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Volumn 31, Issue 23, 1998, Pages 8075-8082

Effect of stereoregularity on the thermal behavior of poly(methacrylic acid)s. 2. Decomposition at low temperatures

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CONFORMATIONS; CROSSLINKING; GLASS TRANSITION; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; PYROLYSIS; REACTION KINETICS; SOLUBILITY; STEREOCHEMISTRY;

EID: 0032206552     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma981025+     Document Type: Article
Times cited : (41)

References (49)
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    • Results on the thermal degradation of st- and it-PMMAs are also reported in: (a) Jellinek, H. H. G.; Luh, M. D. J. Phys. Chem. 1966, 70, 3672. (b) Chiantore, O.; Guaita, M. Polym Bull. 1988, 20, 201. (c) Chiantore, O.; Guaita, M.; Rendina, G. Makromol. Chem. 1989, 190, 449.
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    • Results on the thermal degradation of st- and it-PMMAs are also reported in: (a) Jellinek, H. H. G.; Luh, M. D. J. Phys. Chem. 1966, 70, 3672. (b) Chiantore, O.; Guaita, M. Polym Bull. 1988, 20, 201. (c) Chiantore, O.; Guaita, M.; Rendina, G. Makromol. Chem. 1989, 190, 449.
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    • Results on the thermal degradation of st- and it-PMMAs are also reported in: (a) Jellinek, H. H. G.; Luh, M. D. J. Phys. Chem. 1966, 70, 3672. (b) Chiantore, O.; Guaita, M. Polym Bull. 1988, 20, 201. (c) Chiantore, O.; Guaita, M.; Rendina, G. Makromol. Chem. 1989, 190, 449.
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    • On commercially available PMAD: (a) Gritter, R. J.; Seeger, M.; Johnson, D. E. J. Polym. Sci., Polym. Chem. Ed. 1978, 16, 169. (b) Fyfe, C. A.; McKinnon, M. S. Macromolecules 1986, 19, 1909. (c) Ho, B. C.; Lee, Y. D.; Chin, W. K. J. Polym. Sci., Part A: Polym. Chem. Ed. 1992, 30, 2389. (d) Schild, H. G. J. Polym. Sci., Part A: Polym. Chem. Ed. 1993, 31, 2403. On PMAD specially prepared by radical polymerization: (e) Grant, D. H.; Grassie, N.; Polymer I960, 1, 125. (f) Roux, F. X.; Audebert, R.; Quivoron, C. Eur. Polym J. 1973, 9, 815. (g) Bajaj, P.; Goyal, M.; Chavan, R. B. J. Appl. Polym. Sci. 1994, 51, 423. (h) McNeill, I. C.; Ahmed, S.; Memetea, L. Polym. Degrad. Stab. 1995, 47, 423. (i) McNeill, I. C.; Ahmed, S.; Memetea, L. Polym. Degrad. Stab. 1995, 48, 89. (l) McNeill, I. C.; Memetea, L.; Ahmed, S.; Cole, W. J. Polym. Degrad. Stab. 1995, 48, 395.
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    • On commercially available PMAD: (a) Gritter, R. J.; Seeger, M.; Johnson, D. E. J. Polym. Sci., Polym. Chem. Ed. 1978, 16, 169. (b) Fyfe, C. A.; McKinnon, M. S. Macromolecules 1986, 19, 1909. (c) Ho, B. C.; Lee, Y. D.; Chin, W. K. J. Polym. Sci., Part A: Polym. Chem. Ed. 1992, 30, 2389. (d) Schild, H. G. J. Polym. Sci., Part A: Polym. Chem. Ed. 1993, 31, 2403. On PMAD specially prepared by radical polymerization: (e) Grant, D. H.; Grassie, N.; Polymer I960, 1, 125. (f) Roux, F. X.; Audebert, R.; Quivoron, C. Eur. Polym J. 1973, 9, 815. (g) Bajaj, P.; Goyal, M.; Chavan, R. B. J. Appl. Polym. Sci. 1994, 51, 423. (h) McNeill, I. C.; Ahmed, S.; Memetea, L. Polym. Degrad. Stab. 1995, 47, 423. (i) McNeill, I. C.; Ahmed, S.; Memetea, L. Polym. Degrad. Stab. 1995, 48, 89. (l) McNeill, I. C.; Memetea, L.; Ahmed, S.; Cole, W. J. Polym. Degrad. Stab. 1995, 48, 395.
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    • On commercially available PMAD: (a) Gritter, R. J.; Seeger, M.; Johnson, D. E. J. Polym. Sci., Polym. Chem. Ed. 1978, 16, 169. (b) Fyfe, C. A.; McKinnon, M. S. Macromolecules 1986, 19, 1909. (c) Ho, B. C.; Lee, Y. D.; Chin, W. K. J. Polym. Sci., Part A: Polym. Chem. Ed. 1992, 30, 2389. (d) Schild, H. G. J. Polym. Sci., Part A: Polym. Chem. Ed. 1993, 31, 2403. On PMAD specially prepared by radical polymerization: (e) Grant, D. H.; Grassie, N.; Polymer I960, 1, 125. (f) Roux, F. X.; Audebert, R.; Quivoron, C. Eur. Polym J. 1973, 9, 815. (g) Bajaj, P.; Goyal, M.; Chavan, R. B. J. Appl. Polym. Sci. 1994, 51, 423. (h) McNeill, I. C.; Ahmed, S.; Memetea, L. Polym. Degrad. Stab. 1995, 47, 423. (i) McNeill, I. C.; Ahmed, S.; Memetea, L. Polym. Degrad. Stab. 1995, 48, 89. (l) McNeill, I. C.; Memetea, L.; Ahmed, S.; Cole, W. J. Polym. Degrad. Stab. 1995, 48, 395.
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  • 38
    • 85034481333 scopus 로고    scopus 로고
    • n of 60 000, and temperatures at the peak top slightly increased with the molecular weight
    • n of 60 000, and temperatures at the peak top slightly increased with the molecular weight.
  • 39
    • 85034477736 scopus 로고    scopus 로고
    • Initial samples are partially soluble in both water or aqueous hydrogen chloride, and DMSO
    • Initial samples are partially soluble in both water or aqueous hydrogen chloride, and DMSO.
  • 46
    • 85034486440 scopus 로고    scopus 로고
    • -1 only in the case of 2,2-disubstituted and 2,2,4,4-tetrasubstituted glutaric anhydrides
    • -1 only in the case of 2,2-disubstituted and 2,2,4,4-tetrasubstituted glutaric anhydrides.
  • 49
    • 85034486562 scopus 로고    scopus 로고
    • 13 has not been possible because the method used for their analysis, (i.e., a gas chromatograph with a quadrupole mass detector) is not suitable for the discrimination of small molecules with the same molecular weight such as carbon oxide and molecular nitrogen, which is always present owing to inevitable air leaks
    • 13 has not been possible because the method used for their analysis, (i.e., a gas chromatograph with a quadrupole mass detector) is not suitable for the discrimination of small molecules with the same molecular weight such as carbon oxide and molecular nitrogen, which is always present owing to inevitable air leaks.


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