lichte, F. E. and Finnegan D. L. (1987) Volatilization, transport and sublimation of metallic and non-metallic elements in high temperature gases at Merapi Volcano, Indonesia. Geochim. Cosmochim. Acta 51, 2083-2101.
61. Takahashi, K. and Oana, S. (1957) Report on the geological, geophysical and geochemical studies of Showa-shinzan, Usu volcano. Geol. Survey Japan Rept. 170, 122-123.
62. Thompson, J. M. (1985) Chemistry of thermal and non thermal springs in the vicinity of Lassen volcanic national park. J. Volcanol. Geotherm. Res. 25, 81-104.
63. Toutain, J. P. (1987) Contribution à l'étude des sublimés volcaniques. Minéralogie, géoquimie, thermodinamique. Examples du Momotombo, du Piton de la Fournaise et du Poas. Thèse de doctorat, Université Paris 6.
64. Welz, B., Schlemmer, G. and Mudakavi, J. R. (1988a) Palladium nitrate-Magnesium nitrate modifier for graphite furnace atomic absorption spectrometry. Part 1. Determination of As, Sb, Se and T1 in airborne particulate matter. J. Anal. At. Spectrom. 3, 93-97.
65. Welz, B., Schlemmer, G. and Mudakavi, J. R. (1988b) Palladium nitrate-Magnesium nitrate modifier for graphite furnace atomic absorption spectrometry. Part 2. Determination of As, Cd, Cu, Mn, Pb, Sb, Se and T1 in water. J. Anal. At. Spectrom. 3, 695-701.