Third order nonlinear optical properties of phthalocyanines and related compounds

Proceedings of SPIE - The International Society for Optical Engineering

Volumn 3473, Issue , 1998, Pages 91-100

  Díaz García, María A ^a   Rojo, Gema ^a   Agulló López, Fernando ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

Nonlinear absorption; Phthalocyanines; Second harmonic generation; Subphthalocyanines; Third harmonic generation; Z scan

Indexed keywords

ELECTRIC FIELD EFFECTS; EVAPORATION; HARMONIC GENERATION; LIGHT ABSORPTION; LIGHT POLARIZATION; OPTICAL PROPERTIES; OPTICAL VARIABLES MEASUREMENT; ORGANIC COMPOUNDS; PHOTONS; RAYLEIGH SCATTERING; THIN FILMS;

ELECTRIC FIELD INDUCED SECOND HARMONIC GENERATION; HYPER-RAYLEIGH SCATTERING; NONLINEAR RESPONSE; PHTHALOCYANINES; THIRD HARMONIC GENERATION; THIRD ORDER NONLINEAR OPTICAL PROPERTIES; Z-SCAN;

NONLINEAR OPTICS;

EID: 0032405042     PISSN: 0277786X     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1117/12.328179     Document Type: Conference Paper

References (24)

1. C. C. Leznoff and A. B. P. Lever, Phthalocyanines: Properties and Applications, Vols. 1-4, VCH Publishers Ltd., Cambridge, 1989, 1993, 1996.
2. H. S. Nalwa and S. Miyata, Nonlinear Optics of Organic Molecules and Polymers, CRC Press, Boca Raton, Florida,, 1997
3. A. Sastre, M. A. Díaz-García, B. del Rey, C. Dhenaut, J. Zyss, I. Ledoux, F. Agulló-López and T. Torres. "Push-Pull Phthalocyanines: A Hammett Correlation between the Cubic Hyperpolarizability and the Donor-Acceptor Character of the Substituents", J. Phys. Chem., 101, pp. 9773-9777, 1997.
4. G. de la Torre, T. Torres and F. Agulló-López. "The phthalocyanine approach to second harmonic generation". Adv. Mater. 9, pp. 265, 1997.
5. M. A. Díaz-García, F. Agulló-López, W.E. Torruellas and G.I. Stegeman. "Identification of two-photon states in phthalocyanines by Third Harmonic Generation spectroscopy". Chem. Phys. Lett. 235, pp. 535-540, 1995.
6. M. A. Díaz-García, J.M. Cabrera, F. Agulló-López, J.A. Duro, G. de la Torre, T. Torres, F. Fernandez-Lazaro, P. Delhaes and D. Mingotaud. "Third-order nonlinear optical susceptibilities of the Langmuir-Blodgett films of octa-substituted metallophthalocyanines". Appl. Phys. Lett. 69, pp. 293-295, 1996.
7. M. A. Díaz-García, I. Ledoux, J.A. Duro, T. Torres, F. Agulló-López and J. Zyss. "Third-order nonlinear optical properties of Soluble Octa-substituted metallophthalocyanines". J. Phys. Chem. 98, pp. 8761-8764, 1994.
8. M. A. Díaz-García, A. Dogariu, D.J. Hagan and E.W. Van Stryland. "Nonlinear absorption of soluble octasubstituted metallophthalocyanines". Chem. Phys. Lett. 266, pp. 86-90, 1996.
9. F. Kajzar and J. Messier. "Original technique for third-harmonic generation in liquids". Rev. Sci. Instrum. 58, pp. 2081, 1987.
10. F. Kajzar and J. Messier., in Nonlinear optical properties of organic molecules and crystals, Vol. 2, pp. 51, Eds. D.S. Chemla and J. Zyss, Academic Press, New York, 1987.
11. B. Orr and J.F. Ward, "Perturbation theory of nonlinear optical polarization of an isolated system". Mol. Phys. 20, pp. 513, 1971.
12. M. Sheik-bahae, A.A. Said, T.H. Wei, D.J. Hagan and E.W. Van Stryland. "Sensitive measurement of optical nonlinearities using a single beam". IEEE J. QE-26, pp. 760-769, 1990.
13. E. Ortí, J.L. Bredas and C. Clarisse. "Electronic structure of phthalocyanines - Theoretical investigation of the optical properties of phthalocyanine monomers, dimers and crystals". J. Chem. Phys. 92, pp. 1228-1235, 1990.
14. B.N. Figgis, in Introduction to ligand fields, pp. 313, Wiley-Interscience, New York, 1966.
15. T.H. Wei, D.J. Hagan, M.J. Sence, E.W. Van Stryland, J.W. Perry and D.R. Coulter. "Direct measurement of nonlinear absorption and refraction in solutions of phthalocyanines". Appl. Phys. B54, pp. 46, 1992.
16. E.A. Guggenheim. Trans. Faraday Soc. 45, pp. 714, 1949.
17. R.W. Terhune, P.D. Maker and C.M. Savage. Phys. Rev. Lett. 14, pp. 681, 1965.
18. A. Sastre, T. Torres, M.A. Díaz-García, Agulló-López, C. Denhaut, S. Brasselet, I. Ledoux and J Zyss. "Subphthalocyanines: Novel Targets for Remarkable Second-Order Optical Nonlinearities". J. Am. Chem. Soc. 118, pp. 2746-2747, 1996.
19. B. del Rey, U. Keller, T. Torres, G. Rojo, F. Agulló-López, S. Nonell, C. Marti, S. Brasselet, I. Ledoux and J. Zyss. "Synthesis, Nonlinear Optical, Photophysical and Electrochemical properties of Subphthalocyanines". Submitted to J. Am. Chem. Soc.
20. M.A. Díaz-García, F. Agulló-López, A. Sastre, T. Torres, W.E. Torruellas and G.I. Stegeman. "Third Harmonic Generation Spectroscopy of Boron Subphthalocyanine". J. Phys. Chem. 99, pp. 14988-14991, 1995.
21. G. Rojo, A. Hierro, M.A. Díaz-García, Agulló-López, B. del Rey, A. Sastre and T. Torres. "Second Harmonic Generation from trinitro-substituted subphthalocyanines films: Evidence of noncentrosymmetric molecular organization". Appl. Phys. Lett. 70, pp. 1802-1804, 1997.
22. G. Rojo, Agulló-López, B. del Rey and T. Torres. "Macroscopic and microscopic second-harmonic response from subphthalocyanine thin films". Submitted to J. Appl. Phys.
23. L. M. Hayden, G.F. Sauter, F.R. Ore, P.L. Pasillas, J.M. Hoover, G.A. Lindsay and R.A. Henry. "Second-order nonlinear optical measurements in guest-host and side-chain polymers". J. Appl. Phys. 68, 456, 1990.
24. P.N. Prasad and D. J. Williams, Introduction to Nonlinear Optical Effects in Molecules and Polymers, Wiley, New York, 1991.