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85038546828
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Fractional atomic charges were computed using the the Gaussian 94 for Windows (revision E. 1) Program and an Intel Pentium 200 MHz Personal Computer. The computations were unconstrained and the geometries were true minima
-
11. Fractional atomic charges were computed using the the Gaussian 94 for Windows (revision E. 1) Program and an Intel Pentium 200 MHz Personal Computer. The computations were unconstrained and the geometries were true minima.
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18
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0000856602
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A of its conjugate acid. Reference 4, however, provided data in support of a value < 5. Furthermore, the value of 5.59 reported for an analogous oxazoline would support a value in the range of 3-5 pK units. Clearly, acids such as ethanesulfonic acid and TFA should be sufficiently strong to protonate the oxazolone
-
A of its conjugate acid. Reference 4, however, provided data in support of a value < 5. Furthermore, the value of 5.59 reported for an analogous oxazoline (Weinberger, M.A.; Green halgh, R. Can. J. Chem. 1963, 41, 1038-1041) would support a value in the range of 3-5 pK units. Clearly, acids such as ethanesulfonic acid and TFA should be sufficiently strong to protonate the oxazolone.
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Green Halgh, R.2
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19
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85038541376
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-
There were no remarkable differences in the IR spectra of 1a and 1b suggestive of a lack of coplanarity of the alkenyl and C=N units
-
13. There were no remarkable differences in the IR spectra of 1a and 1b suggestive of a lack of coplanarity of the alkenyl and C=N units.
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20
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21
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85038540039
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-
1a was not examined in this study because of competitive Michael addition
-
15. 1a was not examined in this study because of competitive Michael addition.
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-
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22
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85038548227
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-
The 1:1:1 stoichiometry was utilized so that reasonable quantities of the ring opened product derived from the less reactive oxazolone would be formed and facilitate quantification
-
16. The 1:1:1 stoichiometry was utilized so that reasonable quantities of the ring opened product derived from the less reactive oxazolone would be formed and facilitate quantification.
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26
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