Structural changes in sodium tetrasilicate glass around the liquid-glass transition: A neutron diffraction study

Physics and Chemistry of Minerals

Volumn 26, Issue 2, 1998, Pages 107-110

  Zotov, N ^a   Delaplane, R G ^a   Keppler, H ^a  

^a UNIVERSITÄT BAYREUTH   (Germany)

Author keywords

Glass transition; Neutron diffraction; Silicate glasses

Indexed keywords

GLASS; LIQUID; NEUTRON DIFFRACTION; PHASE TRANSITION; SILICATE; SODIUM;

EID: 0032422946     PISSN: 03421791     EISSN: None     Source Type: Journal    
DOI: 10.1007/s002690050166     Document Type: Article

References (19)

1. Brown GE Jr, Farges F, Calas G (1995) X-ray scattering and X-ray spectroscopy studies of silicate melts. In: Stebbins JF, McMillan PF, Dingwell DB (eds) Structure, dynamics, and properties of silicate melts (Reviews in Mineralogy vol. 32). Mineralogical Society of America, Washington DC, pp 317-401
2. Dingwell DB (1995) Relaxation in silicate melts: some applications. In: Stebbins JF, McMillan PF, Dingwell DB (eds) Structure, dynamics, and properties of silicate melts (Reviews in Mineralogy vol. 32). Mineralogical Society of America, Washington DC, pp 21-63
3. Elliot SR (1995) Extended-range order, interstitial voids and the first sharp diffraction peak of network glasses. J Non-Cryst Solids 182:40-48
4. 3 above and below the glass transition temperature. NFL Experimental Report: SLAD14-SLAD15
5. Haller W, Blackburn DH, Simmons JH (1974) Miscibility gaps in alkali-silicate binaries - data and thermodynamic interpretation. J Am Ceram Soc 57:120-126
6. Howe MA, McGreevy RL (1995) CORRECT: a correction program for neutron diffraction data, Version 2.18
7. 5. Geochim Cosmochim Acta 61:2569-2575
8. McMillan PF, Wolf GH (1995) Vibrational spectroscopy of silicate liquids. In: Stebbins JF, McMillan PF, Dingwell DB (eds) Structure, dynamics, and properties of silicate melts (Reviews in Mineralogy vol. 32). Mineralogical Society of America, Washington DC, pp 247-308
9. McMillan PF, Wolf GH, Poe BT (1992) Vibrational spectroscopy of silicate liquids and glasses. Chem Geol 96:351-366
10. 2 binary compositions in the temperature range 25-1475°C. Chem Geol 96:321-332
11. Mysen BO, Frantz JD (1994) Silicate melts at magmatic temperatures: in-situ structure determination to 1651°C and the effect of temperature and bulk composition on the mixing behaviour of structural units. Contrib Mineral Petrol 117:1-14
12. Pusztai L, McGreevy RL (1997) MCGR: an inverse method for deriving the pair correlation function from the structure factor. Physica B 234 & 236:357-358
13. Richet P, Bottinga Y, Tequi C (1984) Heat capacity of sodium silicate liquids. Am Ceram Soc Commun 67:C6-C8
14. Stebbins JF (1995) Dynamics and structure of silicate and oxide melts: nuclear magnetic resonance studies. In: Stebbins JF, McMillan PF, Dingwell DB (eds) Structure, dynamics, and properties of silicate melts (Reviews in Mineralogy vol. 32). Mineralogical Society of America, Washington DC, pp 191-239
15. Stebbins JF, Farnan I, Xue X (1992) The structure and dynamics of alkali silicate liquids: a view from NMR spectroscopy. Chem Geol 96:371-385
16. 1.4 from glass to liquid state. Physica B 234 & 236:414-415
17. Wannberg A, Delaplane RG, McGreevy RL (1997) SLAD: the Studsvik disordered materials diffractometer. Physica B 234 & 236:1155-1156
18. 9) glass. J Chem Phys 93:2280-2288
19. Zotov N, Keppler H, Hannon AC, Soper AK (1996) The effect of water on the structure of silicate glasses - a neutron diffraction study. J Non-Cryst Solids 202:153-163