Addition of Grignard and organolithium reagents to the negatively charged sulfur atom of 2,2-bis(diethylamino)ethan-2-ylium-1-dithioate

Chemistry Letters

Volumn , Issue 4, 1998, Pages 321-322

  Nakayama, Juzo ^a   Otani, Takashi ^a   Sugihara, Yoshiaki ^a   Ishii, Akihiko ^a  

^a SAITAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032391518     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.321     Document Type: Article

References (15)

1. a) J. Nakayama and I. Akiyama, J. Chem. Soc., Chem. Commun., 1992, 1522.
2. b) A. Nagasawa, I. Akiyama, S. Mashima, and J. Nakayama, Heteroatom Chem., 6, 45 (1995).
3. c) K. Akimoto and J. Nakayama, Heleroatom Chem., 8, 505 (1997).
4. d) K. Akimoto, K. Masaki, and J. Nakayama, Bull. Chem. Soc. Jpn., 70, 471 (1997).
5. e) K. Akimoto, Y. Sugihara, and J. Nakayama, Bull. Chem. Soc. Jpn., 70, 2555 (1997).
6. For a review, see J. Nakayama, Sulfur Lett., 15, 239 (1993).
7. J. Nakayama, T. Otani, Y. Sugihara, and A. Ishii, Tetrahedron Lett., 38, 5013 (1997).
8. 13C-NMR) and correct elemental analyses were obtained for all new compounds.
9. N. I. Tyryshkin, A. I. Konovalov, V. V. Gavrilov, and N. A. Polezheva, Phos. Sulf. Sil., 109-110, 553 (1996). See also A. Moradopour and S. Bittner, Tetrahedron Lett., 28, 3805 (1987).
10. N. I. Tyryshkin, A. I. Konovalov, V. V. Gavrilov, and N. A. Polezheva, Phos. Sulf. Sil., 109-110, 553 (1996). See also A. Moradopour and S. Bittner, Tetrahedron Lett., 28, 3805 (1987).
11. 2Br).
12. The extent of solvation and aggregation of t-BuM should be responsible for these effects: J. L. Wardell, in "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon, Oxford (1982), Vol. 1, Chapter 2; W. E. Lindsell, in "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon, Oxford (1982), Vol. 1, Chapter 4.
13. The extent of solvation and aggregation of t-BuM should be responsible for these effects: J. L. Wardell, in "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon, Oxford (1982), Vol. 1, Chapter 2; W. E. Lindsell, in "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon, Oxford (1982), Vol. 1, Chapter 4.
14. 2 at room temperature.
15. 4