Asphalt aging: Dual oxidation mechanism and its interrelationships with asphalt composition and oxidative age hardening

Transportation Research Record

Volumn , Issue 1638, 1998, Pages 47-55

  Petersen, J Claine ^a,b   Harnsberger, P Michael ^a  

^a WESTERN RESEARCH INSTITUTE   (United States)

^b NONE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AGE HARDENING; AROMATIC HYDROCARBONS; KETONES; MICROSTRUCTURE; OXIDATION; PRESSURE EFFECTS; REACTION KINETICS; SULFUR COMPOUNDS; THERMAL EFFECTS;

OXIDATIVE AGING; SULFOXIDE;

ASPHALT;

EID: 0032207255     PISSN: 03611981     EISSN: None     Source Type: Journal    
DOI: 10.3141/1638-06     Document Type: Article

References (30)

1. Dorrence, S. M., F. A. Barbour, and J. C. Petersen. Direct Evidence for Ketones in Oxidized Asphalts. Analytical Chemistry. Vol. 46, 1974, pp. 2242-2244.
2. Petersen, J. C., S. M. Dorrence, M. Nazir, H. Plancher, and F. A. Barbour. Oxidation of Sulfur Compounds in Petroleum Residues: Reactivity-Structural Relationships. American Chemical Society Division of Petroleum Chemistry Preprints, Vol. 26, No. 4, 1981, pp. 898-906.
3. Petersen, J. C., F. A. Barbour, and S. M. Dorrence. Identification of Dicarboxylic Anhydrides in Oxidized Asphalts. Analytical Chemistry, Vol. 47, 1975, pp. 107-111.
4. Petersen, J. C., and H. Plancher. Quantitative Determination of Carboxylic Acids and Their Salts and Anhydrides in Asphalts by Selective Chemical Reaction and Differential Infrared Spectroscopy. Analytical Chemistry, Vol. 53, 1981, pp. 786-789.
5. Lau, C. K., K. M. Lundsford, C. J. Glover, R. R. Davidson, and J. A. Bullin. Reaction Rates and Hardening Susceptibilities as Determined for Pressure Oxygen Vessel Aging of Asphalts. In Transportation Research Record 1342, TRB, National Research Council, Washington, D.C., 1992, pp. 50-57.
6. Petersen, J. C., J. F. Branthaver, R. E. Robertson, P. M. Harnsberger, J. J. Duvall, and E. K. Ensley. Effects of Physicochemical Factors on Asphalt Oxidation Kinetics. In Transportation Research Record 1391, TRB, National Research Council, Washington, D.C., 1993, pp. 1-10.
7. Petersen, J. C., P. M. Harnsberger, and R. E. Robertson. Factors Affecting the Kinetics and Mechanisms of Asphalt Oxidation and the Relative Effects of Oxidation Products on Age Hardening. American Chemical Society Division of Fuel Chemistry Preprints, Vol. 41, No. 4, 1996, pp. 1232-1244.
8. Liu, M., K. M. Lundsford, R. R. Davidson, C. J. Glover, and J. A. Bullin. Kinetics of Carbonyl Formation in Asphalts. American Institute of Chemical Engineers Journal, Vol. 42, No. 4, 1996, pp. 1069-1076.
9. Knotnerus, J. Oxygen Uptake by Bitumen Solutions as a Potential Measure of Bitumen Durability. American Chemical Society Division of Petroleum Chemistry Preprints, Vol. 16, No. 1, 1971, pp. D37-D59.
10. Martin, K. G. Influence of Stabilizers on Bitumen Durability. Journal of Applied Chemistry, Vol. 16, 1966, pp. 197-202.
11. Haxo, H. E., and R. M. White. Reducing the Hardening of Paving Asphalts Through the Use of Lead Antioxidants. Proc., Association of Asphalt Paving Technologists, Vol. 48, 1975, pp. 611-645.
12. van Gooswilligen, E. H., H. Berger, and F. Th. de Bats. Oxidations of Bitumens in Various Tests. Proc., European Bitumen Conference, 1985, pp. 95-101.
13. King, G. N. Oxycyclics: Understanding Catalyzed Oxidation Mechanisms on Bitumen and Other Petroleum Products. Fuel Science and Technology International, Vol. 11, No. 1, 1993, pp. 201-238.
14. Nellensteyn, F. J. Relation of the Micelle to the Medium of Asphalt. Institute of Petroleum Technology, Vol. 14, 1928, pp. 134-138.
15. Storm, D. A., R. J. Barresi, and E. Y. Sheu. Development of Solid Properties and Thermochemistry of Asphalt Binders in the 25-65°C Temperature Range. Energy and Fuels, Vol. 10, 1996, pp. 855-864.
16. Petersen, J. C. Quantitative Functional Group Analysis of Asphalts Using Differential Infrared Spectrometry and Selective Chemical Reactions - Theory and Practice. In Transportation Research Record 1091, TRB, National Research Council, Washington, D.C., 1986, pp. 1-11.
17. Branthaver, J. F., J. C. Petersen, R. E. Robertson, J. J. Duvall, S. S. Kim, P. M. Harnsberger, T. Mill, F. A. Barbour, and J. F. Schabron. Binder Characterization and Evaluation, Volume 2: Chemistry. SHRP-A-368. National Research Council, Washington, D.C., 1993, 479 pp.
18. Petersen, J. C. A Thin Film Accelerated Aging Test for Evaluating Asphalt Oxidative Aging. Proc., Association of Asphalt Paving Technologists, Vol. 58, 1989, pp. 220-237.
19. Branthaver, J. F., J. C. Petersen, J. J. Duvall, and P. M. Harnsberger. Compatibilities of Strategic Highway Research Program Asphalts. In Transportation Research Record 1323, TRB, National Research Coun-cil, Washington, D.C., 1991, pp. 22-31.
20. Petersen, J. C. Chemical Composition of Asphalt as Related to Asphalt Durability: State of the Art. In Transportation Research Record 999, TRB. National Research Council, Washington, D.C., 1984, pp. 13-30.
21. Mill, T. The Role of Hydroaromatics in Oxidative Aging in Asphalt. American Chemical Society Division of Petroleum Chemistry Preprints, Vol. 41, No. 4, 1996, pp. 1245-1249.
22. Mill, T., C. C. D. Yao, and M. Su. Asphalt Oxidation Pathway Studies. Final Report, SRI Project No. 1271, prepared for Western Research Institute, 1997.
23. Bateman, L., and K. R. Hargrave. Oxidation of Organic Sulfides. I. Interaction of Cyclohexylmethyl Sulfide with Hydroperoxides in Alcohols Proc., the Royal Society, A224 (part 1), 1954, pp. 389-398.
24. Mill, T., and D. G. Hendry. Kinetics and Mechanisms of Free Radical Oxidation of Alkenes and Olefins in Liquid Phase. In Comprehensive Chemical Kinetics (C. H. Bamford and C. F. H. Tipper, eds.), Vol. 16, Elsevier, Amsterdam, 1980, pp. 1-83.
25. Mushrush, G. U. Fuel Instability 1: Organo-Sulfur Hydroperoxide Reactions. Fuel Science and Technology International, Vol. 10, No. 9, 1992, pp. 1523-1560.
26. Hiatt R., J. Mill, K. C. Irwin, and J. K. Castleman. Homolytic Decompositions of Hydroperoxides. III. Radical-Induced Decompositions of Primary and Secondary Hydroperoxides. Journal of Organic Chemistry, Vol. 33, 1968, pp. 1428-1430.
27. Mushrush, G. W., E. J. Beal, E. Slone, and D. R. Hardy. Reaction of Organosulfur Compounds with Naturally Occurring Peroxides in Jet Fuel. Energy and Fuels, Vol. 10, 1996, pp. 504-508.
28. Petersen, J. C. A Dual, Sequential Mechanism for the Oxidation of Petroleum Asphalt. Petroleum Science and Technology, 1998, in press.
29. Branthaver, J. F., M. Nazir, J. C. Petersen, S. M. Dorrence, and M. J. Ryan The Effect of Metalloporphyrins in Asphall Oxidation. II. The Effect of Vanadyl Chelates Found in Petroleum. Liquid Fuels and Technology, Vol. 2, No. 1, 1984, pp. 67-89.
30. Huh, J. D., and R. E. Robertson. Modeling of Oxidative Aging Behavior of Asphalts from Short Term, High Temperature Data as a Step Toward Prediction of Pavement Aging. In Transportation Research Record 1535, TRB, National Research Council, Washington, D.C., 1996, pp. 91-97.