Preparation of diaza dioxa dithia crown p-tert-butylcalix[4]arene by S-alkylation reactions: Use of metallo-calix[4]arene complexes as reaction templates

Chemistry Letters

Volumn , Issue 10, 1998, Pages 1037-1038

  Tomapatanaget, Boosayarat ^a   Pulpoka, Buncha ^a   Tuntulani, Thawatchai ^a  

^a CHULALONGKORN UNIVERSITY   (Thailand)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032274825     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.1037     Document Type: Article

References (19)

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2. S. Shinkai, Tetrahedron, 49, 8933 (1993); V. Böhmer, Angew. Chem. Int. Ed. Engl., 34, 713 (1995); A. Pochini and R. Ungaro, in "Comprehensive Supramolecular Chemistry," ed by F. Vögtle, Pergamon Press, London (1996), Vol. 2, p. 103.; A. Ikeda and S. Shinkai, Chem. Rev., 97, 1713 (1997).
3. S. Shinkai, Tetrahedron, 49, 8933 (1993); V. Böhmer, Angew. Chem. Int. Ed. Engl., 34, 713 (1995); A. Pochini and R. Ungaro, in "Comprehensive Supramolecular Chemistry," ed by F. Vögtle, Pergamon Press, London (1996), Vol. 2, p. 103.; A. Ikeda and S. Shinkai, Chem. Rev., 97, 1713 (1997).
4. S. Shinkai, Tetrahedron, 49, 8933 (1993); V. Böhmer, Angew. Chem. Int. Ed. Engl., 34, 713 (1995); A. Pochini and R. Ungaro, in "Comprehensive Supramolecular Chemistry," ed by F. Vögtle, Pergamon Press, London (1996), Vol. 2, p. 103.; A. Ikeda and S. Shinkai, Chem. Rev., 97, 1713 (1997).
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8. D. K. Mills, Y. M. Hsiao, P. J. Farmer, E. V. Atnip, J. H. Reibenspies, and M. Y. Darensbourg, J. Am. Chem. Soc., 113, 1421 (1991); T. Tuntulani, J. H. Reibenspies, P. J. Farmer, and M. Y. Darensbourg, Inorg. Chem., 31, 3497 (1992); G. Musie, P. J. Farmer, T. Tuntulani, J. H. Reibenspies, and M. Y. Darnsbourg, Inorg. Chem., 35, 2176 (1996).
9. D. K. Mills, Y. M. Hsiao, P. J. Farmer, E. V. Atnip, J. H. Reibenspies, and M. Y. Darensbourg, J. Am. Chem. Soc., 113, 1421 (1991); T. Tuntulani, J. H. Reibenspies, P. J. Farmer, and M. Y. Darensbourg, Inorg. Chem., 31, 3497 (1992); G. Musie, P. J. Farmer, T. Tuntulani, J. H. Reibenspies, and M. Y. Darnsbourg, Inorg. Chem., 35, 2176 (1996).
10. M. Y. Darensbourg, I. Font, D. K. Mills, M. Pala, and J. H. Reibenspies, Inorg. Chem., 31, 4965 (1992); G. Musie, J. H. Reibenspies, and M. Y. Darensbourg, Inorg. Chem., 37, 302 (1998).
11. M. Y. Darensbourg, I. Font, D. K. Mills, M. Pala, and J. H. Reibenspies, Inorg. Chem., 31, 4965 (1992); G. Musie, J. H. Reibenspies, and M. Y. Darensbourg, Inorg. Chem., 37, 302 (1998).
12. 8: C, 81.86; H, 8.66%. Found: C, 81.86; H, 8.86%.
13. 1H NMR spectrum is too broad to deduce any information from it.
14. 2+ ion in a square planar fashion. This complex is found in almost every reaction of 1. See references 3 and 4.
15. max): 244 nm.
16. 2O): C, 58.54; H, 7.28; N. 2.35%. Found: C, 58.08; H, 7.05; N, 2.22%.
17. 3OD) δ 0.96 (s, 18H), 1.31 (s, 18H), 1.68 (m, 4H), 2.8 (m, 8H), 2.96 (m, 4H), 3.15 (m, 4H), 3.30 and 4.13 (dd, 8H, J = 13 Hz), 4.00 (m, 2H), 4.32 (m. 6H), 6.77 (s, 4H), 6.93 (s, 2H), 7.03 (s, 4H).
18. 2 component can accommodate many transition metal ions such as Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Pd(II), and Cd(II); T. Tuntulani, Ph.D. Thesis (1995), Texas A&M University, College Station, Texas.
19. D. K. Mills, I. Font, P. J. Farmer, Y.-M. Hsiao, T. Tuntulani, R. M. Buonomo, D. C. Goodman, G. Musie, C. A. Grapperhaus, M. J. Maguire, C.-H. Lai, M. L. Hatley, J. J. Smee, J. A. Bellefeuille, and M. Y. Darensbourg, Inorg. Synth., 32, 89 (1998).