Synthesis and structures of (porphinato)(thiolato)gallium(III) complexes

Chemistry Letters

Volumn , Issue 3, 1998, Pages 199-200

  Okamura, Taka Aki ^a   Nishikawa, Nami ^a   Ueyama, Norikazu ^a   Nakamura, Akira ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032331532     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.199     Document Type: Article

References (20)

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12. 3OH): C. 67.84; H, 7.84, N, 8.22%. The original crystal contains three methanol molecules as crystal solvent which is easily removed under reduced pressure.
13. 2), 5.87 (1H, t, 5-H), 6.47 (1H, t, 4-H), 7.72 (1H, d, 3-H), 6.30 (1H, s, NH), 10.26 (4H, s, meso-H).
14. 3), 4.06 (2H, d, C-H), 6.10 (2H, m, m-H), 6.45 (1H, t, p-H), 10.25 (4H, s, meso-H).
15. w = 0.054, GOF = 1.52.
16. G. M. Scheldrick, "Crystallographic Computing 3", ed by G. M. Scheldrick, C. Krüger, and R. Goddard, Oxford University Press (1985), pp 175-189.
17. N. Ueyama, T. Okamura, and A. Nakamura, J. Chem. Soc., Chem. Commun., 1992, 1019.; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, and J. M. Waters, J. Chem. Soc., Chem. Commun., 1993, 1658.; N. Ueyama, T. Okamura, and A. Nakamura, J. Am. Chem. Soc., 114, 8129 (1992).
18. N. Ueyama, T. Okamura, and A. Nakamura, J. Chem. Soc., Chem. Commun., 1992, 1019.; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, and J. M. Waters, J. Chem. Soc., Chem. Commun., 1993, 1658.; N. Ueyama, T. Okamura, and A. Nakamura, J. Am. Chem. Soc., 114, 8129 (1992).
19. N. Ueyama, T. Okamura, and A. Nakamura, J. Chem. Soc., Chem. Commun., 1992, 1019.; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, and J. M. Waters, J. Chem. Soc., Chem. Commun., 1993, 1658.; N. Ueyama, T. Okamura, and A. Nakamura, J. Am. Chem. Soc., 114, 8129 (1992).
20. 1u(π) orbital without any electron density on Ga and SPh.