Hetero-dinuclear metal complexes for RNA hydrolysis

Chemistry Letters

Volumn , Issue 10, 1998, Pages 1047-1048

  Kamitani, Jun ^a   Kawahara, Ryuto ^a   Yashiro, Morio ^a   Komiyama, Makoto ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032257436     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.1047     Document Type: Article

References (15)

1. Reviews: a) A. D. Mesmaeker, R. Häner, P. Martin, and H. E. Moser, Acc. Chem. Res., 28, 366 (1995).
2. b) M. Komiyama, J. Biochem., 118, 665 (1995).
3. a) M. Komiyama, K. Matsumura, and Y. Matsumoto, J. Chem. Soc., Chem. Commun., 1992, 640.
4. b) J. R. Morrow, L. A. Buttrey, V. M. Shelton, and K. A. Berback, J. Am. Chem. Soc., 114, 1903 (1992).
5. c) K. Matsumura and M. Komiyama, J. Biochem., 122, 387 (1997).
6. A review: N. Sträter, W. N. Lipscomb, T. Klabunde, and B. Krebs, Angew. Chem., Int. Ed. Engl., 35, 2024 (1996).
7. M. Yashiro, A. Ishikubo, and M. Komiyama, J. Chem. Soc., Chem. Commun., 1995, 1793.
8. a) T. Koike, M. Inoue, E. Kimura, and M. Shiro, J. Am. Chem. Soc., 118, 3091 (1996).
9. b) K. G. Ragunathan and H. -J. Schneider, Angew. Chem., Int. Ed. Engl., 35, 1219 (1996).
10. c) P. Molenveld, S. Kapsabelis, F. J. Engbersen, and D. N. Reinhoudt, J. Am. Chem. Soc., 119, 2948 (1997) and references therein.
11. Mixed hydroxide clusters of two kinds of metal ions hydrolyzed RNA in heterogeneous systems due to bimetallic synergism: M. Irisawa, N. Takeda, and M. Komiyama, J. Chem. Soc., Chem. Commun., 1995, 1221.
12. B. Krebs, K. Schepers, B. Bremer, G. Henkel, E. Althaus, W. Müller-Warmuth, K. Griesar, and W. Haase, Inorg. Chem., 33, 1907 (1994).
13. -3) was initiated by the addition of a stock solution of the Fe(III) complex and/or stock solutions of other metal ions to the reaction mixture.
14. A dinuclear Fe(III)/Zn(II) complex was found at the active site of a purple acid phosphatase: N. Sträter, T. Klabunde, P. Tucker, H. Witzel, and B. Krebs, Science, 268, 1489 (1995).
15. a values of the Fe(III)-bound and the Zn(II)-bound water are around 3 and 9, respectively (J. Burgess, in "Metal Ions in Solution," Horwood, Chichester (1978)).