XANES studies of oxidation states of sulfur in aquatic and soil humic substances

Soil Science Society of America Journal

Volumn 62, Issue 5, 1998, Pages 1240-1246

  Xia, K ^a   Weesner, F ^b   Bleam, W F ^b   Bloom, P R ^c   Skyllberg, U L ^c   Helmke, P A ^b  

^a KANSAS STATE UNIVERSITY   (United States)

^b UNIVERSITY OF WISCONSIN MADISON   (United States)

^c UNIVERSITY OF MINNESOTA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; OXIDATION; SOILS; X RAY SPECTROSCOPY;

HUMIC SUBSTANCES; X RAY ABSORPTION NEAR EDGE STRUCTURE (XANES) SPECTROSCOPY;

SULFUR COMPOUNDS;

AQUATIC ENVIRONMENT; HUMIC ACID; MEASUREMENT METHOD; OXIDATION; SOIL PROPERTY;

EID: 0032170117     PISSN: 03615995     EISSN: None     Source Type: Journal    
DOI: 10.2136/sssaj1998.03615995006200050014x     Document Type: Article

References (36)

1. 31P-NMR analysis of phosphorus compounds in extracts of surface soils from selected Karri (Eucalyptus diversicolor F. Muell) forests. Soil Biol. Biochem. 21:523-528.
2. Cram, D.J., and G.S. Hammond. 1959. Organic chemistry. McGraw-Hill, New York.
3. Frank, P., B. Hedman, R.M.K. Carlson, T.A. Tyson, A.L. Roe, and K.O. Hodgson. 1987. A large reservoir of sulfate and sulfonate residues within plasma cells from Ascidia ceratodes revealed by X-ray absorption near-edge structure spectroscopy. Biochemistry 26:4975-4976.
4. Freney, J.R. 1967. Sulfur-containing organics. p. 229-259. In A.D. McLaren and G.H. Peterson (ed.) Soil biochemistry. Marcel Dekker, New York.
5. Freney, J.R., G.E. Melville, and C.H. Williams. 1970. The determination of carbon bonded sulfur in soil. Soil Sci. 109:310-318.
6. George, G.N., and M.L. Gorbaty. 1989. Sulfur K-edge x-ray absorption spectroscopy of petroleum asphaltenes and model compounds. J. Am. Chem. Soc. 111:3182-3186.
7. George, G.N., M.L. Gorbaty, S.R. Kelemen, and M. Sansone. 1991. Direct determination and quantification of sulfur forms in coals from the Argonne premium sample program. Energy Fuels 5:93-97.
8. Germida, J.J., M. Wainwright, and V.V.S.R. Gupta. 1992. Biochemistry of sulfur cycling in soil. p. 1-53. In G. Stotzky and J.M. Bollag (ed.) Soil biochemistry. Marcel Dekker, New York.
9. Gorbaty, M.L., G.N. George, and S.R. Kelemen. 1990. Direct determination and quantification of sulphur forms in heavy petroleum and coals. 2. The sulphur K edge x-ray absorption spectroscopy approach. Fuel 69:945-949.
10. Harter, R.D., and R. Naidu. 1995. Role of metal-organic complexation in metal sorption by soils. Adv. Agron. 55:219-263.
11. Huffman, G.P., S. Mitra, F.E. Huggins, N. Shah, S. Vaidya, and F. Lu. 1991. Quantitative analysis of all major forms of sulfur in coal by x-ray absorption fine structure spectroscopy. Energy Fuels 5:574-581.
12. Huffman, G.P., N. Shah, F.E. Huggins, L.M. Stock, K. Chatterjee, J.J. Kilbane II, M.M. Chou, and D.H. Buchanan. 1995. Sulfur speciation of desulfurized coals by XANES spectroscopy. Fuel 74:549-555.
13. Leenheer, J.A., D.M. McKnight, E.M. Thurman, and P. MacCarthy. 1994. Structural components and proposed structural models of fulvic acid from the Suwannee River. p. 195-211. In R.C. Averett et al. (ed.) Humic substances in the Suwannee River, Georgia: Interactions, properties, and proposed structures. U.S. Geol. Surv. Water-Supply Pap. 2373.
14. Lytle, F.W., R.B. Greegor, D.R. Sandsrom, E.C. Marques, J. Wong, C.L. Spiro, G.P. Huffman, and F.E. Huggins. 1984. Measurement of soft x-ray absorption spectra with a fluorescent ion chamber detector. Nucl. Instrum. Methods Phys. Res. 226:542-548.
15. MacCarthy, P., R.L. Malcolm, C.E. Clapp, and P.R. Bloom. 1990. An introduction to soil humic substances. p. 1-12. In P. MacCarthy et al. (ed.) Humic substances in soil and crop sciences: Selected readings. ASA and SSSA, Madison, WI.
16. 13C-NMR spectroscopy. p. 13-36. In P. MacCarthy et al. (ed.) Humic substances in soil and crop sciences: Selected readings. ASA and SSSA, Madison, WI.
17. Malcolm, R.L., D.M. McKnight, and R.C. Averett. 1994. Isolation of fulvic and humic acids from the Suwannee River. p. 13-19. In R.C. Averett et al. (ed.) Humic substances in the Suwannee River, Georgia: Interactions, properties, and proposed structures. U.S. Geol. Surv. Water-Supply Pap. 2373.
18. McKnight, D.M. 1994. Metal-binding structure. p. 204-206. In R.C. Averett et al. (ed.) Humic substances in the Suwannee River, Georgia: Interactions, properties, and proposed structures. U.S. Geol. Surv. Water-Supply Pap. 2373.
19. Misono, M., E. Ochiai, Y. Saito, and Y. Yoneda. 1967. A new dual parameter scale for the strength of Lewis acids and bases with the evaluation of their softness. J. Inorg. Nucl. Chem. 29:2685-2691.
20. Morra, M.J., S.E. Fendorf, and P.D. Brown. 1997. Speciation of sulfur in humic and fulvic acids using x-ray absorption near-edge structure (XANES) spectroscopy. Geochim. Cosmochim. Acta 61:683-688.
21. Murphy, E.M., and J.M. Zachara. 1995. The role of sorbed humic substances on the distribution of organic and inorganic contaminants in groundwater. Geoderma 67:103-124.
22. Reddy, M.M., J.A. Leenheer, and R.L. Malcolm. 1994. Elemental analysis and heat of combustion of fulvic acid from the Suwannee River. p. 81-88. In R.C. Averett et al. (ed.) Humic substances in the Suwannee River, Georgia: Interactions, properties, and proposed structures. U.S. Geol. Surv. Water-Supply Pap. 2373.
23. Spiro, C.L., J. Wong, F.W. Lytle, R.B. Geegor, D.H. Maylotte, and S.H. Lamson. 1984. X-ray absorption spectroscopic investigation of sulfur sites in coal: Organic sulfur identification. Science (Washington, DC) 226:48-50.
24. Stevenson, F.J. 1986. The sulfur cycle. p. 285-320. In Cycles of soil: Carbon, nitrogen, phosphorus, sulfur, micronutrients. John Wiley & Sons, New York.
25. Stevenson, F.J. 1994. Humus chemistry: Genesis, composition, reactions. 2nd ed. John Wiley & Sons, New York.
26. Tabatabai, M.A., and J.M. Bremner. 1972a. Sulphur in Iowa soils. Sulphur Inst. J. 8:10-13.
27. Tabatabai, M.A., and J.M. Bremner. 1972b. Forms of sulfur, and carbon, nitrogen and sulfur relationships, in Iowa soils. Soil Sci. 114:380-386.
28. Taghiei, M.M., F.E. Huggins, N. Shah, and G.P. Huffman. 1992. In situ x-ray absorption fine structure spectroscopy investigation of sulfur functional groups in coal during pyrolysis and oxidation. Energy Fuels 6:293-300.
29. Thurman, E.M., and R.L. Malcolm. 1981. Preparative isolation of aquatic humic substances. Environ. Sci. Technol. 15:463-466.
30. Vairavamurthy, A., B. Manowitz, G.W. Luther III, and Y. Jeon. 1993. Oxidation state of sulfur in thiosulfate and implications for anaerobic energy metabolism. Geochim. Cosmochim. Acta. 57:1619-1623.
31. Vairavamurthy, A., W. Zhou, T. Eglinton, and B. Manowitz. 1994. Sulfonates: a novel class of organic sulfur compounds in marine sediments. Geochim. Cosmochim. Acta 58:4681-4687.
32. Van Loon, W.M.G.M., J.J. Boon, and B. DeGroot. 1993. Quantitative analysis of sulfonic acid groups in macromolecular lignosulfonic acids and aquatic humic substances by temperature-resolved pyrolysis-mass spectrometry. Environ. Sci. Technol. 27:2387-2396.
33. Waldo, G.S., R.M.K. Carlson, J.M. Moldowan, K.E. Petters, and J.E. Penner-Hahn. 1991a. Sulfur speciation in heavy petroleum: Information from x-ray absorption near-edge structure. Geochim. Cosmochim. Acta 55:801-814.
34. Waldo, G.S., O.C. Mullins, J.E. Penner-Hahn, and S.P. Cramer. 1991b. Determination of the chemical environment of sulphur in petroleum asphaltenes by x-ray absorption spectroscopy. Fuel 70:549-559.
35. Weber, J.H. 1988. Binding and transport of metals by humic materials. p. 165-178. In F.H. Frimmel and R.F. Christman (ed.) Humic substances and their role in the environment. Wiley-Interscience, Chichester, England.
36. Xia, K., W.F. Bleam, and P.A. Helmke. 1997. Studies of the nature of binding sites of first row transition elements bound to aquatic and soil humic substances using x-ray absorption spectroscopy. Geochim. Cosmochim. Acta 61:2223-2235.