Hydrogen transfer in Pt-Mo heterodinuclear hydride complexes promoted by alkynes

Chemistry Letters

Volumn , Issue 1, 1998, Pages 29-30

  Yasuda, Toshiyuki ^a   Fukuoka, Atsushi ^a,b   Hirano, Masafumi ^a   Komiya, Sanshiro ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

^b HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032364281     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.29     Document Type: Article

References (12)

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2. For recent reviews: D. W. Stephan, Cood. Chem. Rev., 95, 41 (1989); M.J. Chetculi, "Comprehensive Organometallic Chemistry II," ed by R. D. Adams ed., Pergamon Press, Oxford (1995), vol 10.
3. a) S. Komiya and I. Endo, Chem. Lett., 1988, 1709;
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6. d) A. Fukuoka, T. Sadashima, I. Endo, N. Ohashi, Y. Kambara, T. Sugiura, K. Miki, N. Kasai, and S. Komiya, Organometallics, 13, 4033 (1994);
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9. Such reductive elimination between hydrido and transition metal has been proposed by Braunstein, but the reactions are not clean enough due to many side reactions: O. Bars, P. Braunstein, G. L. Geoffroy, and B. Metz, Organometallics, 5, 2021 (1986).
10. Pt-P = 2701 Hz).
11. w = 0.064, 1666 unique reflections with I > 3σ(I).
12. H. Scordia, R. Kergoat, M. M. Kubicki, and J. E. Guerchais, Organometallics, 2, 1681, (1983).