Measurements of Kleinman-disallowed hyperpolarizability in conjugated chiral molecules

Journal of the Optical Society of America B: Optical Physics

Volumn 15, Issue 1, 1998, Pages 289-301

  Hubbard, S F ^a   Petschek, R G ^a   Singer, K D ^a   D'Sidocky, N ^b   Hudson, C ^b   Chien, L C ^b   Henderson, C C ^c   Cahill, P A ^d  

^a CASE WESTERN RESERVE UNIVERSITY   (United States)

^b KENT STATE UNIVERSITY   (United States)

^c SANDIA NATIONAL LABORATORIES   (United States)

^d SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032359096     PISSN: 07403224     EISSN: None     Source Type: Journal    
DOI: 10.1364/JOSAB.15.000289     Document Type: Article

References (45)

1. K. D. Singer, J. E. Sohn, and S. J. Lalama, "Second harmonic generation in poled polymer films," Appl. Phys. Lett. 49, 248-250 (1986).
2. J. Zyss and I. Ledoux, "Nonlinear optics in multipolar media: theory and experiments," Chem. Rev. 94, 77-105 (1994).
3. R. W. Terhune, P. D. Maker, and C. M. Savage, "Measurements of nonlinear light scattering," Phys. Rev. Lett. 14, 681-684 (1965).
4. B. Hendrickx, C. Dehu, K. Clays, J. L. Bredàs, and A. Persoons, Polymers for Second-Order Nonlinear Optics (American Chemical Society, Washington, D.C., 1994), Chap. 6, p. 601.
5. S. F. Hubbard, R. G. Petschek, and K. D. Singer, "Spectral content and dispersion of hyper-Rayleigh scattering," Opt. Lett. 21, 1774-1778 (1996).
6. P. Kaatz and D. P. Shelton, "Polarized hyper-Rayleigh light scattering measurements of nonlinear optical chromophores," J. Chem. Phys. 105, 3918-3929 (1998).
7. I. D. Morrison, R. G. Denning, W. M. Laidlaw, and M. A. Stammers, "Measurement of first hyperpolarizabilities by hyper-Rayleigh scattering," Rev. Sci. Instrum. 67, 1445-1453 (1998).
8. O. J. F. Noordman and N. F. van Hulst, "Time-resolved hyper-Rayleigh scattering: measuring first hyperpolarizabilities β of fluorescent molecules," Chem. Phys. Lett. 253, 145-150 (1996).
9. J. Zyss, "Octupolar organic systems in quadratic nonlinear optics: molecules and materials," Nonlinear Opt. 1, 3-18 (1991).
10. T. Luo, A. Cesar, and H. Ågren, "The hyperpolarizability of the tricyanomethanide molecular ion in solution," Chem. Phys. Lett. 252, 389-397 (1996).
11. T. Verbiest, K. Clays, C. Samyn, J. Wolff, D. Reinhoudt, and A. Persoons, "Investigations of the hyperpolarizability in organic molecules from dipolar to octopolar systems," J. Am. Chem. Soc. 116, 9320-9323 (1994).
12. M. Joffre, D. Yaron, R. Silbey, and J. Zyss, "Second order optical nonlinearity in octopolar aromatic systems," J. Chem. Phys. 97, 5607-5615 (1992).
13. E. Kelderman, W. A. J. Starmans, J. P. M. Van Duynhoven, W. Verboom, J. F. J. Engersen, D. N. Reinhoudt, T. Verbiest, K. Clays, and A. Persoons, "Triphenylcarbinol derivatives as molecules for second-order nonlinear optics," Chem. Mater. 6, 412-417 (1993).
14. E. Hendrickx, K. Clays, A. Persoons, C. Dehu, and J. L. Bredàs, "The bacteriorhodopsin chromophore retinal and derivatives: an experimental and theoretical investigation of the second-order optical properties," J. Am. Chem. Soc. 117, 3547-3555 (1994).
15. A. Persoons, K. Clays, M. Kauranen, E. Hendrickx, E. Put, and W. Bijens, "Characterization of nonlinear optical properties by hyper-scattering techniques," Synth. Met. 67, 31-38 (1994).
16. P. K. Schmidt and G. W. Rayfield, "Hyper-Rayleigh light scattering from an aqueous suspension of purple membrane," Appl. Opt. 33, 4286-4292 (1994).
17. J. Zyss, T. Chauvan, C. Dhenaut, and I. Ledoux, "Harmonic Rayleigh scattering from nonlinear octupolar molecular media: the case of Crystal Violet," Chem. Phys. 177, 281-296 (1993).
18. C. Denhaut, I. Ledoux, I. D. W. Samuel, J. Zyss, M. Bourgauld, and H. Le Bozec, "Chiral metal complexes with large octupolar optical nonlinearities," Nature (London) 374, 339-342 (1995).
19. J. Zyss, C. Dhenaut, T. Chauvan, and I. Ledoux, "Quadratic nonlinear susceptibility of octupolar chiral ions," Chem. Phys. Lett. 206, 409-414 (1993).
20. S. Stadler, R. Deitrich, G. Bourhill, and C. Bräuchle, "Long- wavelength first hyperpolarizability measurements by hyper-Rayleigh scattering," Opt. Lett. 21, 251-253 (1995).
21. G. J. T. Heesink, A. G. T. Ruiter, N. F. Van Hulst, and B. Bölger, "Determination of hyperpolarizability tensor components by depolarized hyper-Rayleigh scattering," Phys. Rev. Lett. 71, 999-1002 (1993).
22. D. A. Kleinman, "Nonlinear dielectric polarization in optical media," Phys. Rev. 126, 1977-1979 (1962).
23. M. Kozierowski, "Electric-dipole differential hyper- Rayleigh and hyper-Raman scattering of elliptically polarized light," Phys. Rev. A 31, 509-510 (1985).
24. G. Wagniere, "Theoretical investigation of Kleinman symmetry in molecules," Appl. Phys. B 41, 169-172 (1986).
25. R. Wortmann, P. Krämer, C. Glania, S. Lebus, and N. Detzer, "Deviations from Kleinman symmetry of the second-order polarizability tensor in molecules with low- lying perpendicular electronic bands," Chem. Phys. 173, 99-108 (1992).
26. H. S. Nalwa, T. Watanabe, and S. Miyata, "2-d charge- transfer molecules for second order nlo: off-diagonal orientation," Adv. Mater. 7, 754-758 (1995).
27. J. A. Giordmaine, "Nonlinear optical properties of liquids," Phys. Rev. 138, 1599-1606 (1965).
28. P. M. Rentzepis, J. A. Giordmaine, and K. W. Wecht, "Coherent optical mixing in optically active liquids," Phys. Rev. Lett. 16, 792-794 (1966).
29. W. M. McClain, "Polarization dependence of three-photon phenomena for randomly oriented molecules," J. Chem. Phys. 67, 2264-2274 (1972).
30. S. J. Cyvin, J. E. Rauch, and J. C. Decius, "Theory of hyper- Raman effects (nonlinear inelastic light scattering): selection rules and depolarization ratios for the second-order polarizability," J. Chem. Phys. 43, 4083-4095 (1965).
31. R. Bersohn, Y. Pao, and H. L. Frisch, "Double-quantum light scattering by molecules," J. Chem. Phys. 45, 3184-3198 (1966).
32. S. Kielich and M. Kozierowski, "Symmetric and antisymmetric second-harmonic elastic light scattering and its angular dependences," Acta Phys. Pol. A45, 231-251 (1974).
33. P. D. Maker, "Spectral broadening of elastic second- harmonic light scattering in liquids," Phys. Rev. A 1, 923-951 (1969).
34. M. Kauranen and A. Persoons, "Theory of polarization measurements of second-order nonlinear light scattering," J. Chem. Phys. 104, 3445-3456 (1995).
35. G. Wagniere, "The evaluation of three-dimensional rotational averages," J. Chem. Phys. 76, 473-480 (1982).
36. J. Jerphagnon, D. Chemla, and R. Bonneville, "The description of the physical properties of condensed matter using irreducible tensors," Adv. Phys. 27, 609-650 (1978).
37. J. Jerphagnon, "Invariants of the third-rank Cartesian tensor: optical nonlinear susceptibilities," Phys. Rev. B 2, 1091-1098 (1970).
38. M. Tinkham, Group Theory and Quantum Mechanics (McGraw-Hill, New York, 1964).
39. K. D. Singer, J. E. Sohn, L. A. King, H. M. Gordon, H. E. Katz, and C. W. Dirk, "Second-order nonlinear optical propperties of donor and acceptor substituted aromatic compounds," J. Opt. Soc. Am. B 6, 1339-1350 (1989).
40. M. W. Schmidt, K. K. Baldridge, J. A. Boatz, S. T. Elbert, M. S. Gordon, J. H. Jensen, S. Koseki, N. Matsunaga, K. A. Nguyen, S. J. Su, T. L. Windus, M. Dupuis, and J. A. Montgomery, "General atomic and molecular electronic structure system," J. Comput. Chem. 14, 1347-1363 (1993).
41. J. D. V. Khaydarov, J. H. Andrews, and K. D. Singer, "Pulse compression mechanism in a synchronously pumped optical parametric oscillator," J. Opt. Soc. Am. B 12, 2199-2208 (1995).
42. S. W. Wong and K. Y. Wong, "Studies of depolarized hyper- Rayleigh scattering of organic molecule," Opt. Commun. 133, 268-272 (1997).
43. P. R. Bevington, Data Reduction and Error Analysis for the Physical Sciences (McGraw-Hill, New York, 1969).
44. J. J. Maki, M. Kauranen, and A. Persoons, "Surface second-harmonic generation from chiral materials," Phys. Rev. B 51, 1425-1433 (1995).
45. M. Kauranen, T. Verbiest, J. J. Maki, and A. Persoons, "Second-harmonic generation from chiral surfaces," J. Chem. Phys. 101, 8193-8199 (1994).