Study of the (electro)chemical equilibria in molten carbonate under MCFC cathode gas conditions. Part II: Non-equilibrium study of (electro)chemical reactions involved in oxygen reduction in molten carbonate

Electrochimica Acta

Volumn 43, Issue 21-22, 1998, Pages 3313-3331

  Peelen, W H A ^a   Van Driel, M ^a   Hemmes, K ^a   De Wit, J H W ^a  

^a DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

MCFC; Molten carbonate; Non equilibrium; Oxygen reduction; Rate constants

Indexed keywords

CARBONATES; CATHODES; CYCLIC VOLTAMMETRY; DIFFUSION; MOLTEN MATERIALS; OXYGEN; PEROXIDES; REACTION KINETICS; REDUCTION;

MOLTEN CARBONATE; OXYGEN REDUCTION;

ELECTROCHEMISTRY;

EID: 0032316215     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0013-4686(98)00070-X     Document Type: Article

References (33)

1. S. H. Lu and J. R. Selman, J. Electrochem. Soc. 137, 1125 (1990).
2. T. Nishina, S. Ohuchi, K. Yamada and I. Uchida, J. Electroanal. Chem. 408, 181-187 (1996).
3. J. A. Prins-Jansen, Cathodes in molten carbonate fuel cells. Ph.D. thesis, Delft University of Technology, The Netherlands, 1996, pp. 245-249.
4. T. Nishina, I. Uchida and J. R. Selman, J. Electrochem. Soc. 141, 1191 (1994).
5. M. Cassir, B. Malinowska, W. Peelen, K. Hemmes and J. H. W. de Wit, J. Electroanal. Chem. 433, 195-205 (1997).
6. R. W. Reeve, A study of oxygen reduction and related electrochemistry at the molten carbonate fuel cell cathode. Ph.D. thesis, The Univ. of Essex, January 1994.
7. G. Moutiers, M. Cassir, C. Piolet and J. Devynck, Electrochim. Acta 36, 1063 (1991).
8. G. Moutiers, M. Cassir and J. Devynck, J. Electroanal. Chem. 324, 175-189 (1992).
9. M. Cassir, G. Moutiers and J. Devynck, J. Electrochem. Soc. 140, 3114 (1993).
10. S. H. White and U. M. Twardoch, J. Appl. Electrochem. 19, 901 (1989).
11. P. K. Adanuvor, R. E. White and A. J. Appleby, J. Electrochem. Soc. 137, 209 (1990).
12. G. Mordarski, J. Electroanal. Chem. 304, 123-132 (1991).
13. I. Uchida, T. Nishina, Y. Mugikura and K. Itaya, J. Electroanal. Chem. 209, 125 (1986).
14. C. Y. Yuh and J. R. Selman, J. Electrochem. Soc. 138, 3642 (1991).
15. R. Ch. Makkus, K. Hemmes and J. H. W. de Wit, Ber. Bunsenges. Phys. Chem. 94, 960 (1990).
16. P. Tomczyck, J. Electroanal. Chem. 379, 353 (1994).
17. R. W. Reeve and A. C. C. Tseung, J. Electroanal. Chem. 403, 69-83 (1996).
18. D. Moyaux, J. Glibert and P. Claes, J. Electroanal. Chem. 349, 415-428 (1993).
19. P. Tomczyck and L. K. Bieniasz, J. Electroanal. Chem. 304, 111 (1991).
20. ELSIM, Technical Software Distributors, 5930 South Boulevard, Suite 102, Charlotte, NC 28217, U.S.A.
21. A. Borucka, J. Electrochem. Soc. 124, 972 (1977).
22. R. S. Nicholson and I. Shain, Anal. Chem. 36, 706 (1964).
23. L. K. Bieniasz, J. Electroanal. Chem. 304, 101-109 (1991).
24. Bard and Faulkner, Electrochemical Methods: Fundamentals and Applications. Wiley, New York, 1980, p. 228.
25. T. Berzins and P. Delahay, J. Am. Chem. Soc. 75, 555 (1953).
26. B. Kr. Andersen, Thermodynamic properties of molten alkali carbonates. Ph.D. thesis, Tech. Univ. of Denmark, Lyngby, 1975.
27. Bard and Faulkner, Electrochemical Methods: Fundamentals and Applications. Wiley, New York, 1980, p. 434.
28. B. Kr. Andersen, Thermodynamic properties of molten alkali carbonates. Ph.D. thesis, Tech. Univ. of Denmark, Lyngby, 1975, p. 96.
29. NIST Properties of Molten Salts Database, Version 2.0, Standard Reference Database, NIST Gaithersburg, MD 20899, U.S.A., 1991.
30. M. Cassir, private communication.
31. T. Nishina, C.-G. Lee, H. Nakano, I. Uchida and S. Kuroe, Proc. 4th Symp. on MCFC Technology, ed. J. R. Selman, I. Uchida, H. Wendt, D. A. Shores and T. Fuller, PV 97-4. The Electrochemical Softbound Proc. Series, Pennington, NJ, 1997.
32. J. A. Prins-Jansen, Cathodes in molten carbonate fuel cells. Ph.D. thesis, Delft University of Technology, The Netherlands, 1996.
33. J.O'M. Bockris and A. K. N. Reddy, in Modern Electrochemistry, Vol. 2. Plenum, New York, 1970.